硅在土壤溶液中溶解度的控制因素

L. Anggria, H. Husnain, T. Masunaga
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引用次数: 1

摘要

二氧化硅是一种对水稻有益的元素,具有防治稻瘟病、提高茎秆强度、缓解非生物胁迫等作用。土壤溶液中的硅受pH、温度、有机质和氧化还原电位(Eh)等因素的影响。本研究旨在探讨硅在土壤溶液中溶解度的控制因素。本研究收集了日本产的硅胶(JSG)和Ultisols。在室内实验中,研究了Ca(钙)、Mg(镁)等对Si(二氧化硅)溶解度的影响。在浸水条件下,将10克含硅胶、Ca、Mg的土壤放入塑料管中,在300℃下培养29 d。土壤中分别施用5、10、15 Mg Ca L-1(T2、T3、T4)和5、10、15 Mg Mg L-1(T5、T6、T7)钙和Mg。有两个对照,分别是T0(土壤)和T1(土壤+硅胶)。在孵育期间,在第8、15和29天使用ICP光谱测量地表水中的Si、Ca、Mg、Fe和Mn浓度。结果表明:处理前土壤呈微酸性(pH 5.7),可提取Si浓度为267.1 mg SiO2 kg-1;水稻有效硅含量低于临界水平(300 mg SiO2 kg-1)。土壤溶液中Ca和Mg的总浓度分别以T4和T7处理最高。在培养的前8天,T1和T2处理释放到土壤溶液中的硅含量高于其他处理。Si在土壤溶液中的溶解度与Mn、Eh呈显著正相关,与pH呈显著负相关,表明它们是Si在土壤溶液中释放的控制因素。土壤溶液中Si与Ca、Mg浓度无相关性。
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THE CONTROLLING FACTORS OF SILICON SOLUBILITY IN SOIL SOLUTION
Silica is a beneficial element for rice plants which can protect from blast disease, increase stem strength, and alleviate abiotic stress. Silicon in soil solution is affected by several factors such as pH, temperature, organic matter, and redox potential (Eh). This study aims to investigate the controlling factor of Si solubility in soil solution. In the present study, Japanese silica gel (JSG) and Ultisols were collected from Japan. In laboratory experiment, the effects of Ca (calcium), Mg (magnesium) and others on solubility of Si (silica) were investigated. Under submerged condition, ten gram of soil with silica gel, Ca and Mg in plastic tube were incubated at 300C for 29 days. Calcium and Mg were applied into soil, at the concentration of 5, 10, 15 mg Ca L-1(T2, T3, T4 respectively) and 5, 10, 15 mg Mg L-1(T5, T6, T7 respectively). There was two controls as a follow T0 (soil) and T1 (soil + silica gel). During incubation, Si, Ca, Mg, Fe, and Mn concentrations in surface water were measured using ICP spectroscopy at day 8, 15, and 29. The results show the soil before treatment was slightly acidic (pH 5.7) and extractable Si concentration was 267.1 mg SiO2 kg-1. It was classified to be below critical level of available Si for rice (300 mg SiO2 kg-1). Total concentration of Ca and Mg in soil solution were highest for treatment T4 and T7, respectively compared with other treatments. On the first 8 days of incubation, Si released into soil solution was higher in T1 and T2 compared to other treatments. The solubility of Si was significantly positive correlated with Mn, Eh, and negatively correlated with pH, that indicated these were the controlling factors of the Si release in soil solution. There was no correlation between Si and Ca or Mg concentration in soil solution.
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