Porphyry-related mineral deposits are giant geochemical anomalies in the Earth’s crust with orders-of-magnitude differences in the content and proportion of the three main ore metals Cu, Au, and Mo. Deposit formation a few kilometers below surface is the product of a chain of geologic processes operating at different scales in space and time. This paper explores each process in this chain with regard to optimizing the chances of forming these rare anomalies. On the lithosphere scale, deposits with distinct metal ratios occur in provinces that formed during brief times of change in plate motions. Similar metal ratios of several deposits in such provinces compared with global rock reservoirs suggest preceding enrichment of Au or Mo in lithospheric regions giving rise to distinct ore provinces. The largest Cu-dominated deposits and provinces are traditionally explained by selective removal of Au during generation or subsequent evolution of mantle magmas, but the possibility of selective Cu pre-enrichment of lithosphere regions by long-term subduction cannot be dismissed, even though its mechanism remains speculative. Evolution of hydrous basaltic melts to fertile magmas forming porphyry Cu deposits requires fractionation toward more H2O-rich magmas in the lower crust, as shown by their adakite-like trace element composition. The prevailing interpretation that this fractionation leads to significant loss of chalcophile ore metals by saturation and removal of magmatic sulfide might be inverted to a metal enrichment step, if the saturating sulfides are physically entrained with the melt fraction of rapidly ascending magmas. Ascent of fertile magma delivers a large mass of H2O-rich ore fluid to the upper crust, along points of weakness in an overall compressive stress regime, within a limited duration as required by mass and heat balance constraints. Two mechanisms of rapid magma ascent are in debate: (1) wholesale emplacement of highly fractionated and volatile-rich granitic melt into a massive transcrustal channelway, from which fluids are exsolved by decompression starting in the lower crust, or (2) partly fractionated magmas filling a large upper crustal magma chamber, from which fluids are expelled by cooling and crystallization. Transfer of ore-forming components to a hydrothermal ore fluid is optimized if the first saturating fluid is dense and Cl rich. This can be achieved by fluid saturation at high pressure, or after a moderately H2O rich intermediate-composition melt further crystallizes in an upper crustal reservoir before reaching fluid saturation. In either case, metals and S (needed for later hydrothermal sulfide precipitation) are transferred to the fluid together, no matter whether ore components are extracted from the silicate melt or liberated to the ore fluid by decomposition of magmatic sulfides. Production and physical focusing of fluids in a crystallizing upper crustal magma chamber are controlled by the rate of heat loss t
{"title":"The Chain of Processes Forming Porphyry Copper Deposits—An Invited Paper","authors":"Christoph A. Heinrich","doi":"10.5382/econgeo.5069","DOIUrl":"https://doi.org/10.5382/econgeo.5069","url":null,"abstract":"\u0000 Porphyry-related mineral deposits are giant geochemical anomalies in the Earth’s crust with orders-of-magnitude differences in the content and proportion of the three main ore metals Cu, Au, and Mo. Deposit formation a few kilometers below surface is the product of a chain of geologic processes operating at different scales in space and time. This paper explores each process in this chain with regard to optimizing the chances of forming these rare anomalies.\u0000 On the lithosphere scale, deposits with distinct metal ratios occur in provinces that formed during brief times of change in plate motions. Similar metal ratios of several deposits in such provinces compared with global rock reservoirs suggest preceding enrichment of Au or Mo in lithospheric regions giving rise to distinct ore provinces. The largest Cu-dominated deposits and provinces are traditionally explained by selective removal of Au during generation or subsequent evolution of mantle magmas, but the possibility of selective Cu pre-enrichment of lithosphere regions by long-term subduction cannot be dismissed, even though its mechanism remains speculative.\u0000 Evolution of hydrous basaltic melts to fertile magmas forming porphyry Cu deposits requires fractionation toward more H2O-rich magmas in the lower crust, as shown by their adakite-like trace element composition. The prevailing interpretation that this fractionation leads to significant loss of chalcophile ore metals by saturation and removal of magmatic sulfide might be inverted to a metal enrichment step, if the saturating sulfides are physically entrained with the melt fraction of rapidly ascending magmas.\u0000 Ascent of fertile magma delivers a large mass of H2O-rich ore fluid to the upper crust, along points of weakness in an overall compressive stress regime, within a limited duration as required by mass and heat balance constraints. Two mechanisms of rapid magma ascent are in debate: (1) wholesale emplacement of highly fractionated and volatile-rich granitic melt into a massive transcrustal channelway, from which fluids are exsolved by decompression starting in the lower crust, or (2) partly fractionated magmas filling a large upper crustal magma chamber, from which fluids are expelled by cooling and crystallization.\u0000 Transfer of ore-forming components to a hydrothermal ore fluid is optimized if the first saturating fluid is dense and Cl rich. This can be achieved by fluid saturation at high pressure, or after a moderately H2O rich intermediate-composition melt further crystallizes in an upper crustal reservoir before reaching fluid saturation. In either case, metals and S (needed for later hydrothermal sulfide precipitation) are transferred to the fluid together, no matter whether ore components are extracted from the silicate melt or liberated to the ore fluid by decomposition of magmatic sulfides.\u0000 Production and physical focusing of fluids in a crystallizing upper crustal magma chamber are controlled by the rate of heat loss t","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141396632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Eileena Das, Dipak C Pal, D. Upadhyay, Aparajita Tripathi, Vijendra Kashyap, Kastoor Meena
The Kayad Zn-Pb deposit, situated within the Proterozoic Aravalli-Delhi fold belt in western India, is primarily characterized by sphalerite and galena along with pyrrhotite and chalcopyrite. The mineralization occurs as disseminated ores in quartzite, disseminated/laminated and massive ores in quartz-mica schist, and in pegmatite and quartz veins. The laminated ores conform to the regional schistosity and folding, whereas the massive Zn-Pb ores postdate the pervasive tectonic fabric, accumulating at the fold hinges. The massive ore is characterized by durchbewegung texture, discrete blebs of galena and chalcopyrite in a sphalerite matrix with low interfacial angles, and discrete intergrowths of sulfides and sulfosalts such as pyrargyrite, gudmundite, Ag-tetrahedrite, and breithauptite. Geochemical analyses of sulfides reveal microinclusions of sulfosalts comprising Ag, Sb, Cu, Tl, and As, which are regarded as low-melting chalcophile elements (LMCEs). Hydrothermal alteration is insignificant in the laminated and massive ores but prominent around Fe-Cu ± Zn-Pb and Zn-Pb ± Fe-Cu veins. The alteration assemblages in these veins evince a pervasive K + Na ± Fe alteration, later overprinted by a subsidiary Ca ± Na alteration. We interpret the laminated/disseminated ores to be of syndiagenetic sedimentary-exhalative (SedEx) origin formed within an euxinic basin. Conversely, the textural features, mineralogical composition, lack of associated hydrothermal alterations, and evident structural influence on the emplacement of the massive ores suggest they have been remobilized both via plastic flow and by sulfide partial melting. Temperature estimates of up to 650°C, derived from Ti-in-biotite geothermometry of the metamorphosed host rocks, indicate lower-middle amphibolite facies conditions during regional metamorphism. The initiation of melting at these temperatures was promoted by the desulfurization of pyrite to pyrrhotite in quartz-mica schist, aided by melting point depression due to the presence of LMCEs like Ag, Sb, and As.
卡亚德锌铅矿床位于印度西部新生代阿拉瓦利-德里褶皱带，主要特征是闪锌矿和方铅矿以及黄铁矿和黄铜矿。矿化物以散粒矿石形式出现在石英岩中，以散粒/层状和块状矿石形式出现在石英云母片岩中，以及伟晶岩和石英脉中。层状矿石与区域片岩和褶皱相一致，而块状锌铅矿则是在普遍构造结构形成之后才出现的，在褶皱铰链处堆积。块状矿石的特点是纹理不规则，闪锌矿基质中的方铅矿和黄铜矿呈不连续的斑点状，界面角较小，硫化物和硫化物（如黄铁矿、古蒙德石、银四面体矿和辉钼矿）呈不连续的互生。硫化物的地球化学分析显示，硫化物的微包裹体中含有Ag、Sb、Cu、Tl和As，这些元素被认为是低熔性亲铝元素（LMCEs）。热液蚀变在层状矿石和块状矿石中微不足道，但在铁-铜±锌-铅和锌-铅±铁-铜矿脉周围却很突出。这些矿脉中的蚀变组合显示出普遍的 K + Na ± Fe 蚀变，后来又被辅助的 Ca ± Na 蚀变所覆盖。我们认为，这些层状/解理矿石是在戊辛基盆地内形成的联合成因沉积-吸水（SedEx）矿石。相反，块状矿石的纹理特征、矿物成分、缺乏相关的热液蚀变以及明显的构造对其成矿的影响，都表明它们是通过塑性流动和硫化物部分熔融而重新移动的。根据变质主岩的钛-硼酸盐地热测定法得出的温度估计值高达 650°C，表明区域变质过程中的中下闪长岩面条件。石英云母片岩中的黄铁矿脱硫成黄铁矿的过程促进了这些温度下的熔化，而由于银、锑和砷等低熔点元素的存在，熔点降低也为熔化提供了帮助。
{"title":"Sulfide Remobilization in the Metamorphosed Kayad Sedimentary Exhalative Zn-Pb Deposit, Western India: Evidence from Mode of Occurrence, Texture, Hydrothermal Alteration Features, and Trace Element Chemistry","authors":"Eileena Das, Dipak C Pal, D. Upadhyay, Aparajita Tripathi, Vijendra Kashyap, Kastoor Meena","doi":"10.5382/econgeo.5075","DOIUrl":"https://doi.org/10.5382/econgeo.5075","url":null,"abstract":"\u0000 The Kayad Zn-Pb deposit, situated within the Proterozoic Aravalli-Delhi fold belt in western India, is primarily characterized by sphalerite and galena along with pyrrhotite and chalcopyrite. The mineralization occurs as disseminated ores in quartzite, disseminated/laminated and massive ores in quartz-mica schist, and in pegmatite and quartz veins. The laminated ores conform to the regional schistosity and folding, whereas the massive Zn-Pb ores postdate the pervasive tectonic fabric, accumulating at the fold hinges. The massive ore is characterized by durchbewegung texture, discrete blebs of galena and chalcopyrite in a sphalerite matrix with low interfacial angles, and discrete intergrowths of sulfides and sulfosalts such as pyrargyrite, gudmundite, Ag-tetrahedrite, and breithauptite. Geochemical analyses of sulfides reveal microinclusions of sulfosalts comprising Ag, Sb, Cu, Tl, and As, which are regarded as low-melting chalcophile elements (LMCEs). Hydrothermal alteration is insignificant in the laminated and massive ores but prominent around Fe-Cu ± Zn-Pb and Zn-Pb ± Fe-Cu veins. The alteration assemblages in these veins evince a pervasive K + Na ± Fe alteration, later overprinted by a subsidiary Ca ± Na alteration. We interpret the laminated/disseminated ores to be of syndiagenetic sedimentary-exhalative (SedEx) origin formed within an euxinic basin. Conversely, the textural features, mineralogical composition, lack of associated hydrothermal alterations, and evident structural influence on the emplacement of the massive ores suggest they have been remobilized both via plastic flow and by sulfide partial melting. Temperature estimates of up to 650°C, derived from Ti-in-biotite geothermometry of the metamorphosed host rocks, indicate lower-middle amphibolite facies conditions during regional metamorphism. The initiation of melting at these temperatures was promoted by the desulfurization of pyrite to pyrrhotite in quartz-mica schist, aided by melting point depression due to the presence of LMCEs like Ag, Sb, and As.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141412578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zinnwald/Cínovec is one of the largest Li-Sn-W greisen deposits in Europe. Greisens in general are important hosts for many major ore deposits of several high-tech elements—most prominently Sn, W, and Li. However, the mechanisms of greisenization in relationship to ore formation are still not well understood, especially for the important case of fluoride-rich greisen. Here, we investigate the sequence and formation mechanism of the topaz-greisen in the Zinnwald/Cínovec deposit. Based on the mineral abundances, the alteration profile can be divided into four distinct zones: (1) rhyolite, (2) albitite, (3) low-degree greisen, and (4) high-degree greisen. In the greisen zones, almost all the feldspar has been replaced by topaz (up to 12 vol %) + quartz (up to 78 vol %), and the abundance of mica gradually decreases from 11 to 3 vol % with increasing degree of greisenization. Mass balance calculations indicate a net influx of F and silica during greisenization. Our observations are best explained by a two-stage greisenization process involving phase separation by boiling in the pore space of the sample: first an acidic HF-rich phase, likely a vapor, reacted with feldspar to form topaz and quartz in a dissolution-precipitation reaction. This reaction created substantial transient porosity, which was subsequently sealed by the precipitation of quartz and fluorite from a boiling liquid. We interpret the vapor and liquid as emerging from a common supercritical aqueous parental fluid. The characteristic sequence of creation of pore space by a vapor and the subsequent reduction of porosity by precipitation from the associated boiling liquid constrain the conditions and time available for ore formation. This study evaluates the mechanism of topaz greisenization and the controls on porosity evolution, which are crucial to ore element redistribution.
{"title":"Formation of Topaz-Greisen by a Boiling Fluid: A Case Study from the Sn-W-Li Deposit, Zinnwald/Cínovec","authors":"Shilei Qiao, Timm John, A. Loges","doi":"10.5382/econgeo.5074","DOIUrl":"https://doi.org/10.5382/econgeo.5074","url":null,"abstract":"\u0000 Zinnwald/Cínovec is one of the largest Li-Sn-W greisen deposits in Europe. Greisens in general are important hosts for many major ore deposits of several high-tech elements—most prominently Sn, W, and Li. However, the mechanisms of greisenization in relationship to ore formation are still not well understood, especially for the important case of fluoride-rich greisen. Here, we investigate the sequence and formation mechanism of the topaz-greisen in the Zinnwald/Cínovec deposit. Based on the mineral abundances, the alteration profile can be divided into four distinct zones: (1) rhyolite, (2) albitite, (3) low-degree greisen, and (4) high-degree greisen. In the greisen zones, almost all the feldspar has been replaced by topaz (up to 12 vol %) + quartz (up to 78 vol %), and the abundance of mica gradually decreases from 11 to 3 vol % with increasing degree of greisenization. Mass balance calculations indicate a net influx of F and silica during greisenization.\u0000 Our observations are best explained by a two-stage greisenization process involving phase separation by boiling in the pore space of the sample: first an acidic HF-rich phase, likely a vapor, reacted with feldspar to form topaz and quartz in a dissolution-precipitation reaction. This reaction created substantial transient porosity, which was subsequently sealed by the precipitation of quartz and fluorite from a boiling liquid. We interpret the vapor and liquid as emerging from a common supercritical aqueous parental fluid. The characteristic sequence of creation of pore space by a vapor and the subsequent reduction of porosity by precipitation from the associated boiling liquid constrain the conditions and time available for ore formation. This study evaluates the mechanism of topaz greisenization and the controls on porosity evolution, which are crucial to ore element redistribution.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141390145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ji’en Zhang, Hongrui Fan, W. Xiao, Xingwang Xu, John Wakabayashi, Lili Zhang, Yonggang Zhao, Qiwei Wang, Yulong Zhao, Kaiyi Wang
The Bayan Obo ore deposit is the largest rare earth element (REE) deposit in the world and has been assumed to be hosted in dolomite that was folded in a syncline. This has been challenged by results from drill holes and low-resistivity, controlled-source audio-frequency magnetotellurics (CSAMT) survey. In this paper, we present structural analysis of clastic sedimentary rocks from around the deposit, their relationship with carbonatite, and the orientations of the carbonatite bodies and dikes to constrain the possible configuration of carbonatite. Clastic sedimentary rocks underwent mylonitic deformation to slate, metasandstone, and metaconglomerate, displaying dramatic changes of thickness along strike. Slates locally preserve intrafolial folds and hook folds bounded by foliations; metasandstones have parallel layers of recrystallized and preferred-orientated quartz aggregations; metaconglomerates contain flattened pebbles with Flinn k values of 0.01 to 0.05 and 0. The above structures and foliations were crosscut and intruded by carbonatite and associated fenite, demonstrating preintrusion transposition of original bedding to steep foliation. Preintrusion foliation provides zones of weakness that were exploited by upwelling of carbonatite magma. Northeast-SW–striking left-stepping en echelon carbonatite dikes and E-W–striking carbonatite bodies indicate that the carbonatite was emplaced in a sinistral transtensional zone. The northern and southern segments of the carbonatite bodies are parallel to the steep foliation at shallow depths and merge together at depth, constraining a Y-shaped configuration, consistent with the low resistivity result of the CSAMT survey. The newly recognized Y-shaped morphology indicates that the carbonatite extends deeper than 1,775.4 m, more than twice the previously inferred maximum depth of the syncline model, and contributes to a significant >1.78 times increase in global potential RE2O3 resources than previously estimated in 2021.
巴彦奥博矿床是世界上最大的稀土元素（REE）矿床，一直被假定为赋存于在一个向斜中褶皱的白云岩中。钻孔和低电阻率受控声源-频率磁测（CSAMT）勘测结果对这一假设提出了质疑。在本文中，我们介绍了对矿床周围碎屑沉积岩的结构分析、它们与碳酸盐岩的关系以及碳酸盐岩体和尖晶石的走向，以确定碳酸盐岩的可能构造。碎屑沉积岩经过熔岩化变形，形成板岩、元砂岩和元砾岩，厚度沿走向发生了巨大变化。板岩局部保留了叶片内褶皱和以褶皱为界的钩状褶皱；元砂岩具有平行的再结晶层和优选取向的石英集合体；元角砾岩含有扁平的鹅卵石，Flinn k值为0.01至0.05和0。上述结构和褶皱被碳酸盐岩和相关的栅栏岩横切和侵入，显示了侵入前将原始的层理转为陡峭的褶皱。侵入前的褶皱提供了薄弱区，碳酸岩浆的上涌利用了这些薄弱区。东北-西南走向的左旋梯状碳酸盐岩岩峰和东-西走向的碳酸盐岩体表明，碳酸盐岩是在一个正弦横断带中堆积的。碳酸盐岩体的北段和南段在浅层与陡峭的褶皱平行，在深层合并在一起，形成 Y 型构造，与 CSAMT 勘测的低电阻率结果一致。新发现的 Y 型形态表明，碳酸盐岩延伸到了 1775.4 米以上的深处，是之前推断的切线模型最大深度的两倍多，并使全球潜在 RE2O3 资源量比之前估计的 2021 年大幅增加了 >1.78 倍。
{"title":"Configuration of Carbonatite Constrained in Preintrusion Transpositional Foliation in the Bayan Obo Giant Rare Earth Element Deposit, China","authors":"Ji’en Zhang, Hongrui Fan, W. Xiao, Xingwang Xu, John Wakabayashi, Lili Zhang, Yonggang Zhao, Qiwei Wang, Yulong Zhao, Kaiyi Wang","doi":"10.5382/econgeo.5076","DOIUrl":"https://doi.org/10.5382/econgeo.5076","url":null,"abstract":"\u0000 The Bayan Obo ore deposit is the largest rare earth element (REE) deposit in the world and has been assumed to be hosted in dolomite that was folded in a syncline. This has been challenged by results from drill holes and low-resistivity, controlled-source audio-frequency magnetotellurics (CSAMT) survey. In this paper, we present structural analysis of clastic sedimentary rocks from around the deposit, their relationship with carbonatite, and the orientations of the carbonatite bodies and dikes to constrain the possible configuration of carbonatite. Clastic sedimentary rocks underwent mylonitic deformation to slate, metasandstone, and metaconglomerate, displaying dramatic changes of thickness along strike. Slates locally preserve intrafolial folds and hook folds bounded by foliations; metasandstones have parallel layers of recrystallized and preferred-orientated quartz aggregations; metaconglomerates contain flattened pebbles with Flinn k values of 0.01 to 0.05 and 0. The above structures and foliations were crosscut and intruded by carbonatite and associated fenite, demonstrating preintrusion transposition of original bedding to steep foliation. Preintrusion foliation provides zones of weakness that were exploited by upwelling of carbonatite magma. Northeast-SW–striking left-stepping en echelon carbonatite dikes and E-W–striking carbonatite bodies indicate that the carbonatite was emplaced in a sinistral transtensional zone. The northern and southern segments of the carbonatite bodies are parallel to the steep foliation at shallow depths and merge together at depth, constraining a Y-shaped configuration, consistent with the low resistivity result of the CSAMT survey. The newly recognized Y-shaped morphology indicates that the carbonatite extends deeper than 1,775.4 m, more than twice the previously inferred maximum depth of the syncline model, and contributes to a significant >1.78 times increase in global potential RE2O3 resources than previously estimated in 2021.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141401504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sava Markovic, Manuel Brunner, Lukas Müller, I. Peytcheva, M. Guillong, Cyril Chelle-Michou, K. Kouzmanov, D. Gallhofer, Christoph A. Heinrich, A. von Quadt
The Golden Quadrilateral of the Apuseni Mountains (Romania) represents the richest Au(-Cu-Te) porphyry and epithermal district of Europe and the Western Tethyan metallogenic belt. The Au(-Cu-Te) mineralization is associated with Neogene calc-alkaline magmatism along graben structures growing during the late stages of the Alpine-Carpathian orogeny. We use zircon petrochronology to study the time-space distribution, sources, composition, and timescales of the Au(-Cu-Te)-mineralizing magmatism and explore its link to regional tectonics. Our own and published U-Pb zircon ages document ore-forming magmatic activity between ~13.61 and 7.24 Ma. In combination with available paleomagnetic data, the new zircon ages corroborate the hypothesis that the magmatism in the Golden Quadrilateral evolved in a tectonic environment dominated by major (up to 70°) crustal block rotation. Hafnium isotope composition of Neogene zircon (εHf between –2 and 10) supports the predominant origin of the magmas from a heterogeneous lithospheric mantle, which may have been fertilized during an earlier Cretaceous subduction event and possibly by concurrent Miocene subduction. Xenocrystic zircon shows involvement of crustal sources resembling European continental basement. Fertility indicators, including Eu/Eu* and oxygen fugacity based on zircon composition, show no systematic correlation with the mineralizing events and/or age. High-precision (isotope dilution-thermal ionization mass spectrometry) U-Pb zircon geochronology demonstrates that the magmatic systems exposed at district scale evolved over less than ~100 k.y. and that durations of hydrothermal mineralization pulses were even shorter.
{"title":"Zircon Petrochronology of Au-Rich Porphyry and Epithermal Deposits in the Golden Quadrilateral (Apuseni Mountains, Romania)","authors":"Sava Markovic, Manuel Brunner, Lukas Müller, I. Peytcheva, M. Guillong, Cyril Chelle-Michou, K. Kouzmanov, D. Gallhofer, Christoph A. Heinrich, A. von Quadt","doi":"10.5382/econgeo.5073","DOIUrl":"https://doi.org/10.5382/econgeo.5073","url":null,"abstract":"\u0000 The Golden Quadrilateral of the Apuseni Mountains (Romania) represents the richest Au(-Cu-Te) porphyry and epithermal district of Europe and the Western Tethyan metallogenic belt. The Au(-Cu-Te) mineralization is associated with Neogene calc-alkaline magmatism along graben structures growing during the late stages of the Alpine-Carpathian orogeny. We use zircon petrochronology to study the time-space distribution, sources, composition, and timescales of the Au(-Cu-Te)-mineralizing magmatism and explore its link to regional tectonics. Our own and published U-Pb zircon ages document ore-forming magmatic activity between ~13.61 and 7.24 Ma. In combination with available paleomagnetic data, the new zircon ages corroborate the hypothesis that the magmatism in the Golden Quadrilateral evolved in a tectonic environment dominated by major (up to 70°) crustal block rotation. Hafnium isotope composition of Neogene zircon (εHf between –2 and 10) supports the predominant origin of the magmas from a heterogeneous lithospheric mantle, which may have been fertilized during an earlier Cretaceous subduction event and possibly by concurrent Miocene subduction. Xenocrystic zircon shows involvement of crustal sources resembling European continental basement. Fertility indicators, including Eu/Eu* and oxygen fugacity based on zircon composition, show no systematic correlation with the mineralizing events and/or age. High-precision (isotope dilution-thermal ionization mass spectrometry) U-Pb zircon geochronology demonstrates that the magmatic systems exposed at district scale evolved over less than ~100 k.y. and that durations of hydrothermal mineralization pulses were even shorter.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141394420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Miguel Tavares Nassif, Y. Kuiper, Richard J. Goldfarb, David Rhys, James L. Crowley, R. Creaser
The decrease in gold discoveries is affecting the deployment of new technology and the general society demand, demonstrating the need for new gold exploration approaches. To date, gold exploration remains primarily focused in areas near well-known large gold districts. We demonstrate the potential for new discoveries and significant resource expansion in the Abitibi greenstone belt distal from the giant gold districts across the belt. Unlocking of additional resources in the Garrison district was accomplished by identification of zones of compentency contrast, which resulted in a variety of locally complex and unrecognized structural traps receptive to gold. Our approach is applicable to other little-explored areas in the Abitibi greenstone belt and other orogenic belts worldwide. The Garrison district, situated in the southern part of the Abitibi greenstone belt in the Superior province, lies along an ~3-km NE-trending segment of the gold-rich, Archean Porcupine-Destor deformation zone. The district contains several discoveries, which include the Buffonta deposit hosted in mafic volcanic rocks, the syenite-hosted 903 deposit, and the albitite dike-hosted Jonpol deposit. These deposits occur along high-strain zones developed in embayments and elongate, NE-trending domains of talc-chlorite-serpentine–altered ultramafic rocks, which localized strands and splays of the Porcupine-Destor deformation zone. In addition, the Garrcon deposit comprises northerly-trending gold-bearing quartz veins and lamprophyre dike swarms hosted in sedimentary host rocks that are bounded by high-strain zones. The intrusive rocks in all of these deposits were emplaced prior to gold deposition. They provided a competent substrate in areas of heterogeneous strain that localized gold mineralization. Initial alteration made the surrounding volcanic and sedimentary rocks also rheologically competent. This resulted in enhanced hydrofracturing and the formation of paragenetically late gold-bearing quartz veins. Widespread albite-pyrite-carbonate alteration in all of the gold deposits temporally overlapped with gold mineralization. New U-Pb zircon geochronology data reveal that ~2719 to 2712 Ma volcanism was followed by granitic magmatism and emplacement of a series of ~2683 to 2672 Ma dikes. One Re-Os analysis of a synmineralization molybdenite sample indicates that orogenic gold was deposited at 2671 ± 12 Ma. This is comparable to published ages of major orogenic gold deposits throughout the southern part of the Abitibi greenstone belt, indicating a broadly synchronous principal gold event across the belt.
{"title":"Characterization and Timing of Mineralization in the Garrison Gold District, Southern Abitibi Greenstone Belt, Canada","authors":"Miguel Tavares Nassif, Y. Kuiper, Richard J. Goldfarb, David Rhys, James L. Crowley, R. Creaser","doi":"10.5382/econgeo.5072","DOIUrl":"https://doi.org/10.5382/econgeo.5072","url":null,"abstract":"\u0000 The decrease in gold discoveries is affecting the deployment of new technology and the general society demand, demonstrating the need for new gold exploration approaches. To date, gold exploration remains primarily focused in areas near well-known large gold districts. We demonstrate the potential for new discoveries and significant resource expansion in the Abitibi greenstone belt distal from the giant gold districts across the belt. Unlocking of additional resources in the Garrison district was accomplished by identification of zones of compentency contrast, which resulted in a variety of locally complex and unrecognized structural traps receptive to gold. Our approach is applicable to other little-explored areas in the Abitibi greenstone belt and other orogenic belts worldwide.\u0000 The Garrison district, situated in the southern part of the Abitibi greenstone belt in the Superior province, lies along an ~3-km NE-trending segment of the gold-rich, Archean Porcupine-Destor deformation zone. The district contains several discoveries, which include the Buffonta deposit hosted in mafic volcanic rocks, the syenite-hosted 903 deposit, and the albitite dike-hosted Jonpol deposit. These deposits occur along high-strain zones developed in embayments and elongate, NE-trending domains of talc-chlorite-serpentine–altered ultramafic rocks, which localized strands and splays of the Porcupine-Destor deformation zone. In addition, the Garrcon deposit comprises northerly-trending gold-bearing quartz veins and lamprophyre dike swarms hosted in sedimentary host rocks that are bounded by high-strain zones.\u0000 The intrusive rocks in all of these deposits were emplaced prior to gold deposition. They provided a competent substrate in areas of heterogeneous strain that localized gold mineralization. Initial alteration made the surrounding volcanic and sedimentary rocks also rheologically competent. This resulted in enhanced hydrofracturing and the formation of paragenetically late gold-bearing quartz veins. Widespread albite-pyrite-carbonate alteration in all of the gold deposits temporally overlapped with gold mineralization.\u0000 New U-Pb zircon geochronology data reveal that ~2719 to 2712 Ma volcanism was followed by granitic magmatism and emplacement of a series of ~2683 to 2672 Ma dikes. One Re-Os analysis of a synmineralization molybdenite sample indicates that orogenic gold was deposited at 2671 ± 12 Ma. This is comparable to published ages of major orogenic gold deposits throughout the southern part of the Abitibi greenstone belt, indicating a broadly synchronous principal gold event across the belt.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141396180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jonathan Rincon, Nils Jansson, Helen Thomas, M. Kaiser, M. Persson, Erik Nordfeldt, C. Wanhainen
The Skellefte district in northern Sweden hosts many volcanogenic massive sulfide (VMS) deposits and is considered one of the most important European mining districts for Cu, Zn, Pb, Ag, and Au. The volcanic and sedimentary rocks that the VMS deposits are hosted in were deformed during the Svecokarelian orogeny, with three documented regional deformation phases. These events imparted a distinct attitude and geometry to the deposits, their host succession, and discordant zones of synvolcanic hydrothermal alteration. Few studies have investigated the detailed deformation effects on the sulfide minerals. In this contribution, we document the structural characteristics and remobilization history of mineralization at the Rävliden North Zn-Pb-Cu-Ag deposit—one of the most important recent discoveries in the district consisting of 8.5 million tonnes (Mt) grading 1.01% Cu, 3.45% Zn, 0.53% Pb, 78.60 g/t Ag, and 0.23 g/t Au. At Rävliden, massive to semimassive sphalerite-rich mineralization with lesser pyrrhotite, galena, pyrite, and silver minerals occurs structurally above stringer-type mineralization dominated by chalcopyrite, pyrrhotite, and pyrite. These mineralization types exhibit evidence of deformation and remobilization such as (1) sulfide-alignment parallel to tectonic foliations; (2) rounded wall-rock tectonoclasts in a ductile deformed sulfide matrix (“ball ore” or durchbewegt ore); and (3) sulfides in tension gashes, strain shadows, piercement veins, and late, straight veinlets crosscutting tectonic fabrics. These features are attributed to polyphase deformation during the D1, D2, and D3 events at temperature ranging from 200° to 550°C. Remobilization of sulfides was mostly within the bounds of the main mineralization (i.e., 10–100 m), with few local external occurrences. A combination of solid-state and fluid-assisted remobilization processes are inferred. Rare brittle veinlets and zeolite-cemented breccias with sphalerite, galena, and silver minerals occur in the stratigraphic hanging wall, where they crosscut all Svecokarelian structures. This mineralization type is highly reminiscent of Phanerozoic low-T vein- and breccia-hosted Pb-Zn deposits of the Lycksele-Storuman area west of Rävliden North, which have been linked to far-field effects associated with the opening of the Iapetus Ocean (0.7–0.5 Ga). We suggest that this Zn-Pb mineralizing event led to the formation of the late sulfide-zeolite veinlets and breccias at Rävliden North, and that elements such as Ag and Sb within this mineralization were locally remobilized from Rävliden.
{"title":"Ore Remobilization History of the Metamorphosed Rävliden North Volcanogenic Massive Sulfide Deposit, Skellefte District, Sweden","authors":"Jonathan Rincon, Nils Jansson, Helen Thomas, M. Kaiser, M. Persson, Erik Nordfeldt, C. Wanhainen","doi":"10.5382/econgeo.5083","DOIUrl":"https://doi.org/10.5382/econgeo.5083","url":null,"abstract":"\u0000 The Skellefte district in northern Sweden hosts many volcanogenic massive sulfide (VMS) deposits and is considered one of the most important European mining districts for Cu, Zn, Pb, Ag, and Au. The volcanic and sedimentary rocks that the VMS deposits are hosted in were deformed during the Svecokarelian orogeny, with three documented regional deformation phases. These events imparted a distinct attitude and geometry to the deposits, their host succession, and discordant zones of synvolcanic hydrothermal alteration. Few studies have investigated the detailed deformation effects on the sulfide minerals.\u0000 In this contribution, we document the structural characteristics and remobilization history of mineralization at the Rävliden North Zn-Pb-Cu-Ag deposit—one of the most important recent discoveries in the district consisting of 8.5 million tonnes (Mt) grading 1.01% Cu, 3.45% Zn, 0.53% Pb, 78.60 g/t Ag, and 0.23 g/t Au. At Rävliden, massive to semimassive sphalerite-rich mineralization with lesser pyrrhotite, galena, pyrite, and silver minerals occurs structurally above stringer-type mineralization dominated by chalcopyrite, pyrrhotite, and pyrite. These mineralization types exhibit evidence of deformation and remobilization such as (1) sulfide-alignment parallel to tectonic foliations; (2) rounded wall-rock tectonoclasts in a ductile deformed sulfide matrix (“ball ore” or durchbewegt ore); and (3) sulfides in tension gashes, strain shadows, piercement veins, and late, straight veinlets crosscutting tectonic fabrics. These features are attributed to polyphase deformation during the D1, D2, and D3 events at temperature ranging from 200° to 550°C. Remobilization of sulfides was mostly within the bounds of the main mineralization (i.e., 10–100 m), with few local external occurrences. A combination of solid-state and fluid-assisted remobilization processes are inferred.\u0000 Rare brittle veinlets and zeolite-cemented breccias with sphalerite, galena, and silver minerals occur in the stratigraphic hanging wall, where they crosscut all Svecokarelian structures. This mineralization type is highly reminiscent of Phanerozoic low-T vein- and breccia-hosted Pb-Zn deposits of the Lycksele-Storuman area west of Rävliden North, which have been linked to far-field effects associated with the opening of the Iapetus Ocean (0.7–0.5 Ga). We suggest that this Zn-Pb mineralizing event led to the formation of the late sulfide-zeolite veinlets and breccias at Rävliden North, and that elements such as Ag and Sb within this mineralization were locally remobilized from Rävliden.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141415616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aiguo Shi, Cheng Xu, Chaoxi Fan, A. Chakhmouradian, M. Brenna, Chun-wan Wei
Heavy rare earth elements (HREEs), an indispensable resource for modern industry, are extracted mainly from clays in ion adsorption deposits (IADs) in South China. The HREEs in IADs are derived from accessory minerals in parental granites. These precursor HREE phases have low solubility in aqueous environments, and unraveling the mechanism of their decomposition during weathering is critical to understanding how IADs form. Here, we report the micro- to nanoscale structural characteristics of HREE precursor minerals in parental granites from the large Zudong and Zhaibei IADs. High-resolution transmission electron microscopy shows that these minerals are characterized by abundant structural defects that range from lattice dislocations to submicro- to nanoscale crystallite aggregates with a variable proportion of amorphous material. Ubiquitous structural defects make the precursor HREE minerals unstable during weathering, resulting in their rapid decomposition, thereby facilitating the development of clay-hosted mineralization.
{"title":"Structural Defects of Heavy Rare Earth Element Minerals in Granite Accelerate Their Decomposition and Facilitate Mineralization During Weathering","authors":"Aiguo Shi, Cheng Xu, Chaoxi Fan, A. Chakhmouradian, M. Brenna, Chun-wan Wei","doi":"10.5382/econgeo.5057","DOIUrl":"https://doi.org/10.5382/econgeo.5057","url":null,"abstract":"\u0000 Heavy rare earth elements (HREEs), an indispensable resource for modern industry, are extracted mainly from clays in ion adsorption deposits (IADs) in South China. The HREEs in IADs are derived from accessory minerals in parental granites. These precursor HREE phases have low solubility in aqueous environments, and unraveling the mechanism of their decomposition during weathering is critical to understanding how IADs form. Here, we report the micro- to nanoscale structural characteristics of HREE precursor minerals in parental granites from the large Zudong and Zhaibei IADs. High-resolution transmission electron microscopy shows that these minerals are characterized by abundant structural defects that range from lattice dislocations to submicro- to nanoscale crystallite aggregates with a variable proportion of amorphous material. Ubiquitous structural defects make the precursor HREE minerals unstable during weathering, resulting in their rapid decomposition, thereby facilitating the development of clay-hosted mineralization.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141409752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dino Leopardi, Jens Gutzmer, Bernd Lehmann, M. Burisch
The Sadisdorf Li-Sn-(W-Cu) prospect in eastern Germany is characterized by vein- and greisen-style mineralization hosted in and around a small granite stock that intruded into a shallow crustal environment. The nature and origin of this mineral system are evaluated in this contribution by a combination of petrography and fluid inclusion studies, complemented by Raman spectroscopy and whole-rock geochemical analyses. The early magmatic-hydrothermal evolution is characterized by a single-phase low-salinity (7.0 ± 4 wt % NaCl equiv), high-temperature (>340°C), CO2-CH4–bearing aqueous fluid, which caused greisen alteration and mineralization within the apical portions of the microgranite porphyry. The bimodal distribution of brine and vapor fluid inclusions, and the formation of a magmatic-hydrothermal breccia associated with the proximal vein mineralization are interpreted to mark the transition from lithostatic to hydrostatic pressure. The vein- and stockwork-style mineralization (main stage) displays lateral zonation, with quartz-cassiterite-wolframite-molybdenite mineral assemblages grading outward into base-metal sulfide-dominated assemblages with increasing distance from the intrusion. Late fluorite-bearing veinlets represent the waning stage in the evolution of the mineral system. The similarity in the homogenization temperature (250°–418°C) of fluid inclusions in quartz, cassiterite, and sphalerite across the Sadisdorf deposit suggests that cooling was not a significant factor in the mineral zonation. Instead, fluid-rock interaction along the fluid path is considered to have controlled this zonation. In contrast to quartz-, cassiterite- and sphalerite-hosted fluid inclusions, which have a salinity of 0.0 to 10.0 wt % NaCl equiv, the fluid inclusions in late fluorite veins that overprint all previous assemblages have a salinity of 0.0 to 3.0 wt % NaCl equiv and homogenize at temperatures of 120° to 270°C, thus indicating cooling with or without admixture of meteoric fluids during the waning stage of the mineral system. The Sadisdorf deposit shares similar characteristics with other deposits in the Erzgebirge region, including a shallow level of emplacement, similar mineralization/alteration styles, and a hydrothermal evolution that includes early-boiling, fluid-rock interaction, and late cooling. In contrast to most systems in the region, both proximal and distal mineralization are well preserved at Sadisdorf. The recognition of such spatial zoning may be a useful criterion for targeting greisen-related Li and Sn resources.
{"title":"The Spatial and Temporal Evolution of the Sadisdorf Li-Sn-(W-Cu) Magmatic-Hydrothermal Greisen and Vein System, Eastern Erzgebirge, Germany","authors":"Dino Leopardi, Jens Gutzmer, Bernd Lehmann, M. Burisch","doi":"10.5382/econgeo.5077","DOIUrl":"https://doi.org/10.5382/econgeo.5077","url":null,"abstract":"\u0000 The Sadisdorf Li-Sn-(W-Cu) prospect in eastern Germany is characterized by vein- and greisen-style mineralization hosted in and around a small granite stock that intruded into a shallow crustal environment. The nature and origin of this mineral system are evaluated in this contribution by a combination of petrography and fluid inclusion studies, complemented by Raman spectroscopy and whole-rock geochemical analyses. The early magmatic-hydrothermal evolution is characterized by a single-phase low-salinity (7.0 ± 4 wt % NaCl equiv), high-temperature (>340°C), CO2-CH4–bearing aqueous fluid, which caused greisen alteration and mineralization within the apical portions of the microgranite porphyry. The bimodal distribution of brine and vapor fluid inclusions, and the formation of a magmatic-hydrothermal breccia associated with the proximal vein mineralization are interpreted to mark the transition from lithostatic to hydrostatic pressure. The vein- and stockwork-style mineralization (main stage) displays lateral zonation, with quartz-cassiterite-wolframite-molybdenite mineral assemblages grading outward into base-metal sulfide-dominated assemblages with increasing distance from the intrusion. Late fluorite-bearing veinlets represent the waning stage in the evolution of the mineral system. The similarity in the homogenization temperature (250°–418°C) of fluid inclusions in quartz, cassiterite, and sphalerite across the Sadisdorf deposit suggests that cooling was not a significant factor in the mineral zonation. Instead, fluid-rock interaction along the fluid path is considered to have controlled this zonation. In contrast to quartz-, cassiterite- and sphalerite-hosted fluid inclusions, which have a salinity of 0.0 to 10.0 wt % NaCl equiv, the fluid inclusions in late fluorite veins that overprint all previous assemblages have a salinity of 0.0 to 3.0 wt % NaCl equiv and homogenize at temperatures of 120° to 270°C, thus indicating cooling with or without admixture of meteoric fluids during the waning stage of the mineral system. The Sadisdorf deposit shares similar characteristics with other deposits in the Erzgebirge region, including a shallow level of emplacement, similar mineralization/alteration styles, and a hydrothermal evolution that includes early-boiling, fluid-rock interaction, and late cooling. In contrast to most systems in the region, both proximal and distal mineralization are well preserved at Sadisdorf. The recognition of such spatial zoning may be a useful criterion for targeting greisen-related Li and Sn resources.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141403251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. A. MacDonald, G. Bat-Erdene, M. X. Gillis, P. J. Dalton, I. Kavalieris, B.-E. Khashgerel, A. Kloppenburg, A. Coote, J. W. Hedenquist
Mineral exploration since 2005 in a previously underexplored region of southwestern Mongolia resulted in the definition of the Zuun Mod porphyry Mo-Cu deposit, followed by discovery of the Altan Nar and Bayan Khundii epithermal gold deposits along with several prospects and advanced exploration projects. These discoveries form the core of the emerging Khundii (“Valley”) metallogenic province, ~50 × 100 km in size, located within a single island-arc terrane of Middle Carboniferous to early Permian age and predominantly within an individual mapped subterrane. The province is situated ~700 km west-northwest of the late Devonian Oyu Tolgoi porphyry Cu-Au deposit in a belt of mid-Paleozoic island arcs that are part of the Central Asian orogenic belt, host to world-class porphyry Cu-Au and epithermal gold deposits that stretch from southern Mongolia to the west, into China, Kazakhstan, and beyond.The Zuun Mod porphyry Mo-Cu deposit (297 ± 4.8 Ma) is hosted by a granodiorite intrusion cut by B-type quartz-molybdenite-chalcopyrite veins with K-feldspar alteration selvages plus disseminated biotite and magnetite. After definition of this deposit, a regional exploration program was initiated in 2009 over 110,000 km2, based on the underexplored nature of the region. Exploration included compilation of existing geologic, geochemical, and geophysical data and interpretation of satellite imagery followed by ground exploration that included stream, soil, and rock-chip sampling and geologic and alteration mapping. The Nomin Tal Cu-Au prospect was discovered in early 2011, and based on the indications from initial soil sampling, a 400- × 400-m soil survey was conducted over the southern part of the exploration license, which identified a Pb-, Zn-, and Au-in-soil anomaly over an area of ~1.5 × ~5.5 km. The first drill hole within the soil anomaly in late 2011 resulted in the discovery of the Altan Nar Au-polymetallic epithermal deposit with veins of coarsely crystalline quartz-adularia (309.7 ± 0.5 Ma) and Ca-, Mg-, Mn-, and Fe-carbonate gangue that host the base metal sulfides.The Bayan Khundii gold deposit was discovered in 2015 as the result of prospecting, ~16 km southeast of Altan Nar. Subsequent discovery of the Khar Mori gold project was announced in early 2021, ~3 km north of Bayan Khundii along a structural trend, and later in 2021 drilling discovered wide zones of disseminated gold at Ulaan Southeast, ~800 m west of Bayan Khundii. The epithermal quartz-adularia-gold veins (336.8 ± 0.5 Ma) at Bayan Khundii have colloform bands with minor pyrite and are enveloped by proximal illite alteration. The epithermal veins and alteration overprint an earlier, unrelated alteration style of residual quartz and pyrophyllite ± dickite ± diaspore-kaolinite. Similarly, residual quartz and pyrophyllite-dickite at Khar Mori are overprinted by epithermal mineralization, including arsenopyrite. At the central Ulaan project, ~3 km northwest of Bayan Khundii, intens
{"title":"Epithermal Gold Discoveries in the Emerging Khundii Metallogenic Province, Southwest Mongolia","authors":"M. A. MacDonald, G. Bat-Erdene, M. X. Gillis, P. J. Dalton, I. Kavalieris, B.-E. Khashgerel, A. Kloppenburg, A. Coote, J. W. Hedenquist","doi":"10.5382/econgeo.5070","DOIUrl":"https://doi.org/10.5382/econgeo.5070","url":null,"abstract":"Mineral exploration since 2005 in a previously underexplored region of southwestern Mongolia resulted in the definition of the Zuun Mod porphyry Mo-Cu deposit, followed by discovery of the Altan Nar and Bayan Khundii epithermal gold deposits along with several prospects and advanced exploration projects. These discoveries form the core of the emerging Khundii (“Valley”) metallogenic province, ~50 × 100 km in size, located within a single island-arc terrane of Middle Carboniferous to early Permian age and predominantly within an individual mapped subterrane. The province is situated ~700 km west-northwest of the late Devonian Oyu Tolgoi porphyry Cu-Au deposit in a belt of mid-Paleozoic island arcs that are part of the Central Asian orogenic belt, host to world-class porphyry Cu-Au and epithermal gold deposits that stretch from southern Mongolia to the west, into China, Kazakhstan, and beyond.The Zuun Mod porphyry Mo-Cu deposit (297 ± 4.8 Ma) is hosted by a granodiorite intrusion cut by B-type quartz-molybdenite-chalcopyrite veins with K-feldspar alteration selvages plus disseminated biotite and magnetite. After definition of this deposit, a regional exploration program was initiated in 2009 over 110,000 km<sup>2</sup>, based on the underexplored nature of the region. Exploration included compilation of existing geologic, geochemical, and geophysical data and interpretation of satellite imagery followed by ground exploration that included stream, soil, and rock-chip sampling and geologic and alteration mapping. The Nomin Tal Cu-Au prospect was discovered in early 2011, and based on the indications from initial soil sampling, a 400- × 400-m soil survey was conducted over the southern part of the exploration license, which identified a Pb-, Zn-, and Au-in-soil anomaly over an area of ~1.5 × ~5.5 km. The first drill hole within the soil anomaly in late 2011 resulted in the discovery of the Altan Nar Au-polymetallic epithermal deposit with veins of coarsely crystalline quartz-adularia (309.7 ± 0.5 Ma) and Ca-, Mg-, Mn-, and Fe-carbonate gangue that host the base metal sulfides.The Bayan Khundii gold deposit was discovered in 2015 as the result of prospecting, ~16 km southeast of Altan Nar. Subsequent discovery of the Khar Mori gold project was announced in early 2021, ~3 km north of Bayan Khundii along a structural trend, and later in 2021 drilling discovered wide zones of disseminated gold at Ulaan Southeast, ~800 m west of Bayan Khundii. The epithermal quartz-adularia-gold veins (336.8 ± 0.5 Ma) at Bayan Khundii have colloform bands with minor pyrite and are enveloped by proximal illite alteration. The epithermal veins and alteration overprint an earlier, unrelated alteration style of residual quartz and pyrophyllite ± dickite ± diaspore-kaolinite. Similarly, residual quartz and pyrophyllite-dickite at Khar Mori are overprinted by epithermal mineralization, including arsenopyrite. At the central Ulaan project, ~3 km northwest of Bayan Khundii, intens","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":null,"pages":null},"PeriodicalIF":5.8,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140817834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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