封闭室内臭氧生成、分解装置性能评估研究-单一机种测试

文夫 渡辺, 勝義 福岡, 敏之 大谷
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摘要

对市售的室内紫外线臭氧化设备的效率进行了测量和评价。将室内容积分别扩大到4.5m3和54m3,然后使用三种臭氧化设备进行试验。结合小房间的试验结果,得到了房间体积与稳态臭氧浓度、稳态臭氧浓度与灯输入电流的关系式和折线图。实验结果发现了一个新现象,即当室内体积扩大到一定程度后,在初始电流恒定的紫外线灯下,臭氧光分解的表观速度比自发分解的表观速度慢。这种现象被命名为逆温体积。对这三种设备的总体评价如下:1)在臭氧形成的情况下,这些设备是有用的,因为它们的效率足以在一小时内获得稳态的臭氧浓度,尽管达到这一状态所需的时间因其房间体积而异。2)在普通实验室进行臭氧分解的情况下,就分解速度而言,设置一个紫外线灯和一个臭氧灯的效果可能不如自然分解的效果。因此,为了提高分解速度,需要增加一个紫外线灯的输入电流,或者将两个紫外线灯并联设置。3)在极洁净的房间,如生物洁净室,紫外线分解臭氧(采用140W大型双壁)被认为是有用的。最后,对过去测量的所有设备(包括以下系统)进行了效率评估和比较,从而找到了最大的改进空间。
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閉鎖系室内におけるオゾンの生成・分解装置の性能評価に関する研究-単一機種の試験-
The efficiency of commercially available equipments for ozonization by ultraviolet rays in the rooms was measured and assessed. The volume of the room was enlarged to 4.5m3 and to 54m3, and then, the tests were held using three types of ozonization equipments. By considering the data including the results of the tests in the small room, the formulas and the line graphs on the relationships between the room volume and the ozone concentration of the steady state, and those between the ozone concentration of the steady state and the input current of a lamp were obtained. As the result of this experiment, a new phenomenon was found out, that is, the apparent velocity of ozone photo-decomposition by an ultraviolet ray lamp having a constant initial current was slower than that of the spontaneous decompositions, when the room volume was enlarged beyond a certain degree. This phenomenon was named an inversion volume. The overall assessments of these three kinds of equipments were as follows : 1) In the case of the ozone formation those equipments are useful, because they are efficient enough to obtain the ozone concentration of the steady state within an hour, though the time consumed to achieve it varies according to its room volume. 2) In the case of the ozone decomposition in the ordinary laboratory, as far as the decomposition velocity is concerned, setting up one ultraviolet ray lamp and one ozone lamp can be less effective than those of the spontaneous decomposition. Therefore, to increase the decomposition velocity, it is necessary to increase the input current of one ultraviolet ray lamp, or to set up the lamps in parallel. 3) In the extremely clean room, such as a bioclean room, the ozone decomposition by ultraviolet ray (using 140W big type of double wall) is thought to be useful. Lastly, the efficiency assessments and the comparisons of all the equipments (including the following system) measured in the past was conducted, and therefore, the one in which the greatest improvement could be made was found.
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