表面活性剂冲洗修复柴油污染砂柱过程的数学模拟

G. Asadollahfardi, A. Darban, Nazila Noorifar, M. Rezaee
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引用次数: 5

摘要

本文建立了基于UTCHEM仿真器的表面活性剂冲洗修复柴油污染砂柱的数值模型。为此,我们模拟了柴油初始浓度为10000ppm和20000ppm下的修复过程。在我们的模型中考虑了各种百分比质量十二烷基硫酸钠(SDS)。模型结果表明,当柴油初始浓度为10000ppm时,0.1%质量的SDS和0.1%质量的SDS的去除率最大,与实验结果一致。当柴油浓度为10000 ppm时,模型结果与实验数据的决定系数(r2)和一致指数(IA)分别为0.9952和0.9695,当柴油浓度为20000 ppm时,r2和IA分别为0.9977和0.9935。渗透率的敏感性分析表明,在所有柴油浓度和SDS百分比质量下,随着渗透率的增加,该模型的去除效率更高。
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Mathematical simulation of surfactant flushing process to remediate diesel contaminated sand column
This paper presents a numerical model based on a UTCHEM simulator to simulate surfactant flushing process to remediate diesel contaminated sand column. For this purpose, we modeled remediation process under 10000 and 20000 ppm initial concentrations of diesel. Various percent-mass sodium dodecyl sulfate (SDS) considered in our model. The model results indicated that 0.3 percent-mass of SDS at 10000 ppm and 0.1 percent-mass of SDS at 20000 ppm initial diesel concentration had maximum removal perdition which is in agreement with the experiment results. For 10000 ppm diesel concentrations, the coefficient of determination (R 2 ) and index of agreement (IA) between the model result and the experimental data were 0.9952 and 0.9695, respectively, and for 20000 ppm diesel concentrations, R 2 and IA were 0.9977 and 0.9935, respectively. The sensitivity analysis of permeability illustrated that in all diesel concentrations and SDS percent-mass with increasing permeability the model resulted in more removal efficiency.
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