PLD法制备sn1 - xmnxo2薄膜的合成及结构性能表征

V. Rathore, S. Prakash, Priyanka Gupta, M. Rathore, R. Rawat, R. Choudhary, D. Phase
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引用次数: 2

摘要

本文报道了脉冲激光沉积法在Si衬底(011)上制备的纯和Mn掺杂SnO2薄膜的微观结构特性。沉积时衬底温度保持在600℃,固相反应法制备靶材,Sn1-xMnxO2薄膜的掺杂浓度保持在0.5%。x射线衍射表征表明,未掺杂和掺杂的薄膜本质上是结晶的。原子力显微镜(AFM)结果表明,Mn(0.5%)掺杂SnO2的RMS粗糙度值为8.36 nm,平均粗糙度值为6.60 nm,晶粒尺寸为115 nm。其中,纯SnO2的RMS粗糙度值为9.74 nm,粗糙度平均值为7.64 nm,晶粒尺寸为120 nm。与Mn掺杂SnO2薄膜相比,纯SnO2薄膜的粗糙度高,晶粒尺寸大。Sn1-xMnxO2薄膜的粒径、晶格常数和晶体结构等参数随着掺杂浓度的增加而减小。本文报道了脉冲激光沉积法在Si衬底(011)上制备的纯和Mn掺杂SnO2薄膜的微观结构特性。沉积时衬底温度保持在600℃,固相反应法制备靶材,Sn1-xMnxO2薄膜的掺杂浓度保持在0.5%。x射线衍射表征表明,未掺杂和掺杂的薄膜本质上是结晶的。原子力显微镜(AFM)结果表明,Mn(0.5%)掺杂SnO2的RMS粗糙度值为8.36 nm,平均粗糙度值为6.60 nm,晶粒尺寸为115 nm。其中,纯SnO2的RMS粗糙度值为9.74 nm,粗糙度平均值为7.64 nm,晶粒尺寸为120 nm。与Mn掺杂SnO2薄膜相比,纯SnO2薄膜的粗糙度高,晶粒尺寸大。Sn1-xMnxO2薄膜的粒径、晶格常数和晶体结构等参数随着掺杂浓度的增加而减小。
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Synthesis and characterization of structural properties of Sn1-xMnxO2Thin films prepared by PLD
We have reported on the micro-structural properties of pure and Mn doped SnO2 thin films deposited on Si substrate (011) by pulsed laser deposition. Substrate temperature during deposition was kept at 600° C. Target was prepared by solid-state reaction method and doping concentration was kept 0.5% for Sn1-xMnxO2 thin films. X-ray diffraction characterization showed that the undoped and doped films are crystalline in nature. Atomic Force Microscope (AFM) results shows that Mn (0.5%) doped SnO2 the RMS roughness value is 8.36 nm, average roughness 6.60 nm and grain size is 115 nm. Where in pure SnO2 the RMS roughness value is 9.74 nm, roughness average 7.64 nm and grain size is 120 nm. Pure SnO2 thin films are of high roghness with larger grain size as compared to Mn doped SnO2 films. Parameters particle size, lattice constant and crystalline structure of Sn1-xMnxO2 thin films have found to decrease with the doping concentration.We have reported on the micro-structural properties of pure and Mn doped SnO2 thin films deposited on Si substrate (011) by pulsed laser deposition. Substrate temperature during deposition was kept at 600° C. Target was prepared by solid-state reaction method and doping concentration was kept 0.5% for Sn1-xMnxO2 thin films. X-ray diffraction characterization showed that the undoped and doped films are crystalline in nature. Atomic Force Microscope (AFM) results shows that Mn (0.5%) doped SnO2 the RMS roughness value is 8.36 nm, average roughness 6.60 nm and grain size is 115 nm. Where in pure SnO2 the RMS roughness value is 9.74 nm, roughness average 7.64 nm and grain size is 120 nm. Pure SnO2 thin films are of high roghness with larger grain size as compared to Mn doped SnO2 films. Parameters particle size, lattice constant and crystalline structure of Sn1-xMnxO2 thin films have found to decrease with the doping concentration.
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