{"title":"废聚对苯二甲酸乙二醇酯在多元醇和聚氨酯生产中的应用评价","authors":"Tülay Fırat, F. Kar","doi":"10.1080/14658011.2023.2238337","DOIUrl":null,"url":null,"abstract":"ABSTRACT As technology advances and human population grows, we must meet our diverse needs while minimising harm to the environment. One solution is to prioritise recycling and using second-hand consumer goods. In this study, PET flakes were depolymerised by glycolysis using different molar ratios of glycol such as propylene glycol(PG), triethylene glycol(TEG) and polyethylene glycol(PEG 400) in the presence of two different catalysts: zinc acetate- zinc sulphate. As a result, glycated products (polyols-PO) were obtained. The obtained polyols were then used to synthesise polyurethane films (PU) via acetone process. The thermal and chemical characterisations of the polyurethane films (PU) were analysed. In similar studies, zinc acetate was used as a transesterification catalyst for the glycolysis process. In this study, the same process was carried out using zinc sulphate and zinc acetate. Zinc sulphate was found to be a cheaper and eco-friendlier catalyst alternative to zinc acetate for the glycolysis process.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2023-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Evaluation of waste polyethylene terephalate in polyol and polyurethane production\",\"authors\":\"Tülay Fırat, F. Kar\",\"doi\":\"10.1080/14658011.2023.2238337\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT As technology advances and human population grows, we must meet our diverse needs while minimising harm to the environment. One solution is to prioritise recycling and using second-hand consumer goods. In this study, PET flakes were depolymerised by glycolysis using different molar ratios of glycol such as propylene glycol(PG), triethylene glycol(TEG) and polyethylene glycol(PEG 400) in the presence of two different catalysts: zinc acetate- zinc sulphate. As a result, glycated products (polyols-PO) were obtained. The obtained polyols were then used to synthesise polyurethane films (PU) via acetone process. The thermal and chemical characterisations of the polyurethane films (PU) were analysed. In similar studies, zinc acetate was used as a transesterification catalyst for the glycolysis process. In this study, the same process was carried out using zinc sulphate and zinc acetate. Zinc sulphate was found to be a cheaper and eco-friendlier catalyst alternative to zinc acetate for the glycolysis process.\",\"PeriodicalId\":20245,\"journal\":{\"name\":\"Plastics, Rubber and Composites\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2023-08-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Plastics, Rubber and Composites\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/14658011.2023.2238337\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plastics, Rubber and Composites","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/14658011.2023.2238337","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Evaluation of waste polyethylene terephalate in polyol and polyurethane production
ABSTRACT As technology advances and human population grows, we must meet our diverse needs while minimising harm to the environment. One solution is to prioritise recycling and using second-hand consumer goods. In this study, PET flakes were depolymerised by glycolysis using different molar ratios of glycol such as propylene glycol(PG), triethylene glycol(TEG) and polyethylene glycol(PEG 400) in the presence of two different catalysts: zinc acetate- zinc sulphate. As a result, glycated products (polyols-PO) were obtained. The obtained polyols were then used to synthesise polyurethane films (PU) via acetone process. The thermal and chemical characterisations of the polyurethane films (PU) were analysed. In similar studies, zinc acetate was used as a transesterification catalyst for the glycolysis process. In this study, the same process was carried out using zinc sulphate and zinc acetate. Zinc sulphate was found to be a cheaper and eco-friendlier catalyst alternative to zinc acetate for the glycolysis process.
期刊介绍：
Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.
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