一种新型多桥配位铜配合物的合成、结构、发光和磁性能

The Open Crystallography Journal Pub Date : 2009-10-01 DOI:10.2174/1874846500902010015

He-lin Niu, Jingguang Chenb, Ju-zhou Zhang, Wei Caoa, Qianwang Chen

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摘要

在160℃的高温下，水热法制备了一种新型的三维金属有机骨架(Cu5(C10H7N2O2)4(N3)2(SO4)2)n(1)。重要的是，变温磁化率研究表明，当C = 0.87 cm 3 mol -1 K和C = -320.2 K时，铜原子之间存在强的反铁磁相互作用。

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A Novel Copper Complex with Multibridging Coordination Mode: Synthesis, Structure, Luminescent and Magnetic Properties

A novel three-dimensional (3D) metal-organic framework (MOF), (Cu5(C10H7N2O2)4(N3)2(SO4)2)n (1), was constructed by a hydrothermal process at 160 o C. The complex 1 exhibits strong emission at 396 nm in solid state. Importantly, the variable-temperature magnetic susceptibility study indicates that there exists strong antiferromagnetic interactions between the copper atoms with C = 0.87 cm 3 mol -1 K and � = -320.2 K.

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The Open Crystallography Journal

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