美国亚利桑那州Saginaw Hill地区单向凝固结构记录的岩浆-热液转换过程中的流体和熔体

IF 5.5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Economic Geology Pub Date : 2022-11-01 DOI:10.5382/econgeo.4952
W. Bain, P. Lecumberri-Sanchez, E. Marsh, M. Steele‐MacInnis
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引用次数: 3

摘要

岩浆-热液转换过程中的流体溶出和熔体演化是驱动斑岩体系金属富集的关键过程。在美国亚利桑那州西南部Saginaw hill的一个小的斑岩型Cu系统中,单向凝固结构(USTs)中的同期流体和熔体包裹体组合记录了一个动态的、重复的流体聚集和释放过程。整个UST波段石英晶体的岩心含有同时期的硅酸盐熔体和盐水包裹体,但缺乏富气包裹体。这可能表明,在压裂过程中,水蒸气优先排出,高密度卤水被捕获,或者单相高盐度卤水直接从硅酸盐熔体中析出。相比之下,UST石英的边缘含有丰富的同期盐水和蒸汽包裹体,与相应的石英岩心相比,在较低的压力下符合液-气不混相。这种从辉晶岩心中主要的同时期硅酸盐熔体包裹体和卤水到边缘中主要的同时期卤水和蒸汽的转变表明,在UST地层形成过程中,Saginaw Hill体系在相对稳定的温度(一贯为~650℃)下经历了流体析出、聚集、超压和减压的循环过程。熔体包裹体数据表明,这一阶段的熔体分馏程度高,趋于白云母饱和。卤水中的金属浓度与世界级斑岩Cu体系中流体中的金属浓度相当或更高,可能是火成岩分馏和溶解流体中高氯化物含量的结果。虽然规模有限,但Saginaw Hill为预测在大型、矿化良好的斑岩系统形成期间岩浆-热液转变过程中发生的过程提供了证据。
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Fluids and Melts at the Magmatic-Hydrothermal Transition, Recorded by Unidirectional Solidification Textures at Saginaw Hill, Arizona, USA
Fluid exsolution and melt evolution at the magmatic-hydrothermal transition are critical processes driving the metal enrichment of porphyry systems. Coeval fluid and melt inclusion assemblages in unidirectional solidification textures (USTs) at Saginaw Hill—a small, porphyry Cu system in southwestern Arizona—record a dynamic and repetitious process of fluid accumulation and release. The cores of quartz crystals throughout the UST bands host coeval silicate melt and brine inclusions but lack vapor-rich inclusions. This could indicate preferential expulsion of vapor and trapping of high-density brine during episodes of fracturing or the direct exsolution of single-phase high-salinity brine from the silicate melt. In contrast, the rims of UST quartz host abundant coeval brine and vapor inclusions, consistent with liquid-vapor immiscibility at lower pressures compared to the corresponding quartz cores. This transition from dominantly coeval silicate melt inclusions and brine in phenocryst cores to coeval brine and vapor in the rims suggests that the Saginaw Hill system underwent cyclic processes of fluid exsolution, accumulation, overpressure, and decompression at relatively stable temperatures (consistently ~650°C) during UST formation. Melt inclusion data indicate that the melt at this stage was highly fractionated and tended toward muscovite saturation. Metal concentrations in the brine were comparable to or higher than those in fluids reported in world-class porphyry Cu systems and were likely the result of both igneous fractionation and the high chloride content of the exsolved fluids. While limited in scale, Saginaw Hill provides evidence for processes that are predicted to occur at the magmatic-hydrothermal transition during the formation of large, well-mineralized porphyry systems.
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来源期刊
Economic Geology
Economic Geology 地学-地球化学与地球物理
CiteScore
10.00
自引率
6.90%
发文量
120
审稿时长
6 months
期刊介绍: The journal, now published semi-quarterly, was first published in 1905 by the Economic Geology Publishing Company (PUBCO), a not-for-profit company established for the purpose of publishing a periodical devoted to economic geology. On the founding of SEG in 1920, a cooperative arrangement between PUBCO and SEG made the journal the official organ of the Society, and PUBCO agreed to carry the Society''s name on the front cover under the heading "Bulletin of the Society of Economic Geologists". PUBCO and SEG continued to operate as cooperating but separate entities until 2001, when the Board of Directors of PUBCO and the Council of SEG, by unanimous consent, approved a formal agreement of merger. The former activities of the PUBCO Board of Directors are now carried out by a Publications Board, a new self-governing unit within SEG.
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