Huu Son Ta, K. Van, Thu Thuy Luong Thi, Thanh Hoa Ha
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引用次数: 1
摘要
在100 ~ 250 mg L -1苯酚初始浓度范围和10 ~ 40℃温度范围内,研究了咖啡壳氢氧化钾(KOH)活化活性炭(ACs)在650℃和750℃条件下对苯酚的吸附动力学。采用拟一级、拟二级和Elovich模型评价了苯酚吸附动力学模型。采用Reichenberg、Boyd、Weber和Morris模型研究了吸附机理。结果表明,咖啡壳活性炭的吸附速度为0.130 ~ 0.977 min -1,吸附速率为k2q - e。吸附过程主要是物理吸附和化学吸附,整个吸附过程不仅受颗粒内扩散控制,还受孔隙扩散控制。
Kinetic studies on the adsorption of phenol from aqueous solution by coffee husk activated carbon
The kinetics of phenol adsorption from aqueous solution on activated carbons (ACs) obtained from coffee husk by potassium Hydroxide (KOH) activation at 650 and 750 o C have been studied in the range of 100-250 mg L -1 initial phenol concentrations and at the temperatures range of 10 – 40 o C. Kinetic models for phenol adsorption were evaluated using pseudo-first-order, pseudo-second-order, and Elovich models. The adsorption mechanism was investigated using Reichenberg, Boyd, and Weber and Morris models. The adsorption on coffee husk activated carbon was found to be a fast or speedy process with the adsorption rate, k 2 q e , in the range of 0.130 to 0.977 min -1 . The adsorption process was mainly physical and promoted by chemical sorption and controlled not only by intra-particle diffusion but also by pore diffusion throughout the entire adsorption period.