埃及东部沙漠含石榴石白岩浆的起源、动力学和化学演变:A 型岩浆中稀有金属富集的控制因素

IF 2.6 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Chemie Der Erde-Geochemistry Pub Date : 2023-11-01 DOI:10.1016/j.chemer.2023.126025
Nasser M. Mahdy , Tsuyoshi Iizuka , Victoria Pease , Mohamed M. Ghoneim , Amr A. Abdel Hamid
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引用次数: 0

摘要

埃及拥有众多稀有金属花岗岩,即富含稀有金属(Ta、Nb、Be、Sn、Zr、Th 和 REE)的高度演化花岗岩。然而,稀有金属富集的过程还不完全清楚。我们提供了有关埃及东部沙漠 Ras Abdah 地区与微花岗岩尖晶石相关的稀有金属矿化的纹理特征和化学成分的新数据。这些尖晶岩是由透辉石碱长石和石英组成的含石榴石的白榴石(GLG)。与其他埃及 A 型花岗岩相比,微花岗岩尖晶石是 HREE 含量特别高的碱性岩石。锆石、赫托石、铁燧石(Y)和铁-钛-锌氧化物(磁铁矿、含Zn的钛铁矿和焦闪锌矿)在很大程度上与蚀变域有关,这些蚀变域还富含Nb、Zr、Y、Ta、Th和REE。然而,美国格陵兰群岩体中蚀变岩域和未蚀变岩域的软玉归一化REE模式之间的相似性,有利于提出一种独特的岩浆特征假说。此外,稀有金属矿物的化学和纹理特征表明,原生矿物的蚀变是由母体花岗岩岩浆中溶解出来的氘化流体或水性残余熔体(自熔)引起的。石榴石成分中含有丰富的锰铁矿成分(高达 84%),这是高度演化伟晶岩中石榴石的典型特征。此外,石榴石没有表现出主要元素分带,但微量元素浓度出现了化学波动,这表明由于岩浆的连续脉动,熔体成分发生了相应的突变。这种岩浆喷发可能会导致晶体成核和振荡结晶,然后发生岩浆偏析。总之,母岩类型、堤坝注入和岩浆-热液过程都对稀有金属的异常富集起了作用。
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Origin, dynamics, and chemical evolution of garnet-bearing leucogranitic magma, Eastern Desert of Egypt: Controls on the rare-metal enrichment in the A-type magmatism

Egypt hosts numerous rare-metal granites, i.e., highly evolved granites enriched in rare metals (Ta, Nb, Be, Sn, Zr, Th, and REE). However, the processes involved in the rare-metal enrichment are not fully understood. We present new data on the textural characteristics and chemical composition of rare-metal mineralization associated with microgranite dikes in the Ras Abdah area of the Egyptian Eastern Desert. These dikes are garnet-bearing leucogranites (GLG) composed of perthitic alkali-feldspars and quartz. When compared to other Egyptian A-type granites, microgranite dikes are alkaline rocks with particularly higher HREE contents. Zircon, huttonite, fergusonite (Y), and Fe-Ti-Zn oxides (magnetite, Zn-bearing ilmenite and pyrophanite) are largely associated with the altered domains, which are also enriched in Nb, Zr, Y, Ta, Th, and REE. However, similarities between the chondrite-normalized REE patterns of the altered and unaltered domains of the GLG dikes favor the hypothesis of a unique magmatic signature. Moreover, the chemical and textural features of rare-metal minerals indicate that the alteration of primary minerals was caused by deuteric fluids or aqueous residual melt exsolved from the parental granitic magma (autometasomatism). Garnet compositions are rich in the spessartine component (up to 84 %), which is typical of garnet in highly evolved pegmatitic rocks. Furthermore, garnet exhibits no major element zoning but shows chemical fluctuations in trace element concentrations, suggesting correspondingly abrupt changes in melt composition due to sequential magma pulsing. This magma emplacement may cause crystal nucleation and oscillatory crystallization followed by magmatic segregation. Overall, parental magma type, dike injection, and magmatic-hydrothermal processes all play a role in the unusual enrichments of rare metals.

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来源期刊
Chemie Der Erde-Geochemistry
Chemie Der Erde-Geochemistry 地学-地球化学与地球物理
CiteScore
7.10
自引率
0.00%
发文量
40
审稿时长
3.0 months
期刊介绍: GEOCHEMISTRY was founded as Chemie der Erde 1914 in Jena, and, hence, is one of the oldest journals for geochemistry-related topics. GEOCHEMISTRY (formerly Chemie der Erde / Geochemistry) publishes original research papers, short communications, reviews of selected topics, and high-class invited review articles addressed at broad geosciences audience. Publications dealing with interdisciplinary questions are particularly welcome. Young scientists are especially encouraged to submit their work. Contributions will be published exclusively in English. The journal, through very personalized consultation and its worldwide distribution, offers entry into the world of international scientific communication, and promotes interdisciplinary discussion on chemical problems in a broad spectrum of geosciences. The following topics are covered by the expertise of the members of the editorial board (see below): -cosmochemistry, meteoritics- igneous, metamorphic, and sedimentary petrology- volcanology- low & high temperature geochemistry- experimental - theoretical - field related studies- mineralogy - crystallography- environmental geosciences- archaeometry
期刊最新文献
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