预测阻垢作用的统一实验方法和模型

Chong Dai, Z. Dai, Fangfu Zhang, Yue Zhao, Guannan Deng, K. Harouaka, Xin Wang, Yi-Tsung Lu, Samiridhdi Paudyal, Saebom Ko, Shujun Gao, A. Kan, M. Tomson
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引用次数: 12

摘要

结垢地层是油田生产中存在的严重问题。在所有常见的鳞片中,重晶石和方解石是最重要的两种鳞片。阻垢剂的广泛应用是为了延长结垢的诱导时间。本研究评估了在常见卤水条件下,磷酸盐和聚合物抑制剂存在时测量和预测结垢的方法和先前的抑制模型。采用激光浊度测量法准确、快速地测量了诱导时间,并且在不同来源抑制剂之间具有良好的重现性。通过一组独立的抑制实验,对之前的模型进行了评价,并仔细指出了模型改进的需求。在这些评价的基础上,结合各种模拟油田条件(4-175℃)下的所有可用数据,提出了新的ScaleSoftPizer (SSP)模型。新的SSP重晶石缓蚀模型具有更强的内部一致性,新的SSP方解石缓蚀模型扩大了适用温度范围。新的SSP模型被纳入SSP 2019。为了证明新SSP模型的适用性,将预测的最小抑制剂浓度(mic)与实验室观测和现场数据进行了比较,结果显示出良好的一致性和改进。该研究改进了在大温度和抑制剂类型范围内的MIC预测,可以显著降低解决结垢问题的费用和工作量。
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A Unified Experimental Method and Model for Predicting Scale Inhibition
Scale formation that can hinder continuous oil production is a serious problem in oilfield. Among all common scales, barite and calcite are two of the most important scales. Scale inhibitors have been widely added to prolong the induction time of scales. This study evaluates the methods and previous inhibition models to measure and predict scale formation in the presence of phosphonate and polymer inhibitors under common brine conditions. Turbidity measurement with laser light was used accurately and quickly to measure the induction time, and good reproducibility can be achieved between different sources of inhibitors. By conducting a set of independent inhibition experiments, previous models were evaluated and the demand for model improvement was carefully pointed out. On the basis of these evaluations, new ScaleSoftPizer (SSP) model was proposed by incorporating all available data under various simulated oilfield conditions (4-175°C). The new SSP barite inhibition model was more internally consistent, and the new SSP calcite inhibition model expanded the applicable temperature ranges. The new SSP model was incorporated into SSP 2019. To prove the application of new SSP model, the predicted minimum inhibitor concentrations (MICs) were compared with lab observations and field data, which shows good consistence and improvements. This study improved the prediction of MIC over wide ranges of temperature and inhibitor types, which can significantly reduce the expenses and efforts to solve scale formation problems.
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