半纤维素对白桦造纸性能的影响

D. A. Sitch, H. B. Marshall
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引用次数: 9

摘要

用热酸化亚氯酸钠溶液从白桦树中分离出纤维状的全新纤维素。采用碱法制备了不同半纤维素含量的纸浆,并对其打浆性能和制片性能进行了比较。拉伸强度随半纤维素含量的增加而增加,而抗撕裂性和耐折性降低。在碱萃取半纤维素含量为15%左右时,破裂强度达到最大值。产率为46-53%,即含有10-20%半纤维素的纸浆,具有最佳的综合强度。用同样的木片制备的漂白亚硫酸盐纸浆,得率为43.6%,其中碱萃取半纤维素含量为20.7%。以木材为基础,α-纤维素的总产率比全新纤维素低约6%,这表明在亚硫酸盐处理过程中纤维损伤更大。用亚硫酸盐纸浆制成的手板在破裂和抗压性能上都不如用亚氯酸盐纸浆制成的手板。
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THE EFFECT OF HEMICELLULOSES ON THE PAPERMAKING PROPERTIES OF WHITE BIRCH
A fibrous holocellulose was isolated from white birch using hot acidified sodium chlorite solutions. Pulps of varying hemicellulose content were prepared by alkaline treatment, and their beating and sheetmaking properties compared with the original holocellulose. Tensile strength increased with hemicellulose content, whereas tearing resistance and fold endurance decreased. Bursting strength reached a maximum at about 15% alkali-extractable hemicellulose content. Pulps obtained in yields of 46–53%, i.e., containing 10–20% hemicellulose, possessed the best over-all strength.A bleached sulphite pulp prepared from the same chips in a yield of 43.6% contained 20.7% alkali-extractable hemicellulose. The over-all yield of α-cellulose was about 6% lower, based on the wood, than in the case of the holocellulose, thus indicating greater fiber damage during the sulphite process. Hand sheets made from the sulphite pulp were inferior to sheets made from a chlorite pulp of the same hemicellulose content in bursting and...
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