60℃时卤化物浓度对香蕉皮废缓蚀剂效果的影响

Mochamad Puji Widodo, Yohannes Marudut Tua Silaen, Muhammad Faiq Ridho Ahada Kuswara, T. N. Rohmannudin
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引用次数: 1

摘要

有机缓蚀剂因其丰富且对环境无害而被广泛研究作为一种替代的防腐蚀材料。从植物提取物中获得的有机抑制剂之一是香蕉(Musa Paradisica)皮,因为它含有强抗氧化剂没食子儿茶素。反之,随着温度的升高,有机化合物的抑制效果降低。然而,其他物质如卤化物离子的加入提供了多种缓蚀剂的效果。卤化物离子的加入可以提高有机抑制剂的缓蚀效率。本研究重点研究了添加卤化物浓度对香蕉皮在3.5% NaCl条件下对API 5l钢的抑制效果的影响。采用失重法和电化学法对其缓蚀性能进行了研究。结果表明,在60℃条件下,500 ppm的香蕉皮废提液与100 ppm的碘化钾混合,抑菌效果最佳。同时,共混物表现为混合型缓蚀剂。由于碘离子的离子半径较大,其有效性依次为KI > KBr。香蕉皮废弃物;卤化物浓度;有机抑制剂;
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Effect of Halide Concentration on the Effectiveness of Banana Peel Waste Inhibitor at 60C
Organic inhibitors have been widely studying to be an alternative corrosion prevention because of its abundance and non-hazardous effect to the environment. One of organic inhibitors which is obtained from plant extract is banana (Musa Paradisica) peel, because it has gallocatechin which is a strong antioxidant. Otherwise, inhibition effectiveness from organic compound decreases during increasing of temperature. However, the addition of other substance like halide ion has provided multiple effect of corrosion inhibitor effectiveness. The addition of the halide ions can enhanced the inhibition efficiency of the organic inhibitors. This research highlights the effect of additional halide concentration to the inhibition effectiveness of Musa Paradisica (banana) peel on API 5 L steel in 3,5% NaCl at temperature 60C. This inhibition performance is investigated using weight loss measurement and electrochemical measurement. Result shows that the maximum inhibition efficiency was observed with the mixture of 500 ppm banana peel waaste extract and 100 ppm potassium iodide at 60C. Also, The blends behaved as mixed type inhibitor. The effectiveness was found to be in order of KI > KBr due to the larger ionic radius in iodide ion. Keywords Banana Peel Waste, Halide Concentration, Organic Inhibitor, Temperature 60C.
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审稿时长
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