1,2,5-噻二唑和2,1,3-苯并噻唑的合成研究进展

IF 2.2 4区 化学 Q2 CHEMISTRY, ORGANIC Synthesis-Stuttgart Pub Date : 2019-09-23 DOI:10.1055/s-0039-1690679
O. Rakitin
{"title":"1,2,5-噻二唑和2,1,3-苯并噻唑的合成研究进展","authors":"O. Rakitin","doi":"10.1055/s-0039-1690679","DOIUrl":null,"url":null,"abstract":"Abstract The fast-growing interest in 1,2,5-thiadiazoles and their fused analogues including 2,1,3-benzothiadiazoles in recent years as important compounds in materials science and biomedicine has led to great progress in the synthesis of these heterocyclic systems. In this short review, the development of known procedures together with novel reactions is covered. New starting materials, unknown and unexpected transformations for the construction of the thiadiazole ring are emphasized. 1 Introduction 2 Synthesis of Monocyclic 1,2,5-Thiadiazoles 2.1 From 1,2-Diamines, vic-Dioximes and Related Compounds 2.2 From Alkyl Aryl (Hetaryl) Ketoximes and Tetrasulfur Tetranitride 2.3 By Condensation Reactions 2.4 From Other Heterocycles 3 Synthesis of Fused 1,2,5-Thiadiazoles 3.1 From ortho-Phenylenediamines and Related Compounds 3.2 From ortho-Aminonitroso and ortho-Aminonitro Derivatives 3.3 By Condensation Reactions 3.4 By Chalcogen Exchange in 1,2,5-Oxa- and 1,2,5-Selenadiazoles 3.5 Miscellaneous Methods 4 Conclusions","PeriodicalId":49451,"journal":{"name":"Synthesis-Stuttgart","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2019-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"20","resultStr":"{\"title\":\"Recent Developments in the Synthesis of 1,2,5-Thiadiazoles and 2,1,3-Benzothiadiazoles\",\"authors\":\"O. Rakitin\",\"doi\":\"10.1055/s-0039-1690679\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The fast-growing interest in 1,2,5-thiadiazoles and their fused analogues including 2,1,3-benzothiadiazoles in recent years as important compounds in materials science and biomedicine has led to great progress in the synthesis of these heterocyclic systems. In this short review, the development of known procedures together with novel reactions is covered. New starting materials, unknown and unexpected transformations for the construction of the thiadiazole ring are emphasized. 1 Introduction 2 Synthesis of Monocyclic 1,2,5-Thiadiazoles 2.1 From 1,2-Diamines, vic-Dioximes and Related Compounds 2.2 From Alkyl Aryl (Hetaryl) Ketoximes and Tetrasulfur Tetranitride 2.3 By Condensation Reactions 2.4 From Other Heterocycles 3 Synthesis of Fused 1,2,5-Thiadiazoles 3.1 From ortho-Phenylenediamines and Related Compounds 3.2 From ortho-Aminonitroso and ortho-Aminonitro Derivatives 3.3 By Condensation Reactions 3.4 By Chalcogen Exchange in 1,2,5-Oxa- and 1,2,5-Selenadiazoles 3.5 Miscellaneous Methods 4 Conclusions\",\"PeriodicalId\":49451,\"journal\":{\"name\":\"Synthesis-Stuttgart\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2019-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis-Stuttgart\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1055/s-0039-1690679\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis-Stuttgart","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1055/s-0039-1690679","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 20

摘要

近年来,1,2,5-噻二唑及其融合类似物(包括2,1,3-苯并噻唑)作为材料科学和生物医学领域的重要化合物,引起了人们对其快速发展的兴趣,使得这些杂环体系的合成取得了很大进展。在这篇简短的综述中,已知程序的发展以及新的反应被涵盖。强调了新的起始材料,未知的和意想不到的转变,以构建噻二唑环。1绪论2单环1,2,5-噻二唑的合成维二肟及其相关化合物2.2烷基芳基(己基)酮肟和四氮化四硫代化合物2.3缩合反应2.4其他杂环化合物3缩合合成1,2,5-噻二唑3.1邻苯二胺及其相关化合物3.2邻氨基硝基和邻氨基硝基衍生物3.3缩合反应3.4 1,2,5-氧二唑和1,2,5-硒二唑的硫交换法3.5杂项方法4结论
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Recent Developments in the Synthesis of 1,2,5-Thiadiazoles and 2,1,3-Benzothiadiazoles
Abstract The fast-growing interest in 1,2,5-thiadiazoles and their fused analogues including 2,1,3-benzothiadiazoles in recent years as important compounds in materials science and biomedicine has led to great progress in the synthesis of these heterocyclic systems. In this short review, the development of known procedures together with novel reactions is covered. New starting materials, unknown and unexpected transformations for the construction of the thiadiazole ring are emphasized. 1 Introduction 2 Synthesis of Monocyclic 1,2,5-Thiadiazoles 2.1 From 1,2-Diamines, vic-Dioximes and Related Compounds 2.2 From Alkyl Aryl (Hetaryl) Ketoximes and Tetrasulfur Tetranitride 2.3 By Condensation Reactions 2.4 From Other Heterocycles 3 Synthesis of Fused 1,2,5-Thiadiazoles 3.1 From ortho-Phenylenediamines and Related Compounds 3.2 From ortho-Aminonitroso and ortho-Aminonitro Derivatives 3.3 By Condensation Reactions 3.4 By Chalcogen Exchange in 1,2,5-Oxa- and 1,2,5-Selenadiazoles 3.5 Miscellaneous Methods 4 Conclusions
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Synthesis-Stuttgart
Synthesis-Stuttgart 化学-有机化学
CiteScore
4.50
自引率
7.70%
发文量
435
审稿时长
1 months
期刊介绍: SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.
期刊最新文献
Dealkenylative Functionalizations: Conversion of Alkene C(sp3)-C(sp2) Bonds into C(sp3)-X Bonds via Redox-Based Radical Processes. Aryl Annulation: A Powerful Simplifying Retrosynthetic Disconnection. Improved Syntheses of an Arseno-Fatty Acid (As-FA 362) and an Arseno-Hydrocarbon (As-HC 444). SYNFORM ISSUE 2023/12 Linked PDF of Table of Contents
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1