NH4NO3颗粒改性中、大孔生成过程:热力学机制对颗粒结构的影响

A. Artyukhov, A. Ivaniia, A. Voznyi
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引用次数: 0

摘要

本文论述了在涡流造粒机中制备多孔硝酸铵的最佳热力学条件选择的合理性。通过加湿和进一步的热处理,证明了颗粒改性的优点。指出了改进多孔硝酸铵制备工艺的必要性,目的是在颗粒表面和颗粒内部形成中孔和大孔。研究了不同热处理条件下颗粒的内部和表面结构。实验研究结果可以确定在适当的时间内,涡流造粒机工作区内传热剂的温度,并利用该指标计算加热动力学和颗粒脱水。传热剂的温度指数规格允许进行计算,确定颗粒干燥的最短时间,以避免其意外过热和堆芯破坏。
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The meso- and macropores generating process via modification of NH4NO3 granules: Thermodynamic regime impact on the granule structure
The article deals with justification to choose optimal thermodynamic condiions to generate porous ammonium nitrate in the vortex granulators. Advantages of granules modification are justified by way of humidification and further thermal treatment. The necessity to improve technologies for porous ammonium nitrate generation is shown with aim to form meso- and macropores on the surface of the granule and inside it. The internal and surface structure of granules is studied under different thermal treatment regimes. The results of experimental research allow to define the temperature of heat transfer agent in the working area of the vortex granulator during the proper time and to implement this index to calculate heating up kinetics and granule dehydration. Specification of the heat transfer agent's temperature index lets to perform computations, determining minimum time for granule drying, in order to avoid its unintended overheating and core destruction.
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