LDHs的特性、制备路线及冶金应用综述

M. Richetta
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引用次数: 3

摘要

层状双氢氧化物(LDH)的特殊性质逐渐引起了科学界的关注。LDH的主要特点是能够捕获阴离子(有机和无机)来构建不同的复合材料。这是由LDH的夹层结构实现的,类似于水镁石结构,由阴离子点缀的带正电荷的片层组成。几个遥远的领域,从医学到物理和工程,对LDH应用表现出兴趣。为了满足所有这些要求,我们花了很多精力来塑造氢氧化物的物理和化学性质,并“特别”地设计了分层的双氢氧化物,以满足不同的需求和用途。值得注意的是,在许多应用中,与冶金过程和产品有关的应用特别令人感兴趣。本文介绍了LDH的特点、主要制备路线,并结合作者的实验研究实例,综述了LDH在冶金方面的应用。
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Characteristics, Preparation Routes and Metallurgical Applications of LDHs: An Overview
The peculiar properties of layered Double Hydroxides (LDH) have progressively drawn the attention of the scientific community. The main characteristic of LDH is the ability to capture anionic species (organic and inorganic) to build different composites. This is made possible by the sandwich structure of the LDH, similar to the brucite architecture, made up of positive charged lamellas interspersed by anions. Several distant fields, ranging from medicine to physics and engineering, exhibit interest in LDH applications. To satisfy all those requirements, energy was spent to sculpt LDHs physical and chemical properties and for designing layered double hydroxides “ad hoc” for different needs and employments. Notably, among the many applications, those related to metallurgical processes and products are of particular interest. This paper presents the characteristics, the main preparation routes and reviews the applications of LDH to metallurgy with some examples taken from the experimental research of the author.
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