共沉淀法制备BaZr(CoMn)0.5Fe10O19粉末及其磁性能

H. Mao
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摘要

取代m型六铁氧体是一种高度各向异性的铁磁材料。本文报道了用共沉淀法合成BaZr(CoMn)0.5Fe10O19粉末并对其进行了表征。考察了溶剂效应和预热效应。用x射线衍射、扫描电镜和振动样品磁强计对合成的粉末进行了表征。实验结果表明,以水为溶剂制备的粉末具有1.30 kOe的高矫顽力和38.65 emu g-1的高饱和磁化强度,而以水/乙醇为溶剂制备的粉末在30 kOe的电场下具有1.01 kOe的低矫顽力和34.25 emu g-1的低饱和磁化强度。在400℃的预热下,两种粉末的颗粒形态和磁性能也发生了一些变化。
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Synthesis and Magnetic Property of BaZr(CoMn)0.5Fe10O19 Powder by Coprecipitation Method
Substituted M-type hexaferrites are highly anisotropic ferromagnetic materials. In this paper, we report the synthesis and characterisation of BaZr(CoMn)0.5Fe10O19 powder by coprecipitation method. The solvent and preheating effects were investigated. The synthesised powders were characterised with X-ray diffraction, scanning electron microscopy and vibrating sample magnetometer. The experimental results indicated that the powders prepared with the water as solvent exhibits high coercivity of 1.30 kOe and a high saturation magnetisation of 38.65 emu g–1, while the powder prepared with the powder prepared with the water/ethanol solvent exhibits low coercivity of 1.01 kOe and a low saturation magnetization of 34.25 emu g–1, at applied field of 30 kOe. The preheating at 400°C also led to some changes in particle morphology and magnetic property for both powders.
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