新型储氢材料的研制

E. Titus, G. Cabral, J. C. Madaleno, M. Coelho, T. Shokuhfar, J. Gracio
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引用次数: 0

摘要

聚合物与碳纳米管的纳米复合材料是目前储氢研究的热点和发展方向。制备纳米复合材料时,碳纳米管在聚合物基体中的分散是一个重要的问题。原位聚合是一种较好的制备均相聚合物碳纳米管复合材料的方法。然而,碳纳米管在单体溶液中的分散仍然存在问题。本文报道了一种将多壁(MW)碳纳米管直接分散到聚苯胺(PANI)/乙醇溶液中,并在镍催化剂的辅助下制备聚苯胺/MWCNT均匀复合材料的新方法。首次成功地证明了制备同时保留聚苯胺和碳纳米管结构的均匀聚苯胺/碳纳米管悬浮液的可能性。
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Development of a novel material for hydrogen storage
Nanocomposites of polymer and carbon nanotubes (CNTs) are fascinating and progressing area of hydrogen storage research. The dispersion of the CNTs in polymer matrices is an important issue while making the nanocomposites. In-situ polymerization is a better approach for synthesizing homogeneous polymer CNT composites. However, the dispersion of CNT in the monomer solution is still problematic. In this paper, we report a novel approach for dispersing multiwalled (MW) CNTs directly into polyaniline (PANI)/ ethyl alcohol solution and preparation of uniform composite of PANI/MWCNT with the aid of nickel catalyst. The possibility of the preparation of uniform PANI/CNT suspension retaining the structure of both PANI and CNT is successfully demonstrated for the first time.
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