大颗粒悬浮液中的絮凝作用

S. G. Mason, C. Hubley, A. Robertson
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引用次数: 10

摘要

基于剪切诱导粒子间碰撞的粒子聚集机理,提出了一种研究大颗粒悬浮液絮凝的新方法,并给出了纤维素-纤维悬浮液的代表性结果。该方法是将悬浮液置于剪切运动的再现条件下,并通过电子分析光学透射系数的波动。在此基础上,提出了适合于该方法的絮凝指数(σ/N0)。该指数是聚合的数量和大小的函数。絮凝指数随剪切速率的增大和纤维长度的减小而降低。考察了浓度和添加剂的影响。概述了可供选择的实验技术,并指出了本方法的局限性。
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FLOCCULATION IN SUSPENSIONS OF LARGE PARTICLES
Based upon an assumed mechanism of particle aggregation by shear-induced interparticle collisions, a new method of studying flocculation in suspensions of large particles is described, and representative results obtained with cellulose–fiber suspensions are presented. The method consists in subjecting the suspension to a reproducible condition of shear motion and analyzing the fluctuations in optical transmission coefficient electronically. An approximate statistical theory is presented on the basis of which a flocculation index (σ/N0) appropriate to the method is proposed. The index is a function of both the number and size of the aggregates. The flocculation index was found to decrease with increasing rate of shear and decreasing fiber length. The effect of concentration and of additives was investigated. Alternative experimental techniques are outlined and limitations to the present method are pointed out.
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