用于石材保护的偏高岭土聚合物:碱活化的初步结果

Q2 Earth and Planetary Sciences Advances in Geosciences Pub Date : 2023-01-27 DOI:10.5194/adgeo-58-149-2023
Sophie van Roosmale, T. De Kock, J. Blom
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引用次数: 1

摘要

摘要地聚合物是一种无机的、通用的替代粘合剂。它们的存在范围很广,从像砂浆一样的材料到像陶瓷一样的材料。这使得它们成为修复迫击炮的潜在创新选择。在本研究中,以偏高岭土为基础的地聚合物的活化在石头保护的背景下进行了探索。进行了一组反应性测试,以评估活化剂及其与石灰基粘合剂的相容性。结合低比例的泥灰石粉、石灰石粉和石英砂的标准化骨料,研究了粘结剂的物理化学性能。由于孔径较小,最有希望的混合物吸水速度相对较慢。与文献中含有聚集体的地聚合物相比,样品具有较高的开孔率,因此密度较低,但结果与没有聚集体的地聚合物相当。抗压强度与目前使用的修补砂浆相当。本研究表明,偏高岭土与石灰基粘结剂可作为石材修补砂浆的替代粘结剂。
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Metakaolin-based geopolymers for stone conservation: preliminary results on alkaline activation
Abstract. Geopolymers are inorganic and versatile alternative binder. They exist in a wide range, varying from a material which behaves like mortars to a material with properties like ceramics. This makes them a potentially innovative alternative to repair mortars. In this research the activation of metakaolin-based geopolymers is explored in the context of stone conservation. A set of reactivity tests are performed to evaluate activators and compatibility with a lime-based binder. The physico-chemical properties of the binder are investigated, in combination with low proportions of standardized aggregates of marl powder, limestone powder and quartz sand. The most promising mixtures absorb water relatively slowly due to the relative small pore sizes. The samples have a high open porosity and therefore a lower density when compared to results found in literature from geopolymers with aggregate, but the results are comparable to geopolymers without aggregates. The compressive strength is comparable to currently used repair mortars. This study shows that metakaolin with lime-based binders could be investigated in the future as alternative binder in stone repair mortars.
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来源期刊
Advances in Geosciences
Advances in Geosciences Earth and Planetary Sciences-Earth and Planetary Sciences (miscellaneous)
CiteScore
3.70
自引率
0.00%
发文量
16
审稿时长
30 weeks
期刊介绍: Advances in Geosciences (ADGEO) is an international, interdisciplinary journal for fast publication of collections of short, but self-contained communications in the Earth, planetary and solar system sciences, published in separate volumes online with the option of a publication on paper (print-on-demand). The collections may include papers presented at scientific meetings (proceedings) or articles on a well defined topic compiled by individual editors or organizations (special publications). The evaluation of the manuscript is organized by Guest-Editors, i.e. either by the conveners of a session of a conference or by the organizers of a meeting or workshop or by editors appointed otherwise, and their chosen referees.
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