采用生物质热解产物为再燃燃料的再燃技术,降低TPP 312锅炉氮氧化物排放

S. Kobzar, A. Khalatov
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摘要

在乌克兰,以天然气为燃料的三级煤燃烧系统作为氮氧化物减排的再燃燃料安装在Ladyzhyn TPP的4号机组上。该系统是与燃烧工程公司(美国)、VTI公司(俄罗斯)和乌克兰国家科学院天然气研究所合作开发的,并于1992年由Ladyzhyn TPP工作人员组装完成。该系统的测试运行证实了该方法减少氮氧化物排放到大气中的有效性(高达50%)。不幸的是,由于天然气的高价格和对其使用的限制,目前使用天然气作为再燃燃料是不可能的。采用生物质热解产物为再燃燃料的再燃技术是降低TPP 312燃煤锅炉氮氧化物排放的可行途径之一。研究了生物质热解产物作为再燃燃料应用于TPP 312燃煤锅炉再燃技术中降低氮氧化物的可能性。为此,开发并建立了标准TPP 312锅炉和带煤再燃燃烧系统的TPP 312锅炉的详细计算机模型。对安装在DTEK ladyzhnska TPP 4号机组上的再燃煤燃烧系统在280 MWe锅炉负荷下的运行设计参数进行了研究。经确定,以锅炉总热容量的12%供应再燃燃料,可以很好地减少氮氧化物(高达25%),为过热器管道提供无渣条件,并且不会导致未燃烧碳的燃料损失增加。
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USE OF THE REBURNING TECHNOLOGY WITH BIOMASS PYROLYSIS PRODUCTS AS A REBURNING FUEL TO REDUCE EMISSIONS OF NITROGEN OXIDES FROM TPP 312 BOILER
In Ukraine, a three-stage coal combustion system fueled by a natural gas as a reburning fuel for nitrogen oxides emission reduction was mounted on Unit № 4 of the Ladyzhyn TPP. This system was developed in cooperation with Combustion Engineering (USA), VTI (Russia) and the Gas Institute of the National Academy of Sciences of Ukraine and was assembled by the Ladyzhyn TPP staff in 1992. The test runs of this system had confirmed the effectiveness of this method of reducing emissions of nitrogen oxides into the atmosphere (up to 50%).Unfortunately, due to the high price of natural gas and the introduction of limits on its use, currently the use of natural gas as a fuel for reburning is impossible. One of the possible ways to reduce emissions of nitrogen oxides from the coal-fired boiler TPP 312 is the operation of Reburning technology with the biomass pyrolysis product as reburning fuel. The aim of the work was to evaluate the possibility of the application the biomass pyrolysis products as a reburning fuel in Reburning technology to reduce nitrogen oxides from the coal-fired boiler TPP 312. For this purpose, a detailed computer model of a standard TPP 312 boiler and a TPP 312 boiler with a coal reburning combustion system was developed and built. The study of the operation the Reburning coal combustion system, which is mounted on the unit №4 DTEK Ladyzhynska TPP, on the design parameters of the operation for the boiler load of 280 MWe was carried out. It was determinate that the supply of reburning fuel at 12% of the total heat capacity of the boiler gives a good level of the reduction of nitrogen oxides (up to 25%), provides no slag conditions for superheater pipes and does not lead to increase of the fuel losses with unburnt carbon.
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