门东植物活性炭作为H2S和NO2气体吸附剂的初步研究

S. Saputro, Rizka Fauzia Hanif, Inung Widyastuti, L. Mahardiani
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引用次数: 0

摘要

采用活性炭对尾气中H2S和NO2气体进行了处理研究。本研究以门洞毛蚶为原料制备活性炭,采用浓度为2.5的氯化锌(ZnCl2)对活性炭进行活化;5;7.5;10% w/v,测定H2S吸附效率。门东炭是用改良的工具加工而成的。用ZnCl2活化剂(w/v)浸渍24小时活化。紫外-可见分光光度法分析了其对H2S和NO2的吸附。用蓝亚甲基法测定H2S气体1小时后,门东活性炭在浓度为2.5% ZnCl2 w/v时效果最好,H2S去除率为80%。采用浓度为2.5% ZnCl2 w/v的门东活性炭吸附NO2。采用Griess Saltzman法吸附NO2气体1小时。结果表明,当HNO3浓度为1.5 M(0.057µg/mL)时,吸附NO2气体的浓度最大;NO2的吸附效率为28%。
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Utilization of Mendong Plants-Activated Charcoal as H2S and NO2 Gas Adsorbent: Preliminary Study
The study of exhaust H2S and NO2 gases using activated carbon has been conducted. In this study, activated carbon was prepared from mendong plant (Frimbistylis umbellaris), which was activated using zinc chloride (ZnCl2) with concentrations of 2.5; 5; 7.5; and 10 % w/v to determine the efficiency of H2S adsorption. Mendong charcoal was obtained from the process of using a modified tool. Activation was done by maceration using ZnCl2 activator (w/v) for 24 hours. The adsorption of H2S and NO2 was analyzed using UV-Vis spectrophotometry. Determinations of H2S gas carried out using the blue methylene’s method for 1 hour showed the highest effectiveness of mendong activated carbon was of that at the concentration of 2.5 % ZnCl2 w/v with 80% of H2S removal. Further, the mendong activated carbon with the concentration of 2.5% ZnCl2 w/v was used for NO2 adsorption. The adsorption of NO2 gas was conducted for 1 hour using Griess Saltzman’s method. The result showed that the largest concentration of NO2 gas was adsorbed when the HNO3 concentration was 1.5 M (0.057 µg/mL). The percentage of NO2 efficiency adsorbed was at 28%.
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