生物柴油生产:生物技术方法

John Posada, C. Cardona, C. Orrego
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引用次数: 11

摘要

发酵用于将糖、淀粉或其他具有活细胞的底物等原料转化为更复杂的靶产品,如醇、酮、维生素、抗生素、氨基酸或通常是非手性有机分子。生物柴油与甘油通过酯交换反应制备,酯交换反应可通过化学催化或生物催化两种方式进行。其中,不可再生油中的甲醇是使用最多的原料。化学催化存在脂肪酸碱性盐(皂)生成、甘油回收困难、工艺耗能大、使用碱性催化剂或使用催化酸反应温度高、反应时间长等缺点。生物催化方法-全细胞或酶-位于发酵过程和汽油化学之间的界面。本文综述了生物柴油的生物催化过程,并分析了甘油(生物柴油生产的副产品)转化为乙醇(生物柴油生产中潜在的重要原料)和其他生物转化产品的生物技术
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Biodiesel Production: Biotechnological Approach
Fermentation is used to transform raw materials such as sugar, starch or other substrates with living cells to more complex target products such as alcohols, ketones, vitamins, antibiotics, amino acids or often achiral organic molecules. Biodiesel together with glycerol are produced by transesterification process, which can be carried out by two ways, chemically catalyzed or biocatalytically. Where, methanol from non-renewable oil is the most used raw material. Chemical catalysis has several drawbacks as fatty acid alkaline salts (soaps) generation, difficult glycerol recovering, energetically intensive process, using alkaline catalysts or elevated reaction temperatures and high reaction times using catalysis acid. Biocatalytic approach -whole-cell or enzymatic- is located at the interface between fermentation processes and petrol-based chemistry. This work reviews the biodiesel production through biocatalytic process, and analyzes the biotechnological transformation of glycerol (by product of biodiesel production) to ethanol (a potentially important raw material in biodiesel production), and other bioconversion products
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