{"title":"n -杂环碳——有机金属催化的革命性转折点","authors":"Ishita Asrani, Anita Tanwar","doi":"10.1063/1.5122631","DOIUrl":null,"url":null,"abstract":"The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.","PeriodicalId":7262,"journal":{"name":"ADVANCES IN BASIC SCIENCE (ICABS 2019)","volume":"135 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"N-heterocyclic carbenes-A revolutionary turning point in organometallic catalysis\",\"authors\":\"Ishita Asrani, Anita Tanwar\",\"doi\":\"10.1063/1.5122631\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.\",\"PeriodicalId\":7262,\"journal\":{\"name\":\"ADVANCES IN BASIC SCIENCE (ICABS 2019)\",\"volume\":\"135 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-08-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ADVANCES IN BASIC SCIENCE (ICABS 2019)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1063/1.5122631\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ADVANCES IN BASIC SCIENCE (ICABS 2019)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/1.5122631","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
n -杂环羰基化合物以其优异的稳定性和独特的性质成为金属有机配位化学和无机配位化学中的通用配体。它们是这些天科学家们感兴趣的主要话题。由于具有很强的供电子能力,它们被认为是传统膦配体中最有吸引力的替代品。它们在有机转化中也有广泛的应用。事实上,没有比nhc -钌配合物更适合烯烃复分解的催化剂了。随着NHCs的出现,有机金属催化的一个革命性转折点正在出现。n -杂环羰基化合物以其优异的稳定性和独特的性质成为金属有机配位化学和无机配位化学中的通用配体。它们是这些天科学家们感兴趣的主要话题。由于具有很强的供电子能力,它们被认为是传统膦配体中最有吸引力的替代品。它们在有机转化中也有广泛的应用。事实上,没有比nhc -钌配合物更适合烯烃复分解的催化剂了。随着NHCs的出现,有机金属催化的一个革命性转折点正在出现。
N-heterocyclic carbenes-A revolutionary turning point in organometallic catalysis
The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.