D. Sahu, D. P. Bisen, N. Brahme, Kanchan Tiwari, Aastha Sahu
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引用次数: 0
摘要
本文采用固相反应方法,在高温下成功合成了Eu3+掺杂的荧光粉Li4SrCa(SiO4)2。结构表征采用x射线衍射(XRD)确定。利用场发射扫描电镜(FESEM)分析了表面形貌。EDX光谱证实了Li4SrCa(SiO4)2:Eu3+荧光粉中存在的元素。Li4SrCa(SiO4)2:Eu3+荧光粉的光致发光光谱在220 ~ 450nm范围内被有效激发,在395nm激发下荧光粉表现出良好的光致发光强度,在591nm和619nm处分别由于4D0-7F1和4D0-7F2跃迁而出现橘红色的光致发光峰。计算了CIE (Commission International del’Eclairage)颜色坐标,确认了Eu3+掺杂荧光粉的CIE值为(x=0.6259, y=0.3737)。该荧光粉被认为是一种具有较好应用前景的橙红色发光荧光粉。这种荧光粉可用于固态照明。
Structural, Compositional and Photoluminescence Studies of Li4SrCa(SiO4)2: Eu3+ Red Phosphor Synthesized by Solid State Reaction Method
In this paper, Eu3+ doped phosphor Li4SrCa(SiO4)2 is successfully synthesized via a solid-state reaction method at high temperatures. Structure characterization is determined using X-ray diffraction (XRD). Surface morphology was analyzed using Field emission scanning electron microscopy(FESEM). The EDX spectra confirm the elements present in Li4SrCa(SiO4)2:Eu3+ phosphor. Photoluminescence(PL) spectra of Li4SrCa(SiO4)2:Eu3+ phosphor was efficiently excited by UV range 220-450nm and under the excitation 395nm phosphors shows good intensity with an orange-red intense peak at 591nm and 619 nm was due to 4D0-7F1 and 4D0-7F2 transition respectively. Commission International del’ Eclairage (CIE) color coordinate was calculated, which confirms the Eu3+ doped phosphor with a CIE value of (x=0.6259, y=0.3737). This phosphor is considered to be a new promising orange-red emitting phosphor for WLEDs application. This phosphor may be used for solid-state lighting.