基于机器学习的铜阴极板在电解生产铜粉过程中的界面腐蚀过程分析和预测

Youzhi Zhou, Pengcheng Lin, Xin Ke, Qiang Hu, Qi Shi, Jingguo Zhang, Zhong Wang, Limin Wang
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摘要

目前,为了支持铜基金属粉末的工业规模电解生产,迫切需要实时预测电解生产过程中铜阴极腐蚀的方法。然而,由于难以准确模拟复杂的阴极腐蚀过程,目前的方法非常有限。本研究通过自行设计的连续电解腐蚀实验装置,分析了不同参数下的腐蚀过程,阐明了电流密度对固液气界面区域腐蚀的影响机理,并采用基于电解质温度、液位波动周期和电流密度三个过程参数的随机森林机器学习方法解决了这一问题。该模型使用的数据集是采用一种基于电极阵列的新型腐蚀试验方法获得的。实验结果包括电解过程中不同位置的铜阴极板相对于液体电解质水平的腐蚀速率。结果表明,该随机模型对铜阴极板的不同区域的预测精度高达97%。
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Machine learning‐based analysis and prediction of the interfacial corrosion processes of copper cathode plates during the electrolytic production of copper powders
Present efforts to support the essential industrial‐scale electrolytic production of copper‐based metal powders urgently require approaches to the real‐time predicting of corrosion of copper cathodes employed in electrolytic production processes. However, current approaches are extremely limited owing to the difficulty of accurately modeling the complex cathode corrosion process. In this study, the corrosion process under different parameters was analyzed by a self‐designed continuous electrolytic corrosion experimental device, clarify the influence mechanism of current density on the corrosion of the solid–liquid–gas interface area, and addresses this issue by applying a random forest machine learning approach based on three process parameters, including the electrolyte temperature, liquid‐level fluctuation cycle period, and current density. The dataset employed in the model is obtained using a novel experimental corrosion test method based on electrode arrays. The experimental results include the corrosion rates of copper cathode plates at different positions relative to the liquid electrolyte level during the electrolysis process. The resulting stochastic model is demonstrated to obtain a high prediction accuracy of 97% for the various regions of copper cathode plates defined according to liquid electrolyte level.
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