{"title":"对草酸铁辐射计的改进","authors":"K. C. Kurien","doi":"10.1039/J29710002081","DOIUrl":null,"url":null,"abstract":"When a solution of potassium ferrioxalate containing 0·02% of o-phenanthroline monohydrate and acetate buffer (final pH 3·7) is irradiated with 2537 and 3650 A light, the absorbance at 5100 A due to the formation of the ferrous o-phenanthroline complex has been found to increase linearly with dose. The suitability of this system as a more convenient chemical actinometer is discussed here.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"459 1","pages":"2081-2082"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"41","resultStr":"{\"title\":\"A modification to the ferrioxalate actinometer\",\"authors\":\"K. C. Kurien\",\"doi\":\"10.1039/J29710002081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"When a solution of potassium ferrioxalate containing 0·02% of o-phenanthroline monohydrate and acetate buffer (final pH 3·7) is irradiated with 2537 and 3650 A light, the absorbance at 5100 A due to the formation of the ferrous o-phenanthroline complex has been found to increase linearly with dose. The suitability of this system as a more convenient chemical actinometer is discussed here.\",\"PeriodicalId\":17268,\"journal\":{\"name\":\"Journal of The Chemical Society B: Physical Organic\",\"volume\":\"459 1\",\"pages\":\"2081-2082\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"41\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society B: Physical Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J29710002081\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710002081","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
When a solution of potassium ferrioxalate containing 0·02% of o-phenanthroline monohydrate and acetate buffer (final pH 3·7) is irradiated with 2537 and 3650 A light, the absorbance at 5100 A due to the formation of the ferrous o-phenanthroline complex has been found to increase linearly with dose. The suitability of this system as a more convenient chemical actinometer is discussed here.