非金属掺杂对二氧化钛纳米材料光催化降解的改进

F. Ak Azem, I. Birlik, Ö. Keski̇n, Tulay Koc Delice
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摘要

半导体光催化是一种利用阳光启动化学反应的过程。为了充分利用半导体的光催化特性,获得更好的性能,需要对结构进行调整。在本研究中,采用溶胶-凝胶法使用不同数量的氮修饰TiO2纳米结构。利用x射线衍射(XRD)技术对合成的TiO2纳米结构进行了晶体结构研究。利用x射线光电子能谱(XPS)分析了纳米材料的元素组成。XPS分析证实,二氧化钛的晶格中引入了氮。通过紫外光催化降解亚甲基蓝(MB)来评价样品的光催化性能。为了评估降解,使用紫外-可见分光光度计测量了MB随时间的吸收。结果表明,掺杂工艺可以提高TiO2的光催化性能,0.2% N掺杂的TiO2纳米结构对光催化降解MB表现出优异的光催化活性。
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Improvement of Photocatalytic Degradation of Titanium Dioxide Nanomaterials by Non-metal Doping
Semiconductor photocatalysis is a process that benefits from sunlight to start chemical reactions. In order to take advantage photocatalytic properties of semiconductors and to achieve better performance structural adjustment is needed. In this study, varying amounts of nitrogen were used to modify TiO2 nanostructures using the sol-gel method. The crystalline structure of the synthesized TiO2 nanostructures was studied using the X-ray diffraction (XRD) technique. X-ray photoelectron spectroscopy (XPS) was conducted to analyse the elemental composition of nanomaterials. XPS analyze confirms that nitrogen is introduced into the lattice of TiO2. The photocatalytic degradation of methylene blue (MB) under UV irradiation was employed to assess the photocatalytic performance of the samples. To evaluate degradation, the absorption of MB over time was measured using a UV-Vis spectrophotometer. As a result, the doping process has been found to improve the photocatalytic performance of TiO2, and 0.2% N doped TiO2 nanostructures demonstrated superior photocatalytic activity for photocatalytic degradation of MB.
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