硅催化铑钴碱金属催化的二氧化碳氢化反应

仁 草間, 裕則 荒川
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引用次数: 1

摘要

在碱金属(Li、Na和K)的催化下,用硅负载的Rh-Co催化剂(Rh-Co - m /SiO2)对CO2进行加氢。在Rh-Co (1:1)/SiO2大于5 wt%的条件下,Na是三种碱金属中生成乙醇最有效的添加剂。Na的加入量影响产物的选择性和CO2的转化率。在5% Rh-Co-Na (1:1: 0.5)/SiO2催化剂上,乙醇选择性最高。通过原位FT-IR观察,探讨了Na添加量对反应促进作用的机理。Na添加量的变化使Rh2 - (CO)3与桥接型吸附CO的比例变为线性型。这说明Na的加入量影响了Rh-Co /SiO2催化剂的加氢能力,导致了催化剂的CO2加氢活性的差异。
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シリカ担持ロジウム‐コバルト‐アルカリ金属触媒を用いた二酸化炭素の水素化反応
CO2 hydrogenation was carried out over alkali metals such as Li, Na and K promoted silica-supported Rh–Co catalysts (Rh–Co–M/SiO2). Na additive was most effective of the three alkali metals for ethanol formation over 5 wt% Rh–Co(1 : 1)/SiO2. The added amount of Na influenced product selectivity as well as CO2 conversion. The highest ethanol selectivity was obtained over 5 wt% Rh–Co–Na (1 : 1 : 0.5)/SiO2 catalyst. The mechanism of promotion effect of Na added amount was investigated by means of in situ FT-IR observation during reaction. The variation of Na added amount changed the ratio of Rh2–(CO)3 and bridged type adsorbed CO species to linear type one. This finding suggested that the amount of Na affected on the hydrogenation ability of Rh–Co/SiO2 catalysts, leading to the difference in CO2 hydrogenation activity.
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