添加和不添加葡萄糖基添加剂锡镀层的电化学研究与表征

S. Cherrouf, Y. Salhi, Amina El Echhab, Hassan El Grini, Jihane Tellal, M. Cherkaoui, B. Lakhrissi
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引用次数: 0

摘要

在酸性介质中加入双糖苯并咪唑酮,在普通钢基体上电解制备锡涂层。采用固定极化、计时电位法和循环伏安法研究了pH保持在1.2±0.2时双糖苯并咪唑酮对锡涂层电化学性能的影响。这些研究表明阴极峰值电流明显减少,电势下降。随着添加剂浓度的增加,沉积速率也随之降低。SEM(扫描电镜)观察和XRD (x射线衍射)分析表明,在电解质中加入最佳浓度的双糖苯并咪唑酮(10-3M)后,镀层具有良好的镀层表面质量,构成了初步研究的继续。
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Electrochemical study and characterization of tin coatings with and without glucose-based additive
The tin coating was elaborated electrolytically on an ordinary steel substrate in SnSO4 based electrolyte in acid medium with additive (bis-glycobenzimidazolone) at ambient temperature. The pH is maintained at 1.2±0.2 Bis-glycobenzimidazolone influence on the electrochemical properties of the tin coating was investigated using stationary polarization, chronopotentiometry, and cyclic voltammetry techniques. These studies show an apparent decrease in cathodic peak current and a drop in potential. The deposition rate also decreases as the concentration of the additive increases.  SEM (Scanning Electron Microscopy) observation and XRD (X-ray Diffraction) analysis showed that the coating consists of good surface quality of the deposit elaborated by the addition of an optimal concentration of bis-glycobenzimidazolone (10-3M) in the electrolyte, which constitutes the continuation of a preliminary study.
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