M. A. MacDonald, G. Bat-Erdene, M. X. Gillis, P. J. Dalton, I. Kavalieris, B.-E. Khashgerel, A. Kloppenburg, A. Coote, J. W. Hedenquist
Mineral exploration since 2005 in a previously underexplored region of southwestern Mongolia resulted in the definition of the Zuun Mod porphyry Mo-Cu deposit, followed by discovery of the Altan Nar and Bayan Khundii epithermal gold deposits along with several prospects and advanced exploration projects. These discoveries form the core of the emerging Khundii (“Valley”) metallogenic province, ~50 × 100 km in size, located within a single island-arc terrane of Middle Carboniferous to early Permian age and predominantly within an individual mapped subterrane. The province is situated ~700 km west-northwest of the late Devonian Oyu Tolgoi porphyry Cu-Au deposit in a belt of mid-Paleozoic island arcs that are part of the Central Asian orogenic belt, host to world-class porphyry Cu-Au and epithermal gold deposits that stretch from southern Mongolia to the west, into China, Kazakhstan, and beyond.The Zuun Mod porphyry Mo-Cu deposit (297 ± 4.8 Ma) is hosted by a granodiorite intrusion cut by B-type quartz-molybdenite-chalcopyrite veins with K-feldspar alteration selvages plus disseminated biotite and magnetite. After definition of this deposit, a regional exploration program was initiated in 2009 over 110,000 km<sup>2</sup>, based on the underexplored nature of the region. Exploration included compilation of existing geologic, geochemical, and geophysical data and interpretation of satellite imagery followed by ground exploration that included stream, soil, and rock-chip sampling and geologic and alteration mapping. The Nomin Tal Cu-Au prospect was discovered in early 2011, and based on the indications from initial soil sampling, a 400- × 400-m soil survey was conducted over the southern part of the exploration license, which identified a Pb-, Zn-, and Au-in-soil anomaly over an area of ~1.5 × ~5.5 km. The first drill hole within the soil anomaly in late 2011 resulted in the discovery of the Altan Nar Au-polymetallic epithermal deposit with veins of coarsely crystalline quartz-adularia (309.7 ± 0.5 Ma) and Ca-, Mg-, Mn-, and Fe-carbonate gangue that host the base metal sulfides.The Bayan Khundii gold deposit was discovered in 2015 as the result of prospecting, ~16 km southeast of Altan Nar. Subsequent discovery of the Khar Mori gold project was announced in early 2021, ~3 km north of Bayan Khundii along a structural trend, and later in 2021 drilling discovered wide zones of disseminated gold at Ulaan Southeast, ~800 m west of Bayan Khundii. The epithermal quartz-adularia-gold veins (336.8 ± 0.5 Ma) at Bayan Khundii have colloform bands with minor pyrite and are enveloped by proximal illite alteration. The epithermal veins and alteration overprint an earlier, unrelated alteration style of residual quartz and pyrophyllite ± dickite ± diaspore-kaolinite. Similarly, residual quartz and pyrophyllite-dickite at Khar Mori are overprinted by epithermal mineralization, including arsenopyrite. At the central Ulaan project, ~3 km northwest of Bayan Khundii, intens
{"title":"Epithermal Gold Discoveries in the Emerging Khundii Metallogenic Province, Southwest Mongolia","authors":"M. A. MacDonald, G. Bat-Erdene, M. X. Gillis, P. J. Dalton, I. Kavalieris, B.-E. Khashgerel, A. Kloppenburg, A. Coote, J. W. Hedenquist","doi":"10.5382/econgeo.5070","DOIUrl":"https://doi.org/10.5382/econgeo.5070","url":null,"abstract":"Mineral exploration since 2005 in a previously underexplored region of southwestern Mongolia resulted in the definition of the Zuun Mod porphyry Mo-Cu deposit, followed by discovery of the Altan Nar and Bayan Khundii epithermal gold deposits along with several prospects and advanced exploration projects. These discoveries form the core of the emerging Khundii (“Valley”) metallogenic province, ~50 × 100 km in size, located within a single island-arc terrane of Middle Carboniferous to early Permian age and predominantly within an individual mapped subterrane. The province is situated ~700 km west-northwest of the late Devonian Oyu Tolgoi porphyry Cu-Au deposit in a belt of mid-Paleozoic island arcs that are part of the Central Asian orogenic belt, host to world-class porphyry Cu-Au and epithermal gold deposits that stretch from southern Mongolia to the west, into China, Kazakhstan, and beyond.The Zuun Mod porphyry Mo-Cu deposit (297 ± 4.8 Ma) is hosted by a granodiorite intrusion cut by B-type quartz-molybdenite-chalcopyrite veins with K-feldspar alteration selvages plus disseminated biotite and magnetite. After definition of this deposit, a regional exploration program was initiated in 2009 over 110,000 km<sup>2</sup>, based on the underexplored nature of the region. Exploration included compilation of existing geologic, geochemical, and geophysical data and interpretation of satellite imagery followed by ground exploration that included stream, soil, and rock-chip sampling and geologic and alteration mapping. The Nomin Tal Cu-Au prospect was discovered in early 2011, and based on the indications from initial soil sampling, a 400- × 400-m soil survey was conducted over the southern part of the exploration license, which identified a Pb-, Zn-, and Au-in-soil anomaly over an area of ~1.5 × ~5.5 km. The first drill hole within the soil anomaly in late 2011 resulted in the discovery of the Altan Nar Au-polymetallic epithermal deposit with veins of coarsely crystalline quartz-adularia (309.7 ± 0.5 Ma) and Ca-, Mg-, Mn-, and Fe-carbonate gangue that host the base metal sulfides.The Bayan Khundii gold deposit was discovered in 2015 as the result of prospecting, ~16 km southeast of Altan Nar. Subsequent discovery of the Khar Mori gold project was announced in early 2021, ~3 km north of Bayan Khundii along a structural trend, and later in 2021 drilling discovered wide zones of disseminated gold at Ulaan Southeast, ~800 m west of Bayan Khundii. The epithermal quartz-adularia-gold veins (336.8 ± 0.5 Ma) at Bayan Khundii have colloform bands with minor pyrite and are enveloped by proximal illite alteration. The epithermal veins and alteration overprint an earlier, unrelated alteration style of residual quartz and pyrophyllite ± dickite ± diaspore-kaolinite. Similarly, residual quartz and pyrophyllite-dickite at Khar Mori are overprinted by epithermal mineralization, including arsenopyrite. At the central Ulaan project, ~3 km northwest of Bayan Khundii, intens","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"7 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140817834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hidaya Hassan, Jacob Kaavera, Akira Imai, Kotaro Yonezu, Thomas Tindell, Kenzo Sanematsu, Koichiro Watanabe
High-grade Cu mineralization was recently discovered in the Mbesa prospect in southern Tanzania, but its origin is poorly constrained. Herein, we present new major element, trace element, rare earth element (REE), and platinum group element (PGE) geochemistry and petrographic data to constrain the origin of the mineralization. The sulfide mineralization is dominated by chalcopyrite and bornite and characterized by high Cu/Ni over 100 in the massive and disseminated ores. The mineralization lacks pyrrhotite and pentlandite, which are found commonly in magmatic Ni-Cu-PGE sulfide deposits. Platinum group minerals present are michenerite (PdBiTe) and sudburyite (PdSb). PGE concentrations expressed as Pd + Pt + Au are up to 1.31 and 1.04 ppm in the massive and disseminated ores, respectively. The δ34S of chalcopyrite separates range from –3.9 to –0.6‰, bornite separates vary from –1.8 to 1.1‰, and bornite-chalcopyrite mixtures yield –1.3 and 0.6‰, mostly consistent with a magmatic sulfur origin. The sulfides are hosted by coarse-grained plagioclase amphibolite and hornblende gneiss with recrystallization textures suggestive of metamorphism. Both rocks are characterized by enrichment in large ion lithophile elements (LILEs), with negative anomalies of Zr and Nb, consistent with crustal contamination of magmas derived from partial melting of subcontinental lithospheric mantle (SCLM). An SCLM origin is further suggested by the close association of Cu sulfides with carbonates and apatite. It is suggested that the sulfides crystallized from the fractionated Cu-rich sulfide melt enriched in intermediate solid solution (iss) at shallow crustal levels. Sulfide were likely mobilized as droplets attached to CO2 vapor phase as expressed by close association between carbonates and apatite with the Cu-rich sulfides. Nickel-rich sulfides may remain undiscovered at deeper portions around the Mbesa prospect.
{"title":"Cu-Au-Platinum Group Element Mineralization in the Mbesa Prospect, Southern Tanzania: Unconventional Magmatic Sulfides","authors":"Hidaya Hassan, Jacob Kaavera, Akira Imai, Kotaro Yonezu, Thomas Tindell, Kenzo Sanematsu, Koichiro Watanabe","doi":"10.5382/econgeo.5068","DOIUrl":"https://doi.org/10.5382/econgeo.5068","url":null,"abstract":"High-grade Cu mineralization was recently discovered in the Mbesa prospect in southern Tanzania, but its origin is poorly constrained. Herein, we present new major element, trace element, rare earth element (REE), and platinum group element (PGE) geochemistry and petrographic data to constrain the origin of the mineralization. The sulfide mineralization is dominated by chalcopyrite and bornite and characterized by high Cu/Ni over 100 in the massive and disseminated ores. The mineralization lacks pyrrhotite and pentlandite, which are found commonly in magmatic Ni-Cu-PGE sulfide deposits. Platinum group minerals present are michenerite (PdBiTe) and sudburyite (PdSb). PGE concentrations expressed as Pd + Pt + Au are up to 1.31 and 1.04 ppm in the massive and disseminated ores, respectively. The δ<sup>34</sup>S of chalcopyrite separates range from –3.9 to –0.6‰, bornite separates vary from –1.8 to 1.1‰, and bornite-chalcopyrite mixtures yield –1.3 and 0.6‰, mostly consistent with a magmatic sulfur origin. The sulfides are hosted by coarse-grained plagioclase amphibolite and hornblende gneiss with recrystallization textures suggestive of metamorphism. Both rocks are characterized by enrichment in large ion lithophile elements (LILEs), with negative anomalies of Zr and Nb, consistent with crustal contamination of magmas derived from partial melting of subcontinental lithospheric mantle (SCLM). An SCLM origin is further suggested by the close association of Cu sulfides with carbonates and apatite. It is suggested that the sulfides crystallized from the fractionated Cu-rich sulfide melt enriched in intermediate solid solution (iss) at shallow crustal levels. Sulfide were likely mobilized as droplets attached to CO<sub>2</sub> vapor phase as expressed by close association between carbonates and apatite with the Cu-rich sulfides. Nickel-rich sulfides may remain undiscovered at deeper portions around the Mbesa prospect.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"27 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140817772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marina D. Schofield, Bruno Lafrance, Harold L. Gibson, K. Howard Poulsen, Christophe Scheffer, Benoît Quesnel, Georges Beaudoin, Michael A. Hamilton
The Rouyn-Noranda mining district of Quebec contains 20 Cu-Zn (±Au ±Ag) volcanogenic massive sulfide (VMS) deposits, including the giant and gold-rich Quemont and Horne deposits. Mineralized epigenetic veins are also present, but their origin and relative timing remain enigmatic. The nature and extent of their alteration signatures and the effect of their superposition on district-scale alteration patterns is unknown. The VMS-related quartz-sulfide Cu-Zn-Ag veins have δ18Oquartz values of 8.5 ± 0.8‰, reflecting δ18Ofluid compositions of –0.4 to 3.1‰ (250°–350°C) that are typical of Archean seawater. They are associated with a proximal Fe-rich chlorite alteration and marginal spotted sericite-chlorite alteration with whole-rock δ18O values of 2.9 to 5.9‰ and are interpreted to have formed within the structurally controlled discordant upflow zones of a VMS hydrothermal system. Younger gold-bearing quartz-carbonate veins were emplaced along mechanical anisotropies created by mafic dikes during north-south compression and the formation of regional E-trending faults, folds, and cleavage. They are characterized by δ18Oquartz values of 11.3 ± 0.8‰, reflecting δ18Ofluid compositions of 2.4 to 5.9‰ (250°–350°C), typical of a metamorphic fluid, possibly mixed with a lower δ18O upper crustal fluid. They are associated with ankerite, calcite, muscovite, chlorite, albite, and quartz ± hematite alteration with whole-rock δ18O values of 5.8 to 10.3‰. Chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb zircon ages for two tonalite intrusions constrain the maximum age of the Cu-Zn-Ag veins to 2697.6 ± 0.7 Ma and the minimum age to 2695.3 ± 1.0 Ma, which is also the maximum age of the gold quartz-carbonate veins. Superposition of alteration related to the gold quartz-carbonate veins on previously chlorite- and sericite-altered rocks has resulted in mixed alteration signals with whole-rock δ18O values of ~6 to 8‰ that have perturbed and masked regional alteration patterns related to older VMS mineralization, such as those found in the Quemont and Horne deposits. These results indicate that defining alteration vectors in camps that have superimposed hydrothermal systems requires full consideration of the hydrothermal history of the camp, and if such constraints are lacking, whole-rock δ18O values should not be used as a stand-alone exploration method.
{"title":"Discriminating Superimposed Alteration Associated with Epigenetic Base and Precious Metal Vein Systems in the Rouyn-Noranda Mining District, Quebec; Implications for Exploration in Ancient Volcanic Districts","authors":"Marina D. Schofield, Bruno Lafrance, Harold L. Gibson, K. Howard Poulsen, Christophe Scheffer, Benoît Quesnel, Georges Beaudoin, Michael A. Hamilton","doi":"10.5382/econgeo.5063","DOIUrl":"https://doi.org/10.5382/econgeo.5063","url":null,"abstract":"The Rouyn-Noranda mining district of Quebec contains 20 Cu-Zn (±Au ±Ag) volcanogenic massive sulfide (VMS) deposits, including the giant and gold-rich Quemont and Horne deposits. Mineralized epigenetic veins are also present, but their origin and relative timing remain enigmatic. The nature and extent of their alteration signatures and the effect of their superposition on district-scale alteration patterns is unknown. The VMS-related quartz-sulfide Cu-Zn-Ag veins have δ<sup>18</sup>O<sub>quartz</sub> values of 8.5 ± 0.8‰, reflecting δ<sup>18</sup>O<sub>fluid</sub> compositions of –0.4 to 3.1‰ (250°–350°C) that are typical of Archean seawater. They are associated with a proximal Fe-rich chlorite alteration and marginal spotted sericite-chlorite alteration with whole-rock δ<sup>18</sup>O values of 2.9 to 5.9‰ and are interpreted to have formed within the structurally controlled discordant upflow zones of a VMS hydrothermal system. Younger gold-bearing quartz-carbonate veins were emplaced along mechanical anisotropies created by mafic dikes during north-south compression and the formation of regional E-trending faults, folds, and cleavage. They are characterized by δ<sup>18</sup>O<sub>quartz</sub> values of 11.3 ± 0.8‰, reflecting δ<sup>18</sup>O<sub>fluid</sub> compositions of 2.4 to 5.9‰ (250°–350°C), typical of a metamorphic fluid, possibly mixed with a lower δ<sup>18</sup>O upper crustal fluid. They are associated with ankerite, calcite, muscovite, chlorite, albite, and quartz ± hematite alteration with whole-rock δ<sup>18</sup>O values of 5.8 to 10.3‰. Chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb zircon ages for two tonalite intrusions constrain the maximum age of the Cu-Zn-Ag veins to 2697.6 ± 0.7 Ma and the minimum age to 2695.3 ± 1.0 Ma, which is also the maximum age of the gold quartz-carbonate veins. Superposition of alteration related to the gold quartz-carbonate veins on previously chlorite- and sericite-altered rocks has resulted in mixed alteration signals with whole-rock δ<sup>18</sup>O values of ~6 to 8‰ that have perturbed and masked regional alteration patterns related to older VMS mineralization, such as those found in the Quemont and Horne deposits. These results indicate that defining alteration vectors in camps that have superimposed hydrothermal systems requires full consideration of the hydrothermal history of the camp, and if such constraints are lacking, whole-rock δ<sup>18</sup>O values should not be used as a stand-alone exploration method.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"28 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140817838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Robert R. Loucks, Gonzalo J. Henríquez, Marco L. Fiorentini
To meet surging requirements of copper for the green energy revolution, minable resources subequal to all copper production in history must be found in the next two decades. We show that trace elements in zircon and whole-rock samples that are diagnostic of unusually high-pressure magmatic differentiation and high hydration state and oxidation state of their parent silicate melt are effective for discriminating copper sulfide-ore-productive arc magmas from infertile arc magmas. Tests on our database of 5,777 zircons from 80 igneous complexes, including 2,220 zircons from ore-generative intrusions in 37 major porphyry and high-sulfidation epithermal Cu(-Au-Mo) deposits worldwide, demonstrate that our magmatic copper fertility discriminants apparently perform equally well in intraoceanic arcs, continental margin arcs, and continental collision orogens of Ordovician to Quaternary age. That performance consistency means that the tectono-magmatic controls on development of magmatic-hydrothermal copper ore-forming fertility are essentially the same in all those plate-convergence settings. The ratio Ce/√(U × Ti) in zircon is a quantitative indicator of the relative oxygen fugacity of the silicate melt and its sulfur-carrying capacity. The ratio of the europium anomaly to ytterbium in granitoid melts and zircon is an uncalibrated but empirically useful indicator of the melt’s hydration state and ability to provide chloride-complexed metals to exsolving hydrothermal fluids. Plots of (EuN/Eu*)/YbN vs. Ce/√(U × Ti) in zircon are remarkably effective for discriminating igneous complexes, arc segments, and time intervals within them that can generate and are likely to host magmatic-hydrothermal Cu(-Au-Mo) ore deposits. Arrays of cognate zircons on such plots have slopes that vary with pressure-dependent chlorinity of exsolving fluid and its efficacy in scavenging CuCl from the melt. Our zircon indicators of Cu metallogenic fertility are applicable to detrital as well as in situ zircons and can assist with ore discovery in watersheds upstream from a sediment sampling site. We formulated a composite zircon copper fertility index (ZCFI) that can be applied to each microbeam spot analysis—ZCFI = 104 (EuN/EuN*)/YbN + 5 Ce/√(Ui × Ti)—and substantially decreases the number of zircon analyses needed for reliable prospectivity assessment in a detrital grain population, thereby making this watershed-scale exploration tool cost-competitive with other methods of geochemical exploration.
{"title":"Zircon and Whole-Rock Trace Element Indicators of Magmatic Hydration State and Oxidation State Discriminate Copper Ore-Forming from Barren Arc Magmas","authors":"Robert R. Loucks, Gonzalo J. Henríquez, Marco L. Fiorentini","doi":"10.5382/econgeo.5071","DOIUrl":"https://doi.org/10.5382/econgeo.5071","url":null,"abstract":"To meet surging requirements of copper for the green energy revolution, minable resources subequal to all copper production in history must be found in the next two decades. We show that trace elements in zircon and whole-rock samples that are diagnostic of unusually high-pressure magmatic differentiation and high hydration state and oxidation state of their parent silicate melt are effective for discriminating copper sulfide-ore-productive arc magmas from infertile arc magmas. Tests on our database of 5,777 zircons from 80 igneous complexes, including 2,220 zircons from ore-generative intrusions in 37 major porphyry and high-sulfidation epithermal Cu(-Au-Mo) deposits worldwide, demonstrate that our magmatic copper fertility discriminants apparently perform equally well in intraoceanic arcs, continental margin arcs, and continental collision orogens of Ordovician to Quaternary age. That performance consistency means that the tectono-magmatic controls on development of magmatic-hydrothermal copper ore-forming fertility are essentially the same in all those plate-convergence settings. The ratio Ce/√(U × Ti) in zircon is a quantitative indicator of the relative oxygen fugacity of the silicate melt and its sulfur-carrying capacity. The ratio of the europium anomaly to ytterbium in granitoid melts and zircon is an uncalibrated but empirically useful indicator of the melt’s hydration state and ability to provide chloride-complexed metals to exsolving hydrothermal fluids. Plots of (Eu<sub>N</sub>/Eu*)/Yb<sub>N</sub> vs. Ce/√(U × Ti) in zircon are remarkably effective for discriminating igneous complexes, arc segments, and time intervals within them that can generate and are likely to host magmatic-hydrothermal Cu(-Au-Mo) ore deposits. Arrays of cognate zircons on such plots have slopes that vary with pressure-dependent chlorinity of exsolving fluid and its efficacy in scavenging CuCl from the melt. Our zircon indicators of Cu metallogenic fertility are applicable to detrital as well as in situ zircons and can assist with ore discovery in watersheds upstream from a sediment sampling site. We formulated a composite zircon copper fertility index (ZCFI) that can be applied to each microbeam spot analysis—ZCFI = 10<sup>4</sup> (Eu<sub>N</sub>/Eu<sub>N</sub>*)/Yb<sub>N</sub> + 5 Ce/√(U<sub>i</sub> × Ti)—and substantially decreases the number of zircon analyses needed for reliable prospectivity assessment in a detrital grain population, thereby making this watershed-scale exploration tool cost-competitive with other methods of geochemical exploration.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"10 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140817872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Liu, Chuntao Yin, Yasir Shaheen Khalil, Jun Hong, Jilu Feng, Huishan Zhang
The Chagai porphyry Cu belt in Pakistan is an important metallogenic terrain extending approximately 400 km in an east-west direction. Most of the known porphyry Cu deposits, such as the world-class Reko Diq deposit and Saindak deposit, are located in the western Chagai belt. In this study, the ZY1-02D hyperspectral data acquired by a recently launched spaceborne imaging spectrometer with 166 bands within a 0.4- to 2.5-μm spectral region were used to map mineral information over 8,000 km2 for exploring potential targets of porphyry Cu mineralization in the western Chagai belt. False color composite, spectral angle mapper, and wavelength position mapping methods were used in this research leading to the identification of a series of alteration minerals (including muscovite [sericite], kaolinite, alunite, epidote, chlorite, and calcite) from ZY1-02D data. The alteration mineral maps derived from ZY1-02D data match well with the known deposits and field inspections. Twenty-three new targets were identified as potential porphyry Cu mineralization targets for further exploration in the study area. Three targets, north of Saindak, Koh-i-Sultan, and Durban Chah, and six alteration sites in the southwest of Durban Chah, were inspected in the field, and Cu-Au mineralization was confirmed in all these inspected areas. As the ZY1-02D hyperspectral data covers most of the land area of the earth, this study provides new insights for mineral exploration and lithologic mapping in remote regions.
{"title":"Alteration Mapping for Porphyry Cu Targeting in the Western Chagai Belt, Pakistan, Using ZY1-02D Spaceborne Hyperspectral Data","authors":"Lei Liu, Chuntao Yin, Yasir Shaheen Khalil, Jun Hong, Jilu Feng, Huishan Zhang","doi":"10.5382/econgeo.5045","DOIUrl":"https://doi.org/10.5382/econgeo.5045","url":null,"abstract":"The Chagai porphyry Cu belt in Pakistan is an important metallogenic terrain extending approximately 400 km in an east-west direction. Most of the known porphyry Cu deposits, such as the world-class Reko Diq deposit and Saindak deposit, are located in the western Chagai belt. In this study, the ZY1-02D hyperspectral data acquired by a recently launched spaceborne imaging spectrometer with 166 bands within a 0.4- to 2.5-μm spectral region were used to map mineral information over 8,000 km<sup>2</sup> for exploring potential targets of porphyry Cu mineralization in the western Chagai belt. False color composite, spectral angle mapper, and wavelength position mapping methods were used in this research leading to the identification of a series of alteration minerals (including muscovite [sericite], kaolinite, alunite, epidote, chlorite, and calcite) from ZY1-02D data. The alteration mineral maps derived from ZY1-02D data match well with the known deposits and field inspections. Twenty-three new targets were identified as potential porphyry Cu mineralization targets for further exploration in the study area. Three targets, north of Saindak, Koh-i-Sultan, and Durban Chah, and six alteration sites in the southwest of Durban Chah, were inspected in the field, and Cu-Au mineralization was confirmed in all these inspected areas. As the ZY1-02D hyperspectral data covers most of the land area of the earth, this study provides new insights for mineral exploration and lithologic mapping in remote regions.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"26 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Porphyry deposits in magmatic arcs form coincident with changes to steady-state oceanic subduction conditions, such as changes in plate convergence rate and vector or angle of subduction. However, it remains unclear whether such processes also operated during formation of postsubduction porphyry deposits. The Yulong magmatic belt in the eastern Tibetan Plateau consists of middle to late Eocene igneous rocks (~51–35 Ma) that formed during the India-Asia collision, whereas all known porphyry deposits are associated with late Eocene rocks (43–35 Ma). A synthesis of new and published geochemical data shows marked variations from the middle to late Eocene, including increasing whole-rock La/Yb, Sr/Y, and EuN/EuN* values, as well as zircon EuN/EuN* values. These geochemical variations, together with petrographic observations, indicate a transition from plagioclase-dominated to amphibole-dominated fractionation from the middle to late Eocene.Coupled changes of magma compositions and porphyry Cu metallogeny from the middle to late Eocene coincided with, or were slightly preceded by, the onset of regional uplift and crustal thickening, triggered by the India-Asia hard collision and rapid deceleration of the India-Asia convergence rate at ca. 50 to 44 Ma. Crustal thickening may have caused prolonged magma differentiation at greater depths and accumulation of dissolved H2O, both of which contributed to amphibole-dominated fractionation and generation of hydrous melt that are prospective for porphyry Cu mineralization. Our study highlights the importance of tectonic changes in the formation of the Yulong and other postsubduction porphyry Cu belts—a scenario similar to that operated in subduction-related settings such as the Andes.
{"title":"Linking Porphyry Cu Formation to Tectonic Change in Postsubduction Settings: A Case Study from the Giant Yulong Belt, Eastern Tibet","authors":"Ming-Liang Huang, Xian-Wu Bi, Rui-Zhong Hu, Massimo Chiaradia, Jing-Jing Zhu, Lei-Luo Xu, Zong-Yong Yang","doi":"10.5382/econgeo.5052","DOIUrl":"https://doi.org/10.5382/econgeo.5052","url":null,"abstract":"Porphyry deposits in magmatic arcs form coincident with changes to steady-state oceanic subduction conditions, such as changes in plate convergence rate and vector or angle of subduction. However, it remains unclear whether such processes also operated during formation of postsubduction porphyry deposits. The Yulong magmatic belt in the eastern Tibetan Plateau consists of middle to late Eocene igneous rocks (~51–35 Ma) that formed during the India-Asia collision, whereas all known porphyry deposits are associated with late Eocene rocks (43–35 Ma). A synthesis of new and published geochemical data shows marked variations from the middle to late Eocene, including increasing whole-rock La/Yb, Sr/Y, and Eu<sub>N</sub>/Eu<sub>N</sub>* values, as well as zircon Eu<sub>N</sub>/Eu<sub>N</sub>* values. These geochemical variations, together with petrographic observations, indicate a transition from plagioclase-dominated to amphibole-dominated fractionation from the middle to late Eocene.Coupled changes of magma compositions and porphyry Cu metallogeny from the middle to late Eocene coincided with, or were slightly preceded by, the onset of regional uplift and crustal thickening, triggered by the India-Asia hard collision and rapid deceleration of the India-Asia convergence rate at ca. 50 to 44 Ma. Crustal thickening may have caused prolonged magma differentiation at greater depths and accumulation of dissolved H<sub>2</sub>O, both of which contributed to amphibole-dominated fractionation and generation of hydrous melt that are prospective for porphyry Cu mineralization. Our study highlights the importance of tectonic changes in the formation of the Yulong and other postsubduction porphyry Cu belts—a scenario similar to that operated in subduction-related settings such as the Andes.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"20 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R.E. Ernst, H. El Bilali, K. L. Buchan, S.M. Jowitt
A 90° change in stress orientation has been previously proposed as the trigger for the final emplacement of the world-class Norilsk-Talnakh magmatic sulfide mineralization via the migration of accumulated sulfide melts from elsewhere within the plumbing system of the Siberian Traps large igneous province (LIP). We propose that this stress change does not require and was not triggered by a distal change in plate boundary stresses, but instead can be explained both temporally and spatially by stress changes recorded in the dike swarm patterns of the Siberian Traps LIP, namely the transition from a giant radiating dike swarm (associated with mantle plume uplift) to a giant circumferential swarm (linked to flattening of the plume head). The mantle plume stress-related changes recorded by these dike swarms, rather than distal plate boundary stress changes, were therefore most likely the trigger for the emplacement of the Norilsk-Talnakh mineralization. Other LIPs that have both giant radiating and circumferential dike swarms most likely reflect similar major and rapid changes in stress orientation, indicating that mantle plume-induced stress changes revealed by dike swarms should be considered an additional tool in magmatic sulfide exploration.
{"title":"PLUME-GENERATED 90° STRESS CHANGE LINKED TO TRANSITION FROM RADIATING TO CIRCUMFERENTIAL DOLERITE DIKE SWARMS OF THE SIBERIAN TRAPS LARGE IGNEOUS PROVINCE AND TO EMPLACEMENT OF THE NORILSK-TALNAKH ORE DEPOSITS","authors":"R.E. Ernst, H. El Bilali, K. L. Buchan, S.M. Jowitt","doi":"10.5382/econgeo.5065","DOIUrl":"https://doi.org/10.5382/econgeo.5065","url":null,"abstract":"A 90° change in stress orientation has been previously proposed as the trigger for the final emplacement of the world-class Norilsk-Talnakh magmatic sulfide mineralization via the migration of accumulated sulfide melts from elsewhere within the plumbing system of the Siberian Traps large igneous province (LIP). We propose that this stress change does not require and was not triggered by a distal change in plate boundary stresses, but instead can be explained both temporally and spatially by stress changes recorded in the dike swarm patterns of the Siberian Traps LIP, namely the transition from a giant radiating dike swarm (associated with mantle plume uplift) to a giant circumferential swarm (linked to flattening of the plume head). The mantle plume stress-related changes recorded by these dike swarms, rather than distal plate boundary stress changes, were therefore most likely the trigger for the emplacement of the Norilsk-Talnakh mineralization. Other LIPs that have both giant radiating and circumferential dike swarms most likely reflect similar major and rapid changes in stress orientation, indicating that mantle plume-induced stress changes revealed by dike swarms should be considered an additional tool in magmatic sulfide exploration.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"20 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rael D. Lipson, Richard J. Goldfarb, Ben M. Frieman, John Payne
The San Albino deposit is an orogenic gold occurrence hosted by a low-angle thrust that is the site of a new open-pit mine in northern Nicaragua. The deposit is hosted in greenschist facies rocks of the Jurassic metasedimentary Neuvo Segovia Formation. The schist was uplifted and exposed during arc accretion and Cretaceous thin-skin deformation, forming the NE-striking Colon fold-and-thrust belt. Deformation included emplacement of the 119 to 113 Ma NE-trending Dipilto batholith into the regionally metamorphosed clastic rocks about 5 km northwest of the San Albino deposit. Mineralization is dominated by three laminated quartz vein systems (i.e., San Albino, Naranjo, Arras) that broadly follow shallowly dipping (approx. 30°) carbonaceous shears roughly concordant to schistosity along the limbs of a doubly plunging antiform. The three main parallel shears are each separated by about 90 m and individually reach a maximum thickness of about 8 m. Maximum thickness of ore zones is where post-ore local folding and reverse motion along the shallow shears has duplicated the laminated low-angle gold-bearing veins (D2 and early D3). Additional gold was added to the veins, with abundant sulfides, during a subsequent brecciation event of the early formed quartz veins that accompanied progressive thrusting (late D3). This predated boudinage of the veins during continued compression and thrust loading (D4); high gold grades are particularly notable along pyrite- and arsenopyrite-bearing stylolites formed during D4 pressure solution. The D2 to D3 gold event is likely coeval with Albian uplift of the Dipilto batholith and with back thrusting in the schist aided by the stress inhomogeneities provided by the igneous complex.Low-angle thrust-controlled orogenic gold deposits may represent world-class exploration targets because of their large linear footprints, although they are traditionally looked at as less favorable exploration targets relative to gold systems developed more commonly along high-angle reverse faults. Our case study of the San Albino deposit shows that although low-angle deposits are not inherently misoriented for failure like the more common subvertical reverse fault-related deposits, they may be sites of significant pressure buildup due to hydrothermal mineral precipitation during initial water-rock interaction or slight temperature decreases along the low-angle flow path. Resulting fluid cycling may lead to thick laminated vein development, such as seen at San Albino, where especially high-grade zones may be associated with local steepening and/or dilational zones within the broader, low-angle vein-hosting shear system.
{"title":"San Albino, Nicaragua: A Low-Angle, Thrust-Controlled Orogenic Gold Deposit","authors":"Rael D. Lipson, Richard J. Goldfarb, Ben M. Frieman, John Payne","doi":"10.5382/econgeo.5042","DOIUrl":"https://doi.org/10.5382/econgeo.5042","url":null,"abstract":"The San Albino deposit is an orogenic gold occurrence hosted by a low-angle thrust that is the site of a new open-pit mine in northern Nicaragua. The deposit is hosted in greenschist facies rocks of the Jurassic metasedimentary Neuvo Segovia Formation. The schist was uplifted and exposed during arc accretion and Cretaceous thin-skin deformation, forming the NE-striking Colon fold-and-thrust belt. Deformation included emplacement of the 119 to 113 Ma NE-trending Dipilto batholith into the regionally metamorphosed clastic rocks about 5 km northwest of the San Albino deposit. Mineralization is dominated by three laminated quartz vein systems (i.e., San Albino, Naranjo, Arras) that broadly follow shallowly dipping (approx. 30°) carbonaceous shears roughly concordant to schistosity along the limbs of a doubly plunging antiform. The three main parallel shears are each separated by about 90 m and individually reach a maximum thickness of about 8 m. Maximum thickness of ore zones is where post-ore local folding and reverse motion along the shallow shears has duplicated the laminated low-angle gold-bearing veins (D<sub>2</sub> and early D<sub>3</sub>). Additional gold was added to the veins, with abundant sulfides, during a subsequent brecciation event of the early formed quartz veins that accompanied progressive thrusting (late D<sub>3</sub>). This predated boudinage of the veins during continued compression and thrust loading (D<sub>4</sub>); high gold grades are particularly notable along pyrite- and arsenopyrite-bearing stylolites formed during D<sub>4</sub> pressure solution. The D<sub>2</sub> to D<sub>3</sub> gold event is likely coeval with Albian uplift of the Dipilto batholith and with back thrusting in the schist aided by the stress inhomogeneities provided by the igneous complex.Low-angle thrust-controlled orogenic gold deposits may represent world-class exploration targets because of their large linear footprints, although they are traditionally looked at as less favorable exploration targets relative to gold systems developed more commonly along high-angle reverse faults. Our case study of the San Albino deposit shows that although low-angle deposits are not inherently misoriented for failure like the more common subvertical reverse fault-related deposits, they may be sites of significant pressure buildup due to hydrothermal mineral precipitation during initial water-rock interaction or slight temperature decreases along the low-angle flow path. Resulting fluid cycling may lead to thick laminated vein development, such as seen at San Albino, where especially high-grade zones may be associated with local steepening and/or dilational zones within the broader, low-angle vein-hosting shear system.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"71 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140135939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiao-Chun Li, Hong-Rui Fan, Jian-Hui Su, David I. Groves, Kui-Feng Yang, Xin-Fu Zhao
The giant Bayan Obo deposit in China represents the largest rare earth element (REE) resource in the world, but the mechanisms for its highly anomalous REE enrichment have long been controversial. The central debate concerns the nature and origin of the ore-hosting dolomite. In this study, a texturally constrained microanalytical study of carbonate minerals from the Bayan Obo ore-hosting dolomite is presented to resolve this controversy.The dolomite rocks contain two major components: the early-stage coarse-grained dolomite (CD) and the late-stage fine-grained dolomite (FD). The CD dolomite grains have C-O isotope ratios (δ<sup>13</sup>C<sub>Vienna-PeeDee Belemnite (V-PDB)</sub>: –4.8 to –3.3‰; δ<sup>18</sup>O<sub>Vienna-standard mean ocean water (V-SMOW)</sub>: 7.1 to 11.9‰) plotting in or adjacent to the primary igneous carbonatite field, with a narrow range of low <sup>87</sup>Sr/<sup>86</sup>Sr ratios (0.70262–0.70327). The mantle-like C-O and Sr isotopes indicate that the coarse-grained dolomite rocks are magmatic in origin. Dolomite grains from the FD have experienced extensive hydrothermal alteration related to both REE mineralization and post-ore metamorphism of the Bayan Obo deposit. The domains of primary unaltered dolomite have high SrO and MnO contents that clearly distinguish them from sedimentary carbonates. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios of unaltered dolomite domains range from 0.70271 to 0.70473, with the majority lower than 0.7035, contrasting with higher <sup>87</sup>Sr/<sup>86</sup>Sr ratios of Mesoproterozoic sedimentary carbonates globally. Thus, the primary unaltered fine-grained dolomite, the precursor to the FD, is also proposed to be a carbonatite.Compared with dolomite grains from the CD, most of the unaltered dolomite domains within the FD are more enriched in FeO and MnO and have higher δ<sup>13</sup>C<sub>V-PDB</sub> (-4.9 to 0.3 ‰) and δ<sup>18</sup>O<sub>V-SMOW</sub> (9.4 to 17.1 ‰) values. In addition, the FD contains abundant REE- and volatile-rich hydrothermal minerals and Fe-Mg carbonates, which are rare in the CD. The geochemical and mineralogical data in conjunction indicate that the melts forming the late-stage FD were much more evolved than those forming the early-stage CD. It is noteworthy that the unaltered dolomite domains within the FD have a wider range of <sup>87</sup>Sr/<sup>86</sup>Sr ratios than those within the CD, which implies that the CD and FD, at least a proportion of them, are unlikely to have crystallized from the same progenitor magmas. Some FD was possibly the product of fractionation of less-evolved carbonatitic magma that generated the CD, whereas other FD crystallized from new pulses of magmas that were highly fractionated at depth.When compared with other carbonatite complexes, the Bayan Obo carbonatite suite is notable for having a large surface area (~48 km<sup>2</sup> in outcrop) and containing an anomalously large proportion of highly evolved components. The voluminous
中国的巴彦鄂博巨型矿床是世界上最大的稀土元素（REE）资源，但其稀土元素高度异常富集的机制长期以来一直存在争议。争论的焦点是矿床白云岩的性质和来源。本研究对巴彦奥博矿床白云岩中的碳酸盐矿物进行了纹理约束显微分析研究，以解决这一争议。白云岩包含两个主要成分：早期粗粒白云岩（CD）和晚期细粒白云岩（FD）。CD白云岩颗粒的C-O同位素比值（δ13C维也纳-皮迪白云岩（V-PDB）：-4.8至-3.3‰；δ18OV维也纳-标准平均海水（V-SMOW）：7.1至11.9‰）：7.1至11.9‰），分布在原生火成碳酸盐岩场内或附近，87Sr/86Sr比值范围较窄（0.70262-0.70327）。类似地幔的 C-O 和 Sr 同位素表明，粗粒白云岩源于岩浆。来自 FD 的白云岩颗粒经历了广泛的热液蚀变，这与 REE 矿化和巴彦奥博矿床的矿后变质作用有关。原生未蚀变白云岩域的氧化硅和氧化锰含量较高，明显有别于沉积碳酸盐岩。未变质白云岩岩域的 87Sr/86Sr 比率在 0.70271 至 0.70473 之间，大部分低于 0.7035，与全球中新生代沉积碳酸盐岩较高的 87Sr/86Sr 比率形成鲜明对比。与CD中的白云岩颗粒相比，FD中的大部分未变质白云岩域富含更多的FeO和MnO，具有更高的δ13CV-PDB（-4.9至0.3‰）和δ18OV-SMOW（9.4至17.1‰）值。此外，FD 含有大量富含 REE 和挥发性的热液矿物和铁镁碳酸盐，这在 CD 中是罕见的。地球化学和矿物学数据共同表明，形成晚期FD的熔体要比形成早期CD的熔体进化得多。值得注意的是，FD 中未发生变化的白云岩域的 87Sr/86Sr 比值范围比 CD 中的更宽，这意味着 CD 和 FD（至少其中一部分）不太可能是由相同的原生岩浆结晶而成。一些FD可能是生成CD的低演化碳酸盐岩浆分馏的产物，而其他FD则是从深部高度分馏的新岩浆脉冲中结晶出来的。与其他碳酸盐岩群相比，巴彦奥博碳酸盐岩群的显著特点是表面积大（露头面积约48平方公里），而且含有异常大比例的高度演化成分。大量的演化碳酸盐岩显然为大量矿石金属的积累提供了基础。因此，建议巴彦奥博的巨型 REE 矿床与大体积、高演化碳酸盐岩有关。
{"title":"Giant Rare Earth Element Accumulation Related to Voluminous, Highly Evolved Carbonatite: A Microanalytical Study of Carbonate Minerals From the Bayan Obo Deposit, China","authors":"Xiao-Chun Li, Hong-Rui Fan, Jian-Hui Su, David I. Groves, Kui-Feng Yang, Xin-Fu Zhao","doi":"10.5382/econgeo.5060","DOIUrl":"https://doi.org/10.5382/econgeo.5060","url":null,"abstract":"The giant Bayan Obo deposit in China represents the largest rare earth element (REE) resource in the world, but the mechanisms for its highly anomalous REE enrichment have long been controversial. The central debate concerns the nature and origin of the ore-hosting dolomite. In this study, a texturally constrained microanalytical study of carbonate minerals from the Bayan Obo ore-hosting dolomite is presented to resolve this controversy.The dolomite rocks contain two major components: the early-stage coarse-grained dolomite (CD) and the late-stage fine-grained dolomite (FD). The CD dolomite grains have C-O isotope ratios (δ<sup>13</sup>C<sub>Vienna-PeeDee Belemnite (V-PDB)</sub>: –4.8 to –3.3‰; δ<sup>18</sup>O<sub>Vienna-standard mean ocean water (V-SMOW)</sub>: 7.1 to 11.9‰) plotting in or adjacent to the primary igneous carbonatite field, with a narrow range of low <sup>87</sup>Sr/<sup>86</sup>Sr ratios (0.70262–0.70327). The mantle-like C-O and Sr isotopes indicate that the coarse-grained dolomite rocks are magmatic in origin. Dolomite grains from the FD have experienced extensive hydrothermal alteration related to both REE mineralization and post-ore metamorphism of the Bayan Obo deposit. The domains of primary unaltered dolomite have high SrO and MnO contents that clearly distinguish them from sedimentary carbonates. The <sup>87</sup>Sr/<sup>86</sup>Sr ratios of unaltered dolomite domains range from 0.70271 to 0.70473, with the majority lower than 0.7035, contrasting with higher <sup>87</sup>Sr/<sup>86</sup>Sr ratios of Mesoproterozoic sedimentary carbonates globally. Thus, the primary unaltered fine-grained dolomite, the precursor to the FD, is also proposed to be a carbonatite.Compared with dolomite grains from the CD, most of the unaltered dolomite domains within the FD are more enriched in FeO and MnO and have higher δ<sup>13</sup>C<sub>V-PDB</sub> (-4.9 to 0.3 ‰) and δ<sup>18</sup>O<sub>V-SMOW</sub> (9.4 to 17.1 ‰) values. In addition, the FD contains abundant REE- and volatile-rich hydrothermal minerals and Fe-Mg carbonates, which are rare in the CD. The geochemical and mineralogical data in conjunction indicate that the melts forming the late-stage FD were much more evolved than those forming the early-stage CD. It is noteworthy that the unaltered dolomite domains within the FD have a wider range of <sup>87</sup>Sr/<sup>86</sup>Sr ratios than those within the CD, which implies that the CD and FD, at least a proportion of them, are unlikely to have crystallized from the same progenitor magmas. Some FD was possibly the product of fractionation of less-evolved carbonatitic magma that generated the CD, whereas other FD crystallized from new pulses of magmas that were highly fractionated at depth.When compared with other carbonatite complexes, the Bayan Obo carbonatite suite is notable for having a large surface area (~48 km<sup>2</sup> in outcrop) and containing an anomalously large proportion of highly evolved components. The voluminous ","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"22 1","pages":""},"PeriodicalIF":5.8,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140096921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kaixuan Hui, Bertrand Rottier, Kezhang Qin, Zoltan Zajacz, Alexandra Tsay, Junxing Zhao, Shen Gao, Ruizhe Shi
Magmatic-related epithermal silver-rich polymetallic deposits are among the most important sources of Ag in the world, and they are found associated with magmatic systems with striking differences. Most of the time, they are associated either with I-type oxidized (magnetite-series granite) intermediate to evolved intrusions or with S-type/A-type reduced (ilmenite-series granite) highly evolved intrusions. To better understand these associations, the Ag evolution has been tracked during the magmatic differentiation and the magmatic-hydrothermal transition stage of A-type highly evolved porphyritic granites associated with the giant Shuangjianzishan Ag-Pb-Zn-(Sn) epithermal deposit, the largest known Ag deposit of Asia (145 million tonnes at 128.5 g/t Ag and 2.2 wt % Pb + Zn) located in the largest known metallogenic province for Ag in China (the southern Great Xing’an Range). At the Shuangjianzishan deposit, the porphyritic granite complex consists of three temporally distinct intrusions—a coarse-grained monzogranite porphyry, a fine-grained syenogranite porphyry, and a fine-grained syenogranite—having crystallized at ~2 kbar and ~750°C and recording a continuous magmatic differentiation trend. The silicate melt that generated the last highly differentiated intrusion (fine-grained syenogranite) is interpreted as the source of the mineralizing fluids forming the Shuangjianzishan Ag-Pb-Zn-(Sn) epithermal deposit, as it is the only intrusive unit that reached fluid saturation, as indicated by cotrapped fluid and melt inclusions in quartz phenocrysts and by the occurrences of unidirectional solidification textures (USTs). Silver evolution in the different porphyritic granite facies was reconstructed with laser ablation-inductively coupled plasma-mass spectrometry analyses of quartz-hosted silicate melt inclusions, amphibole-hosted magmatic sulfide inclusions, and chemical modeling. The silicate melt forming the porphyritic granite complex was sulfide saturated during the first crystallization stage, as shown by the occurrence of Ag-rich monosulfide solid solution (MSS) inclusions hosted in amphibole phenocrysts from the coarse-grained monzogranite porphyry and from mafic microgranular enclaves hosted in the coarse-grained monzogranite porphyry. However, these Ag-rich MSSs had only a minimal impact on the Ag budget of the magmatic system, as shown by the increase of the Ag concentration (~100–1,000 ppb) in quartz-hosted silicate melt inclusions during the further evolution of the system until fluid exsolution was reached. These results combined with mass balance modeling suggest that Ag and Sn are efficiently transferred to the evolving residual melt during crystallization and crystal-melt segregation. The results of this study indicate that highly Ag endowed epithermal polymetallic deposits can be formed from the exsolution of Ag-rich mineralizing fluids from relatively low volume, highly evolved, reduced melts, similar to those responsible for the fo
与岩浆有关的表生富银多金属矿床是世界上最重要的银矿来源之一，这些矿床与岩浆系统伴生，差异显著。大多数情况下，它们要么与 I 型氧化（磁铁矿系列花岗岩）中进化侵入体有关，要么与 S 型/A 型还原（钛铁矿系列花岗岩）高度进化侵入体有关。为了更好地理解这些关联，我们对与巨大的双剑子山银-铅-锌-（锡）热液矿床相关的 A 型高度演化斑状花岗岩的岩浆分异和岩浆-热液转换阶段的银演化进行了追踪，该矿床是亚洲已知最大的银矿床（1.45 亿吨，银品位 128.5 克/吨，铅锌品位 2.2 重量%），位于中国已知最大的银成矿省（大兴安岭南部）。在双剑子山矿床，斑状花岗岩复合体由三个时间上截然不同的侵入体组成--粗粒单斜斑岩、细粒正长斑岩和细粒正长斑岩--它们在大约2千巴和大约750摄氏度的温度下结晶，并记录了连续的岩浆分异趋势。生成最后一个高度分异侵入体（细粒正长花岗岩）的硅酸盐熔体被解释为形成双剑子山银-铅-锌-（锡）热液矿床的成矿流体的来源，因为它是唯一达到流体饱和的侵入体单元，石英表晶中的共包裹体和熔体包裹体以及出现的单向凝固纹理（UST）都表明了这一点。通过对石英寄生硅酸盐熔体包裹体、闪石寄生岩浆硫化物包裹体的激光烧蚀-电感耦合等离子体-质谱分析以及化学建模，重建了不同斑状花岗岩岩相中银的演化过程。形成斑状花岗岩复合体的硅酸盐熔体在第一结晶阶段硫化物饱和，这表现在粗粒单斜斑岩中的闪石表晶和粗粒单斜斑岩中的黑云母微晶包体中都有富含Ag的单硫化物固溶体（MSS）包裹体。然而，这些富含Ag的MSS对岩浆系统Ag预算的影响微乎其微，这表现在系统进一步演化直至流体外溶解过程中，石英寄存硅酸盐熔体包裹体中Ag浓度的增加（约100-1000ppb）。这些结果与质量平衡模型相结合表明，在结晶和晶体-熔体偏析过程中，银和锡被有效地转移到不断演化的残余熔体中。这项研究结果表明，富含银的表生多金属矿床可以通过富含银的成矿流体从体积相对较小、高度演化的还原熔体中溶出而形成，这与富含锡的绿森矿床的形成过程类似。
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