{"title":"从二次聚合物原料中获得的广泛燃料馏分对金属的腐蚀作用研究","authors":"Andriy Borysovych Grigorov, Kyryl Volodymyrovych Shevchenko, Irina Valeriivna Sinkevich","doi":"10.20998/2079-0821.2020.02.10","DOIUrl":null,"url":null,"abstract":"A research of the corrosion effect on the metal (copper plate) of a broad fuel fraction (FPF) - a liquid product of thermal destruction of secondary raw materials made of low pressure polyethylene (LDPE) at temperatures up to 380 ° C and a pressure of 0,12-0,15 MPa. is conducted. Determination of the corrosion effect on the copper FFT plate was carried out in accordance with the standard ASTM D 130-10 at a temperature of 50 ° C for 120 minutes for both the dehydrated FFT sample and in the presence of 1% water. It was found that the copper plates, which were in the FFT and FFT + 1% water in the visual evaluation, had a light orange color, close to the color of the original plate. This, in turn, indicates that the investigated FFT samples have withstood the test, and the corrosive effect on the copper plate can be attributed to a slight fading, class 1.a. Also, together with the study under standard conditions, the corrosion effect on the copper plate of the products of combustion of FFT at different temperatures at which it was found that in the temperature range 180-230 ° C the surface of the copper plate becomes pale purple, and the corrosion effect on the copper plate can be attributed to moderate dimming, class 2.b; at temperatures of 230-290 ° the surface of the copper plate already has a silver color, and the corrosive effect on the copper plate corresponds to a moderate blackout, class 2.d. Therefore, when the combustion products of the FFT on the copper plate only oxygen corrosion occurs, which is due to the presence of oxygen in the area of the copper plate and the temperature of the combustion products. Thus, it was concluded that there is no corrosive elements in the FFT, which makes it suitable for use as a cheap component of motor, furnace and boiler fuels, improving their performance (e.g., reducing sulfur content).","PeriodicalId":9407,"journal":{"name":"Bulletin of the National Technical University \"KhPI\". Series: Chemistry, Chemical Technology and Ecology","volume":"33 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"INVESTIGATION OF CORROSIVE EFFECT ON METAL OF A BROAD FUEL FRACTION OBTAINED FROM SECONDARY POLYMER RAW MATERIAL\",\"authors\":\"Andriy Borysovych Grigorov, Kyryl Volodymyrovych Shevchenko, Irina Valeriivna Sinkevich\",\"doi\":\"10.20998/2079-0821.2020.02.10\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A research of the corrosion effect on the metal (copper plate) of a broad fuel fraction (FPF) - a liquid product of thermal destruction of secondary raw materials made of low pressure polyethylene (LDPE) at temperatures up to 380 ° C and a pressure of 0,12-0,15 MPa. is conducted. Determination of the corrosion effect on the copper FFT plate was carried out in accordance with the standard ASTM D 130-10 at a temperature of 50 ° C for 120 minutes for both the dehydrated FFT sample and in the presence of 1% water. It was found that the copper plates, which were in the FFT and FFT + 1% water in the visual evaluation, had a light orange color, close to the color of the original plate. This, in turn, indicates that the investigated FFT samples have withstood the test, and the corrosive effect on the copper plate can be attributed to a slight fading, class 1.a. Also, together with the study under standard conditions, the corrosion effect on the copper plate of the products of combustion of FFT at different temperatures at which it was found that in the temperature range 180-230 ° C the surface of the copper plate becomes pale purple, and the corrosion effect on the copper plate can be attributed to moderate dimming, class 2.b; at temperatures of 230-290 ° the surface of the copper plate already has a silver color, and the corrosive effect on the copper plate corresponds to a moderate blackout, class 2.d. Therefore, when the combustion products of the FFT on the copper plate only oxygen corrosion occurs, which is due to the presence of oxygen in the area of the copper plate and the temperature of the combustion products. Thus, it was concluded that there is no corrosive elements in the FFT, which makes it suitable for use as a cheap component of motor, furnace and boiler fuels, improving their performance (e.g., reducing sulfur content).\",\"PeriodicalId\":9407,\"journal\":{\"name\":\"Bulletin of the National Technical University \\\"KhPI\\\". Series: Chemistry, Chemical Technology and Ecology\",\"volume\":\"33 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of the National Technical University \\\"KhPI\\\". 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引用次数: 0
摘要
研究了一种由低压聚乙烯(LDPE)制成的二次原料在380°C的温度和0.12 - 0.15 MPa的压力下热破坏的液体产品——广义燃料馏分(FPF)对金属(铜板)的腐蚀效果。进行。根据标准ASTM D 130-10,在50°C的温度下,在脱水FFT样品和1%的水存在下,对铜FFT板的腐蚀效果进行了测定。在目测评价中发现,在FFT和FFT + 1%水中的铜板呈浅橙色,接近原板的颜色。反过来,这表明所研究的FFT样品经受住了测试,对铜板的腐蚀作用可以归因于轻微的褪色,1.a类。并结合标准条件下对FFT燃烧产物在不同温度下对铜板的腐蚀作用进行了研究,发现在180 ~ 230℃温度范围内,铜板表面呈淡紫色,对铜板的腐蚀作用可归因于中度变暗,2.b类;在230-290°的温度下,铜板表面已经呈银色,对铜板的腐蚀作用相当于中度停电,2.d类。因此,当FFT的燃烧产物在铜板上只发生氧腐蚀时,这是由于在铜板区域存在氧和燃烧产物的温度。因此,得出的结论是,FFT中不含腐蚀性元素,这使得它适合用作电机、炉子和锅炉燃料的廉价成分,从而改善其性能(例如,降低硫含量)。
INVESTIGATION OF CORROSIVE EFFECT ON METAL OF A BROAD FUEL FRACTION OBTAINED FROM SECONDARY POLYMER RAW MATERIAL
A research of the corrosion effect on the metal (copper plate) of a broad fuel fraction (FPF) - a liquid product of thermal destruction of secondary raw materials made of low pressure polyethylene (LDPE) at temperatures up to 380 ° C and a pressure of 0,12-0,15 MPa. is conducted. Determination of the corrosion effect on the copper FFT plate was carried out in accordance with the standard ASTM D 130-10 at a temperature of 50 ° C for 120 minutes for both the dehydrated FFT sample and in the presence of 1% water. It was found that the copper plates, which were in the FFT and FFT + 1% water in the visual evaluation, had a light orange color, close to the color of the original plate. This, in turn, indicates that the investigated FFT samples have withstood the test, and the corrosive effect on the copper plate can be attributed to a slight fading, class 1.a. Also, together with the study under standard conditions, the corrosion effect on the copper plate of the products of combustion of FFT at different temperatures at which it was found that in the temperature range 180-230 ° C the surface of the copper plate becomes pale purple, and the corrosion effect on the copper plate can be attributed to moderate dimming, class 2.b; at temperatures of 230-290 ° the surface of the copper plate already has a silver color, and the corrosive effect on the copper plate corresponds to a moderate blackout, class 2.d. Therefore, when the combustion products of the FFT on the copper plate only oxygen corrosion occurs, which is due to the presence of oxygen in the area of the copper plate and the temperature of the combustion products. Thus, it was concluded that there is no corrosive elements in the FFT, which makes it suitable for use as a cheap component of motor, furnace and boiler fuels, improving their performance (e.g., reducing sulfur content).