2020年,在北纬80°的春季,平流层臭氧消耗达到创纪录水平

R. Alwarda, K. Bognar, K. Strong, M. Chipperfield, S. Dhomse, J. Drummond, W. Feng, V. Fioletov, F. Goutail, Beatriz Herrera, G. Manney, E. McCullough, L. Millán, A. Pazmino, K. Walker, T. Wizenberg, Xiaoyi Zhao
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引用次数: 1

摘要

2019-2020年北极冬季的特征是异常持续的极地涡旋和平流层下层温度始终低于极地平流层云(PSCs)形成的阈值。这些条件导致的臭氧损失堪比南极臭氧空洞。位于加拿大尤里卡(Eureka)的极地环境大气研究实验室(PEARL)的一套地面测量仪器(80.05°N, 86.42°W)被用于调查化学臭氧消耗。涡旋在尤里卡上空停留的时间比过去20年数据集中的任何一年都长,激光雷达测量提供了尤里卡上空极地平流层云(PSCs)的证据。此外,紫外-可见天顶-天空差分光学吸收光谱(DOAS)测量显示,在20年的数据集中,臭氧损失达到了创纪录的水平,反硝化的证据伴随着春季NO2的最慢增长,以及反应性卤素物质(OClO和BrO)的增强。傅里叶变换红外(FTIR)光谱仪对HCl和ClONO2(氯储层物质)的补充测量显示,与2011年相比,色谱柱异常低,前一年化学臭氧消耗显著。FTIR数据集中记录的低HNO3值与psc和反硝化大气的证据相一致。化学臭氧损失的估计是使用来自SLIMCAT离线化学传输模式的被动臭氧得出的,以解释平流层臭氧收支的动力贡献。
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Record springtime stratospheric ozone depletion at 80°N in 2020

The Arctic winter of 2019-2020 was characterized by an unusually persistent polar vortex and temperatures in the lower stratosphere that were consistently below the threshold for the formation of polar stratospheric clouds (PSCs). These conditions led to ozone loss that is comparable to the Antarctic ozone hole. Ground-based measurements from a suite of instruments at the Polar Environment Atmospheric Research Laboratory (PEARL) in Eureka, Canada (80.05°N, 86.42°W) were used to investigate chemical ozone depletion. The vortex was located above Eureka longer than in any previous year in the 20-year dataset and lidar measurements provided evidence of polar stratospheric clouds (PSCs) above Eureka. Additionally, UV-visible zenith-sky Differential Optical Absorption Spectroscopy (DOAS) measurements showed record ozone loss in the 20-year dataset, evidence of denitrification along with the slowest increase of NO2 during spring, as well as enhanced reactive halogen species (OClO and BrO). Complementary measurements of HCl and ClONO2 (chlorine reservoir species) from a Fourier transform infrared (FTIR) spectrometer showed unusually low columns that were comparable to 2011, the previous year with significant chemical ozone depletion. Record low values of HNO3 in the FTIR dataset are in accordance with the evidence of PSCs and a denitrified atmosphere. Estimates of chemical ozone loss were derived using passive ozone from the SLIMCAT offline chemical transport model to account for dynamical contributions to the stratospheric ozone budget.

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