聚砜掺杂聚苯胺复合膜。合成及电化学特性

Ș. Voicu, N. D. Stanciu, A. Nechifor, D. Vãireanu, G. Nechifor
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引用次数: 5

摘要

为了将聚砜作为膜材料的优点与聚苯胺作为导电聚合物的优点结合起来,通过对现有聚砜-聚苯胺复合膜的改进,试图获得一种新型的聚砜-聚苯胺复合膜。该技术的优点在于通过浸泡沉淀法进行相转化,并伴随化学反应,随后用磺化的-环糊精活化聚苯胺。采用扫描电镜、红外光谱、热分析等方法对合成膜进行了结构表征。用电化学阻抗谱法测定了离子电导率和电化学特性。
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Polysulfone- doped polyaniline composite membranes. synthesis and electrochemical characteristics
In order to combine the advantages of polysulfone (PSf) as a membrane material to that of polyaniline as a conductive polymer, one has attempted to obtain novel polysulfone-polyaniline composite membranes by a newly improved technique comparing to the existing ones. The strong point of this technique consists in a phase inversion by immersion precipitation accompanying by chemical reaction followed by the activation of polyaniline with sulfonated beta-cyclodextrine. The above synthesized membranes were structurally characterized using Scanning Electron Microscopy, FT-IR spectroscopy, thermal analysis. The ionic conductivity and electrochemical characteristics were also determined by Electrochemical Impedance Spectroscopy.
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