SDS/GA复合物对碳纳米管稳定性的协同效应

Kriti Singh, S. K. Sharma, Shipra Mital Gupta
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引用次数: 0

摘要

纳米流体的稳定性是其传热应用面临的主要挑战。稳定性意味着分散在基液(如机油、乙二醇(EG)、水)中的固体纳米颗粒不会以显著的速率聚集。在基液中加入表面活性剂是维持纳米流体稳定性的一个很好的选择。本研究的重点是利用不同的表面活性剂制备稳定的热应用纳米流体。采用改进的两步法,在SDS、GA和混合表面活性剂(SDS和GA以50:50的比例混合)的帮助下,将碳纳米管(CNT)纳米颗粒分散在水中。结果表明,当表面活性剂/CNT比为1:1、CNT浓度为0.3 wt%、超声作用时间为180 min (SDS)、150 min (GA)、90 min(混合表面活性剂)时,CNT在基液中的分散效果较好。SDS、GA和混合表面活性剂制备的纳米流体的稳定性分别为~90天、~150天和~200天。与DDW相比,SDS、GA和混合表面活性剂制备的CNT纳米流体的导热系数分别提高了33.9%、46.3%和54.3%。结果表明,这三种纳米流体均可作为传热流体,但混合表面活性剂制备的纳米流体更适合作为传热流体,因为它具有更高的导热性和更好的稳定性,这是传热应用所必需的。
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Synergetic Effect of SDS/GA Mixture on Stability of Aqueous CNT Nanofluid
The stability of nanofluid is the main challenge for their heat transfer applications. Stability means that dispersed solid nanoparticles in basefluid such as engine oil, ethylene glycol (EG), water do not aggregate at a significant rate. The addition of surfactant in basefluid is an excellent option to maintain the stability of nanofluid. This research’s major emphasis is in order to make stable nanofluid for thermal applications using different surfactants. Carbon nanotubes (CNT) nanoparticles are dispersed in water (DDW) with the help of SDS, GA and mixed surfactant (mixture of SDS and GA in 50:50 ratio) using a modified-two step method. Results showed that dispersion of CNT in basefluid was better at 1:1 surfactant/CNT ratio, 0.3 wt% of CNT concentration and 180 minutes (SDS), 150 minutes (GA), 90 minutes (mixed surfactant) ultrasonication time. Nanofluid prepared with SDS, GA and mixed surfactant were found to be stable upto about ~90 days, ~150 days and ~200 days, respectively. CNT nanofluid prepared with SDS, GA and mixed surfactant showed 33.9%, 46.3% and 54.3% enhancement in thermal conductivity as compared to DDW, respectively. According to the results, all three nanofluids can be used as a heat transfer fluid, but nanofluid prepared with mixed surfactant is more suitable because it showed higher thermal conductivity enhancement and better stability which are essential for heat transfer application.
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