强极性-弱极性二元体系向列相和各向同性相的介电行为

M. Sarvamangala, M. V. Kumar, S. M. Khened, D. S. S. Rao, S. K. Prasad
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引用次数: 1

摘要

我们测量了二元体系中各向同性液体和各向异性液晶(向列)相的介电常数,其中一个组分的分子具有强极性的纵向基团,而另一个组分具有弱极性的横向基团。两相之间的转变是弱一级的,表现出过渡前效应,表明各向同性相中出现了向列状区域。与典型的极性液体不同,二元混合物的强极性组分的液相在接近向列相时其介电常数呈现凸形异常。我们讨论了弱极性分量对这种异常强度的影响,以及介电各向异性的非线性变化。
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Dielectric behavior in the nematic and isotropic phases of a strongly polar-weakly polar binary system
We have performed measurements of the dielectric constant in the isotropic liquid and anisotropic liquid crystalline (nematic) phases of a binary system, in which one component has molecules with a strongly polar longitudinal group, and the other has a weakly polar transverse group. The transition between the two phases, being weakly first order, exhibits pretransitional effects signifying the appearance of the nematic-like regions in the isotropic phase. Unlike a typical polar liquid, the liquid phase of the strongly polar component of the binary mixture exhibits a convex shaped anomaly in its dielectric constant on approaching the nematic phase. We comment on the effect of the weakly polar component on the magnitude of this anomaly, as well as the nonlinear variation of the dielectric anisotropy.
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