Alexander I. Lebedev, I. Sluchinskaya, V. N. Demin, I. Munro
{"title":"强局部应力诱发GeTe中Pb、Sn杂质偏离中心","authors":"Alexander I. Lebedev, I. Sluchinskaya, V. N. Demin, I. Munro","doi":"10.1051/JP4:19972172","DOIUrl":null,"url":null,"abstract":"Noncentrality of large impurity atoms—Pb and Sn atoms—substituting for Ge atoms in a GeTe lattice has been discovered by means of EXAFS investigations in Ge0.9Pb0.1Te and Ge0.85Sn0.15Te samples. The transition of impurity atoms into a noncentral position under conditions of a strong local stress is explained by the participation of an unshared electron pair from the impurity atoms in the formation of the chemical bond.","PeriodicalId":15816,"journal":{"name":"Journal of Experimental and Theoretical Physics Letters","volume":"247 1","pages":"635-638"},"PeriodicalIF":0.0000,"publicationDate":"1996-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"23","resultStr":"{\"title\":\"Off-centering of Pb and Sn impurities in GeTe induced by strong local stress\",\"authors\":\"Alexander I. Lebedev, I. Sluchinskaya, V. N. Demin, I. Munro\",\"doi\":\"10.1051/JP4:19972172\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Noncentrality of large impurity atoms—Pb and Sn atoms—substituting for Ge atoms in a GeTe lattice has been discovered by means of EXAFS investigations in Ge0.9Pb0.1Te and Ge0.85Sn0.15Te samples. The transition of impurity atoms into a noncentral position under conditions of a strong local stress is explained by the participation of an unshared electron pair from the impurity atoms in the formation of the chemical bond.\",\"PeriodicalId\":15816,\"journal\":{\"name\":\"Journal of Experimental and Theoretical Physics Letters\",\"volume\":\"247 1\",\"pages\":\"635-638\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"23\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Experimental and Theoretical Physics Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1051/JP4:19972172\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Experimental and Theoretical Physics Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1051/JP4:19972172","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Off-centering of Pb and Sn impurities in GeTe induced by strong local stress
Noncentrality of large impurity atoms—Pb and Sn atoms—substituting for Ge atoms in a GeTe lattice has been discovered by means of EXAFS investigations in Ge0.9Pb0.1Te and Ge0.85Sn0.15Te samples. The transition of impurity atoms into a noncentral position under conditions of a strong local stress is explained by the participation of an unshared electron pair from the impurity atoms in the formation of the chemical bond.