纳米晶镉掺杂铁氧体镍的组成依赖性结构和磁性研究

R. Tiwari, Manojit De, H. S. Tewari
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引用次数: 1

摘要

采用自燃自燃方法,制备了镉掺杂镍锌铁氧体纳米结构。对样品进行了表征,以确定其成分依赖的结构和磁性能。制备样品的XRD图谱显示立方尖晶石结构(单相)。拉曼光谱显示了与尖晶石相一致的五种活动模式。用饱和磁化强度和磁矩测定了这些铁氧体的磁性能。在300 K温度下记录的穆斯堡尔光谱分析了同分异构体位移、超精细场、四极分裂和谱线宽度随镉掺杂量的变化。采用自燃自燃方法,制备了镉掺杂镍锌铁氧体纳米结构。对样品进行了表征,以确定其成分依赖的结构和磁性能。制备样品的XRD图谱显示立方尖晶石结构(单相)。拉曼光谱显示了与尖晶石相一致的五种活动模式。用饱和磁化强度和磁矩测定了这些铁氧体的磁性能。在300 K温度下记录的穆斯堡尔光谱分析了同分异构体位移、超精细场、四极分裂和谱线宽度随镉掺杂量的变化。
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Studies on composition dependent structural and magnetic characterization of nano-crystalline cadmium doped nickel ferrite
Using self-ignited auto-combustion method, Cd doped Ni-Zn Ferrite nano-structures were prepared. Samples were characterized to determine their composition dependent structural and magnetic properties. XRD patterns of as-prepared specimens’ revealed cubic spinel structure (single phase). Raman spectra disclosed five active modes consistent to the spinel phase. Magnetic properties of these ferrites were determined in terms of saturation magnetization, magnetic moment. Mossbauer spectra recorded at 300 K temperature Variations of isomer shift, hyperfine field, quadrupole splitting and line width are analyzed with the amount of doped Cadmium.Using self-ignited auto-combustion method, Cd doped Ni-Zn Ferrite nano-structures were prepared. Samples were characterized to determine their composition dependent structural and magnetic properties. XRD patterns of as-prepared specimens’ revealed cubic spinel structure (single phase). Raman spectra disclosed five active modes consistent to the spinel phase. Magnetic properties of these ferrites were determined in terms of saturation magnetization, magnetic moment. Mossbauer spectra recorded at 300 K temperature Variations of isomer shift, hyperfine field, quadrupole splitting and line width are analyzed with the amount of doped Cadmium.
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