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Gold and Trace Element Release From Pyrite During Prograde Metamorphism of Carbonaceous Metapelites: Implications for Orogenic Gold Formation 碳质变质岩进变质过程中黄铁矿中金及微量元素的释放:造山带金形成的意义
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-04 DOI: 10.5382/econgeo.5168
Abdul Latheef Thathrampally, Rajarshi Chakravarti, Crystal Laflamme, Paul Olin
The Neoproterozoic carbonaceous metapelites of the Mandhali Formation in the inner Lesser Himalaya contain diagenetic pyrite with above-background levels of Au (>200 ppb) when analyzed by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). These metapelites exhibit progressively metamorphosed zones (from south to north), ranging from the chlorite-muscovite zone (~372°C), to the muscovite ± biotite (~520°C) zone, to the greenschist-amphibolite transition (~570°C, >5 kbar). Within this regional framework, we document a hitherto unknown paragenesis of pyrite growth from diagenesis to peak metamorphism along with a localized phase of contact metamorphism, which predates regional metamorphism. A comparative assessment of pyrite trace element concentrations from the progressive metamorphic zones reveals that >80% of Au and ~65% of As is released from diagenetic pyrite during early chlorite dehydration at ~372°C, that is, in the chlorite-muscovite zone. Further into the muscovite ± biotite zone, at the terminal chlorite breakdown stage (480°–520°C), pyrite still occurs as the major sulfide with subordinate pyrrhotite. However, by this stage, ~93% of Au; ~75% of As; and ≥90% of Mo, Cd, Pb, Sb, W, Cu, Bi, Te, and Tl are released from pyrite. With the transition of pyrite to pyrrhotite (500°–550°C), almost all trace elements are released from pyrite into metamorphic fluids, except Co that is incorporated into the metamorphic pyrrhotite. This documented grain-scale elemental mobility is also reflected in bulk-rock Au assays; that is, mean Au of 9.8 ppb in the chlorite-muscovite zone and 1.1 ppb in the muscovite ± biotite zone. Our results suggest that pyrite recrystallization during chlorite dehydration is relatively more significant than pyrite-pyrrhotite transition in terms of Au and As release, and by extension, orogenic gold formation.
通过激光烧蚀-电感耦合等离子体质谱(LA-ICP-MS)分析,内小喜马拉雅地区曼达里组新元古代碳质变质岩中含有高于背景水平(200 ppb)的成岩黄铁矿。这些变长岩呈现渐变变质带(由南至北),从绿泥石-白云母带(~372℃)到白云母±黑云母带(~520℃),再到绿片岩-角闪岩过渡带(~570℃,> 5kbar)。在这个区域框架内,我们记录了迄今为止未知的黄铁矿从成岩作用到峰值变质作用的共生作用,以及一个局部的接触变质作用阶段,它早于区域变质作用。对进变质带黄铁矿微量元素浓度的对比分析表明:在~372℃的早期绿泥石脱水过程中,即绿泥石—白云母带,成岩黄铁矿中释放出80%的Au和~65%的As。进入白云母±黑云母带,在绿泥石末期(480°~ 520°C),黄铁矿仍以硫化物为主,磁黄铁矿次之。然而,在这个阶段,~93%的Au;~75%的As;从黄铁矿中释放出的Mo、Cd、Pb、Sb、W、Cu、Bi、Te、Tl含量≥90%。随着黄铁矿向磁黄铁矿的转变(500℃~ 550℃),除Co混入变质磁黄铁矿外,几乎所有微量元素都从黄铁矿中释放到变质流体中。这种记录的颗粒尺度元素流动性也反映在大块岩石Au分析中;即绿泥石-白云母带平均Au为9.8 ppb,白云母±黑云母带平均Au为1.1 ppb。研究结果表明,在绿泥石脱水过程中,黄铁矿的再结晶作用相对于黄铁矿-磁黄铁矿的转变更为显著,在Au和As的释放上,进而在造山造金过程中,黄铁矿的再结晶作用更为显著。
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引用次数: 0
Depth of Magma Crystallization and Fluid Exsolution Beneath the Porphyry-Skarn Cu Deposits at Santa Rita and Hanover-Fierro, New Mexico, USA 美国新墨西哥州Santa Rita和Hanover-Fierro斑岩-矽卡岩型铜矿床岩浆结晶和流体析出深度
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-01 DOI: 10.5382/econgeo.5197
Andreas Audétat, Jia Chang, Sean P. Gaynor
The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton ex
斑岩造铜岩浆分馏和溶解矿化流体的深度一直备受争议。在经典模型中,广泛的岩浆分馏发生在大的上地壳岩浆房中,伴随的流体析出导致残余岩浆以斑岩脉、岩库和角砾岩管的形式被强力排出,这些岩浆随后成为矿化流体的通道。相比之下,最近一些强调深部地壳岩浆分选作用在肥沃岩浆产生中的作用的研究基本上否认了成矿时上部地壳岩浆房的存在。为此,研究人员对美国新墨西哥州Santa Rita和hanver - fierro地区与斑岩-夕卡岩型铜成矿有关的13块中长英质、斑岩型侵入岩进行了详细的热压测量,其中包括2块成矿前岩浆(61 ~ 60 Ma)、7块同成矿岩浆(60 ~ 58 Ma)和4块成矿后期岩浆(58 ~ 57 Ma)。根据石英斑晶中捕获的小角闪石包裹体的al -in-角闪石气压测量和主石英斑晶本身的钛-in-石英(TitaniQ)热气压测量,重建了每个样品在最终岩浆上升到当前暴露水平之前的最后岩浆结晶压力。由于石英是最后结晶的岩浆矿物之一,在岩浆最终侵位后,小岩脉和岩脉中不可能出现明显的斑晶生长,因此石英斑晶及其所含角闪石包裹体记录了岩浆最终上升前的最后结晶深度。当角闪石斑晶存在时,还分析了其他主要斑晶中的角闪石包裹体。石英和角闪石气压计对整个成矿前至成矿后岩浆组的平均压力均为3.2±0.4 kbar,对应深度为11至14 km。同成矿岩浆的平均压力更为稳定,为3.1±0.2 kbar,对应深度为12±1 km。在就位水平的矿化斑岩岩脉和岩脉的体积太小,无法提供形成已观察到的矿床所需的所有流体和金属。因此,大部分成矿流体必须来自于12±1 km深度结晶的岩浆。相反,矿床形成于~ 5km古深度。这意味着大多数矿化流体从岩浆源到最终的矿石沉淀位置平均垂直距离约为7公里。矿化斑岩岩脉和岩脉较深部性质相对不变,脉化程度较低,表明流体在侵入体中的运移主要发生在近固相条件下,流体沿晶界渗流。综上所述,我们的研究结果表明:(1)在Santa Rita和Hanover-Fierro矿床下方约7 km处存在大型上地壳岩体;(2)该深度发生了丰富的斑晶结晶;(3)该岩体是成矿流体析出的主要来源。然而,所研究的岩石整体Sr/Y比值升高,表明岩浆在地壳深部水平分异。因此,我们的首选模型是上述两种端元模型的结合,其中大部分岩浆分选发生在地壳深处,剩余的中英质熔体上升并积聚在11至14 km的古深度,在那里它们继续结晶,相对较少的晶液分离,然后这些岩浆进一步上升到浅层并淬灭为斑岩。
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引用次数: 0
Formation of an Fe-Ti Deposit Within an Open-System Magmatic Chamber: Insights from the Storgangen Deposit, Rogaland Anorthosite Province, Southwest Norway 开放体系岩浆室中铁钛矿床的形成:来自挪威西南部Rogaland斜长岩省Storgangen矿床的启示
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-14 DOI: 10.5382/econgeo.5185
Eduardo Mansur, Alf Andre Orvik, Nolwenn Coint, Magdalena H. Huyskens, Trond Slagstad, Henrik Schiellerup, Sarah Dare
The Storgangen deposit is located in the Rogaland anorthosite province, Norway, and forms an E-W–trending, 4-km-long, and up to 60-m-thick sheetlike intrusion. We have combined field and petrographic observations, whole-rock and mineral compositional variations, and Sr isotope composition through a profile across the deposit. The predominant lithology is a medium-grained, magnetite-ilmenite–rich norite, which is massif at the base and becomes gradually more fine layered upward in the stratigraphy. Although ilmenite is the predominant oxide, there is a decrease in ilmenite proportions relative to magnetite upward in the stratigraphy, which leads to lower whole-rock Ti/Fe ratios in the sampled profile. Mineral compositional variations display a decrease of compatible elements in ilmenite and magnetite (e.g., Co, Cr, V) and in Mg# in orthopyroxene upward in the stratigraphy. These compositional trends support a progressive upward fractionation during the formation of the deposit. Based on the composition of oxides, we estimate that the orebody developed following only about 40% crystallization of the parental magma and preferential accumulation of Fe-Ti oxides at the bottom of the magmatic system due to gravitational segregation. The Storgangen deposit represents a staging chamber within the Rogaland anorthosite province that was part of a larger system. In situ Sr isotope ratios in plagioclase display a slight stratigraphic variation, with 87/86Srinitial varying from 0.70558 to 0.70602, which is greater than values from the host anorthosite in the vicinity of the deposit of 0.70540 to 0.70554. Thus, if contamination occurred, it may have taken place within a deeper staging chamber prior to emplacement. Alternatively, the Sr isotope signature may be inherited from variably contaminated parental primitive jotunites previously described in the Rogaland anorthosite province. Our results support that Fe-Ti-P deposits from the Rogaland anorthosite province likely define a compositional trend from high- to low-Ti/Fe systems, with the Storgangen deposit displaying relatively intermediate Ti/Fe ratios. Such a trend has been proposed for the Central Grenville province and may thus be a global feature of Fe-Ti-P deposits associated with massif-type anorthosites.
Storgangen矿床位于挪威Rogaland斜长岩省,形成一个东西向,长4公里,厚60米的片状侵入体。我们结合了野外和岩石学观察,整个岩石和矿物组成变化,以及Sr同位素组成,通过整个矿床的剖面。主要岩性为中粒、富磁铁矿-钛铁矿的黑岩,基底呈块状,向上逐渐呈细层状。虽然钛铁矿是主要的氧化物,但在地层中,钛铁矿相对于磁铁矿的比例有所下降,这导致采样剖面中全岩Ti/Fe比降低。矿物组成变化表现为在地层向上方向,钛铁矿和磁铁矿中Co、Cr、V等相容元素减少,正辉石中Mg#相容元素减少。这些成分趋势支持在矿床形成过程中向上递进分馏作用。根据氧化物的组成,我们估计该矿体是在母岩浆仅结晶约40%和铁钛氧化物在岩浆系统底部因重力偏析而优先聚集的情况下发育的。Storgangen矿床代表了Rogaland斜长岩省的一个分期室,它是一个更大系统的一部分。斜长石的原位Sr同位素比值表现出轻微的地层变化,87/ 86sr初始值在0.70558 ~ 0.70602之间变化,大于矿床附近寄主斜长岩的0.70540 ~ 0.70554。因此,如果发生污染,它可能在放置前在较深的分级室中发生。或者,Sr同位素特征可能继承自先前在Rogaland斜长岩省描述的受不同污染的亲本原始斑岩。我们的研究结果支持来自Rogaland斜长岩省的Fe-Ti- p矿床可能定义了一个由高到低的Ti/Fe体系的组成趋势,而Storgangen矿床显示相对中等的Ti/Fe比率。这种趋势已在格伦维尔省中部提出,因此可能是与块状斜长岩相关的铁-钛-磷矿床的全球特征。
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引用次数: 0
Hydrothermal Footprint of the Salobo Profundo Cu-Au Orebody, Carajás Mineral Province, Brazil 巴西Carajás矿产省Salobo Profundo铜金矿体热液足迹
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-14 DOI: 10.5382/econgeo.5189
Juliana de Araújo Carvalho, Adalene Moreira Silva, Catarina Labouré Bemfica Toledo, Fernando Martins Vieira Matos, Carlos Augusto de Medeiros Filho
Located in the northern sector of the Carajás mineral province, the Salobo Cu-Au deposit is the largest copper deposit in Brazil. “Salobo Profundo” (Deep Salobo) refers to the portion of the orebody beneath the final proposed pit, where deep exploration drill holes have investigated a panel approximately 700 m deep and 1,800 m long. The alteration footprint of this portion of the deposit has been documented through the integration of petrographic, hyperspectral, and geochemical data from three boreholes, totaling approximately 3,000 m. Hydrothermal zoning is characterized by albitization (Na (I)) and silicification in the distal halo, transitioning to calcic-potassic iron zones proximal to mineralization. Intense Fe metasomatism, along with potassic iron and iron alteration is most closely associated with copper and gold mineralization. Late-stage alteration is characterized by Na-Ca (II) alteration and a later type of a more intense albitic alteration (Na (II)). Hyperspectral scanning, encompassing visible-near infrared (VNIR, 380–1,000 nm), short-wave infrared (SWIR, 1,000–2,500 nm), and long-wave infrared (LWIR, 7,700–12,300 nm) wavelength ranges, has mapped the main minerals involved in the alteration processes at a centimeter-scale resolution. Minerals such as amphiboles, biotite, garnet, chlorite, quartz, and albite were identified, with garnet abundance showing a close association with copper-rich zones. The geochemical data are consistent with the characteristics of many iron oxide copper-gold (IOCG) systems, exhibiting the classic association of Fe, Cu, ± Au, along with enrichment in Ag, Bi, Co, Cs, F, Mo, Ce, La, and U. These results indicate that hyperspectral core scanning, combined with geochemical data analysis, is an effective approach for defining alteration zonation around IOCG deposits. This method enhances the characterization and refined modeling of hydrothermal zoning, providing a powerful tool for exploring for similar deposits, not only in Carajás but also in other metallogenic provinces worldwide.
Salobo铜金矿位于Carajás矿产省的北部,是巴西最大的铜矿。“Salobo Profundo”(深Salobo)指的是最终提议的矿坑下方的矿体部分,在那里,深度勘探钻孔已经调查了一个大约700米深、1800米长的面板。通过对三个钻孔的岩石学、高光谱和地球化学数据的整合,记录了这部分矿床的蚀变足迹,总计约3000米。热液分带在远晕以钠长石化(Na (I))和硅化为特征,在矿化近晕过渡到钙钾铁带。强烈的铁交代、钾化铁和铁蚀变与铜、金成矿关系最为密切。后期蚀变以Na- ca (II)蚀变和后期更为强烈的钠长岩蚀变(Na (II))为特征。高光谱扫描包括可见光-近红外(VNIR, 380-1,000 nm)、短波红外(SWIR, 1,000-2,500 nm)和长波红外(LWIR, 7,700-12,300 nm)波长范围,以厘米尺度分辨率绘制了蚀变过程中涉及的主要矿物。发现了角闪石、黑云母、石榴石、绿泥石、石英、钠长石等矿物,其中石榴石丰度与富铜矿带密切相关。地球化学数据与许多氧化铁铜金(IOCG)体系的特征一致,表现为Fe、Cu、±Au的典型组合,同时富集Ag、Bi、Co、Cs、F、Mo、Ce、La和u。结果表明,高光谱岩芯扫描结合地球化学数据分析是确定IOCG矿床蚀变分带的有效方法。该方法增强了热液分带的表征和精细建模,为Carajás及全球其他成矿省寻找类似矿床提供了有力的工具。
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引用次数: 0
Generation of the Zarshuran Gold Deposit in Northwest Iran Triggered by Exhumation of the Iman Khan Metamorphic Core Complex 伊曼汗变质核杂岩的发掘引发伊朗西北部扎尔舒兰金矿床的生成
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-14 DOI: 10.5382/econgeo.5192
Hongrui Zhang, Zhiming Yang, Pinghua Liu, Shu Yang, Mehraj Aghazadeh, Zengqian Hou, Tiannan Yang, Zahra Badrzadeh
Zarshuran is the largest gold deposit in the Middle East. However, the structural controls and ore-forming processes at Zarshuran remain poorly understood. This study presents new geologic mapping results, detailed descriptions of ore textures, and calcite in situ U-Pb dating and thermochronological data to propose a new genetic model addressing the knowledge gap. New field mapping results demonstrate that the Zarshuran deposit is hosted in the Iman Khan Complex, which exhibits abundant ductile fabrics, and gold mineralization is spatially associated with the Zarshuran fault separating the Neoproterozoic Iman Khan and Cambrian Chaldagh units in its footwall from the Cambrian Zarshuran unit and Oligocene-Miocene Qom Formation in its hanging wall. Ore textures include syntectonic gold-bearing pyrite veins around felsic porphyroclasts, syntectonic cata-clastic flow around lenses, syntaxial euhedral calcite, and pyrite veins filled in brittle fracture and stratabound within the Qom Formation. Muscovite-quartz schist of the Iman Khan Complex underwent peak metamorphism of greenschist facies at pressure-temperature (P-T) conditions of 0.20 to 0.44 GPa and 372° to 446°C as constrained by chemical compositions of muscovite. The 40Ar/39Ar dating of syntectonic muscovite yielded a plateau age of 20.59 ± 0.32 Ma. In situ U-Pb dating of calcite associated with gold-bearing pyrite yields 14.5 ± 2.0 Ma. Apatite (U-Th)/He ages range from 12.73 ± 0.77 to 5.55 ± 0.46 Ma. These ages, combined with HeFTy thermal modeling, suggest that the Zarshuran deposit underwent a slow cooling stage from 20.6 to 14.5 Ma, a rapid cooling stage from 14.5 to 9 Ma, and an extremely slow cooling stage at <9 Ma. We propose that the Iman Khan Complex is an incipient metamorphic core complex (MCC), and gold mineralization occurred in the ductile and brittle deformation stages (20.6–14.5 Ma) associated with exhumation of the Iman Khan MCC. Other MCCs in the Tethyan metallogenic belt may be potential gold exploration targets.
扎舒兰是中东最大的金矿。然而,对扎树然的构造控制和成矿过程仍知之甚少。本研究提出了新的地质填图结果、矿石结构的详细描述、方解石原位U-Pb定年和热年代学数据,提出了一种新的成因模型,以解决知识空白问题。新的野外填图结果表明,扎树然矿床赋存于具有丰富韧性组构的伊曼汗杂岩中,金矿化在空间上与扎树然断裂有关,该断裂将下盘的新元古代伊曼汗和寒武系Chaldagh单元与上盘的寒武系扎树然单元和渐新统—中新统Qom组分隔开。矿石结构包括围绕长英质斑岩碎屑的同构造含金黄铁矿脉、围绕透镜体的同构造变质碎屑流、同构造自面方解石以及库姆组内充填于脆性断裂和层控的黄铁矿脉。受白云母化学成分的限制,伊曼汗杂岩的白云母-石英片岩在0.20 ~ 0.44 GPa、372 ~ 446℃的压力-温度(P-T)条件下发生绿片岩相变质峰。同构造白云母40Ar/39Ar测年结果表明,其高原年龄为20.59±0.32 Ma。方解石与含金黄铁矿的U-Pb原位测年结果为14.5±2.0 Ma。磷灰石(U-Th)/He年龄范围为12.73±0.77 ~ 5.55±0.46 Ma。这些年龄,结合HeFTy热模拟,表明扎树然矿床经历了20.6 ~ 14.5 Ma的缓慢冷却阶段,14.5 ~ 9 Ma的快速冷却阶段,以及极慢的冷却阶段。9马。我们认为,伊曼汗杂岩是一个早期变质核杂岩(MCC),金矿化发生在延性和脆性变形阶段(20.6 ~ 14.5 Ma)。特提斯成矿带内的其他mcc可能是潜在的金矿找矿目标。
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引用次数: 0
Paragenetic Evolution of the Robertson Deposit: Eocene Reduced Intrusion-Related Gold Deposit in the Northern Shoshone Range, Nevada 罗伯逊矿床的共生演化:内华达肖肖尼山脉北部始新世减小侵入体相关金矿床
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-14 DOI: 10.5382/econgeo.5191
Neal E. Mankins, John L. Muntean, Matthieu Harlaux, Matthew Mann, Robert A. Creaser
The Robertson deposit, formerly known as Tenabo, is an Eocene reduced intrusion-related gold deposit located 5 km north of Pipeline, a world-class 20+ Moz Carlin-type gold deposit in the northern Shoshone Range, Nevada. This study is the first in-depth examination of Robertson describing gold mineralization, hydrothermal alteration, petrology of the intrusive rocks, and geochronology of the magmatic and hydrothermal events. We present six new U/Pb zircon ages of intrusive phases, one vein-hosted molybdenite Re/Os age, and one hydrothermal orthoclase 40Ar/39Ar age. Gold mineralization is spatially and temporally related to an intrusive complex referred to as the Tenabo stock, which is composed of successive intrusive phases including an early ilmenite-bearing diorite, andesite dikes, hypabyssal dacitic porphyry dikes, composite ilmenite-bearing granodiorite, granitic porphyry dikes, and hypabyssal rhyolitic dikes. Emplacement of the Tenabo stock resulted in contact metamorphism of the host siliciclastic rocks, yielding quartz, biotite, and calc-silicate hornfels that formed an aureole up to 1 km from the stock. Through petrographic observations and geochemical analyses, distinct alteration assemblages are identified, encompassing sodic-calcic, potassic, calcic, sericitic, and chloritic alteration. Petrographic observations of veins at Robertson indicate the succession of three main stages referred to as (1) pregold, (2) syngold, and (3) postgold. The pregold stage consists of barren quartz veins, potassic alteration veins comprising biotite veinlets and quartz-K-feldspar, quartz-arsenopyrite, quartz-chalcopyrite, and quartz-molybdenite veins. The syngold stage is composed of quartz-gold ± Bi-Te-Se-Pb-Ag–bearing sulfosalt veins containing native visible gold observed as single grains in quartz and/or rimming pyrrhotite, arsenopyrite, chalcopyrite, and loellingite (FeAs2) grains. The postgold veins encompass pyrite ± quartz, quartz-calcite-polymetallic sulfide veins with Pb-Zn-Sb-Ag-Sn base metal sulfides, bull quartz veins, and calcite veins. Crosscutting relationships, along with U/Pb zircon dating of intrusive phases, Re/Os molybdenite dating, and 40Ar/39Ar orthoclase dating, indicate two distinct magmatic phases at Robertson. Phase one is an early phase associated with hydrothermal activity, and phase two is a late phase associated with hypabyssal rhyolitic dikes. The period of gold mineralization at Robertson is linked with the initial phase of magmatism and subsequent hydrothermal activity, which was found to occur between 39.6 and 39.0 Ma. This study demonstrates that gold mineralization is spatially and temporally related to the emplacement of an upper Eocene 39.6 Ma reduced ilmenite-bearing intrusive complex into Paleozoic siliciclastic sedimentary rocks. This produced a high-tonnage, low-grade gold deposit characterized by an Au-As-Bi-Te-Cu metal association. Mineral assemblages observed at Robertson, comprising native bismuth, Bi sulfosal
Robertson矿床,以前称为Tenabo,是一个始新世减少侵入体相关的金矿床,位于内华达州肖肖尼山脉北部的世界级的20moz卡林型金矿床Pipeline以北5公里处。本研究首次深入考察了Robertson对金矿化、热液蚀变、侵入岩岩石学以及岩浆和热液事件年代学的描述。我们获得了6个新的侵入相U/Pb锆石年龄、1个脉状辉钼矿Re/Os年龄和1个热液正长石40Ar/39Ar年龄。金矿成矿在空间和时间上与Tenabo杂岩有关,该杂岩由早期含钛闪长岩、安山岩脉、浅成英质斑岩脉、复合含钛花岗闪长岩、花岗斑岩脉和浅成流纹岩脉等连续侵入期组成。Tenabo岩石的侵位导致了寄主硅质岩石的接触变质作用,产生了石英、黑云母和钙硅酸盐角砾岩,这些角砾岩形成了距离岩石1公里的光圈。通过岩石学观察和地球化学分析,确定了不同的蚀变组合,包括钠钙、钾、钙、绢云母和绿泥石蚀变。罗伯逊岩脉的岩石学观察表明,三个主要阶段依次为(1)前金阶段、(2)同金阶段和(3)后金阶段。前金期由光秃秃的石英脉、由黑云母脉和石英钾长石、石英毒砂、石英黄铜矿和石英辉钼矿脉组成的钾蚀变脉组成。同金阶段由石英-金±bi - te - se - pb - ag -含亚硫酸盐脉体组成,其中含有可见的天然金,在石英和/或边缘磁黄铁矿、毒砂、黄铜矿和辉绿石(FeAs2)颗粒中以单粒形式存在。后金脉包括黄铁矿±石英脉、含Pb-Zn-Sb-Ag-Sn贱金属硫化物的石英-方解石-多金属硫化物脉、牛石英脉和方解石脉。通过对侵入相U/Pb锆石定年、Re/Os辉钼矿定年和40Ar/39Ar正长石定年的分析,表明Robertson地区存在两个不同的岩浆相。第一阶段为早期热液活动阶段,第二阶段为晚期浅成流纹岩岩脉阶段。罗伯逊金矿成矿期与岩浆活动初始阶段及随后的热液活动有关,成矿期在39.6 ~ 39.0 Ma之间。研究表明,上始新统39.6 Ma含钛铁矿的还原侵入杂岩侵位于古生代硅屑沉积岩中,与金矿成矿具有时空关系。形成了以Au-As-Bi-Te-Cu金属组合为特征的高吨位、低品位金矿床。在Robertson观测到的矿物组合,包括天然铋、铋磺酸盐、毒砂、磁黄铁矿和钙辉石(FeAs2),具有低硫化和氧化状态的特征,类似于全球描述的与侵入体相关的减少的金矿床和金夕卡岩。
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引用次数: 0
Automated Detection of Mineralization-Related Craton Structures Using Geophysical Data and Unsupervised Machine Learning 利用地球物理数据和无监督机器学习自动检测与矿化相关的克拉通结构
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-24 DOI: 10.5382/econgeo.5188
Hojat Shirmard, Ehsan Farahbakhsh, Karol Czarnota, R. Dietmar Müller
Internal structures and discontinuities within cratons are economically significant due to their history of tectonic reactivation from varying intraplate stress fields, which open pathways for fluid flow and facilitate mineral deposition. However, the complex overprinting tectonic processes that make cratons prospective can also lead to uncertainty regarding their internal geometries. To address this, we take a fresh perspective on these systems by using a data-driven approach to better delineate their structures and mineral potential, focusing on the Gawler craton in South Australia. We generate over 400 magnetic and gravity anomaly features and use them as input for clustering algorithms to map clusters that represent crustal structures. We compare the efficiency of two clustering methods—self-organizing map and K-means—in outlining internal craton structures at shallow (<5 km) and deep (5–30 km) crustal depths. The results are evaluated using three performance metrics alongside geologic maps. We focus on all metallic mineral systems, including mafic-ultramafic intrusions, for Co, Cr, and Ni and intrusion-related and sediment-hosted systems for Au, Cu, Fe, and Mn. Our findings indicate that most metallic mineral occurrences, particularly significant deposits, form along the boundaries of these clusters. Approximately 80% of mineral occurrences are within 7 km of deep craton structures, and almost all follow shallow and deep structures occupying less than one-third of the study area. Our approach can be easily applied to any craton at any scale and supplemented with other geophysical data, such as magnetotelluric and regional seismic tomography data, to generate more comprehensive and reliable results.
克拉通的内部构造和不连续结构具有重要的经济意义,因为它们的构造活化历史是由不同的板内应力场引起的,这些应力场为流体流动开辟了通道,促进了矿物沉积。然而,复杂的叠印构造过程使克拉通具有勘探前景,但也会导致克拉通内部几何形状的不确定性。为了解决这个问题,我们采用了一种全新的视角,通过使用数据驱动的方法来更好地描绘这些系统的结构和矿产潜力,重点关注南澳大利亚的高勒克拉通。我们生成了超过400个磁和重力异常特征,并将它们作为聚类算法的输入,以绘制代表地壳结构的聚类图。我们比较了两种聚类方法——自组织图和k -means在描绘地壳浅(5公里)和深(5 - 30公里)克拉通内部结构方面的效率。使用三个性能指标和地质图对结果进行评估。我们专注于所有的金属矿物系统,包括基性-超基性侵入体(含Co、Cr和Ni)和侵入体相关的沉积系统(含Au、Cu、Fe和Mn)。我们的发现表明,大多数金属矿物,特别是重要的矿床,都是沿着这些团簇的边界形成的。约80%的矿点位于深克拉通构造7公里范围内,且几乎全部沿占研究面积不到三分之一的浅、深构造发育。我们的方法可以很容易地应用于任何规模的任何克拉通,并与其他地球物理数据(如大地电磁和区域地震层析成像数据)相补充,从而得到更全面、更可靠的结果。
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引用次数: 0
New Recognition of Thallium Enrichment in the Zhangmajing Deposit, Northeast China, with Implications for the Genesis of Volcanic-Related U-Mo-Tl Mineralization 张马井矿床铊富集的新认识及火山相关铀钼钛矿化成因
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-24 DOI: 10.5382/econgeo.5190
Long Zhang, Fangyue Wang, Taofa Zhou, Zhenyu Chen
The Zhangmajing U-Mo deposit, located in the northern margin of the North China Craton, is unusual because both U (ca. 5,000 tonnes at 0.1–0.3% U) and Mo (0.11 million tonnes at 0.339% Mo) in this deposit are of economic interest, and Mo is mainly hosted in jordisite. In this study, thallium enrichment is recognized for the first time at Zhangmajing. This deposit is hosted within rhyolite porphyry and volcanic rocks of the Zhangjiakou Formation and surrounded by the Paleoproterozoic basement. Zircon U-Pb dating indicates that the volcanic-subvolcanic rocks were emplaced during the Early Cretaceous (141–139 Ma). Zircon Hf isotopic results show negative εHf(t) values of –20.6 to –10.9, with two-stage model ages of 1.9 to 2.5 Ga, suggesting that these rocks were dominantly derived from partial melt of Paleoproterozoic crustal materials. Whole-rock geochemical analyses indicate that the ores have highly anomalous Tl concentrations (avg 151 ppm), which are positively correlated with Mo concentrations. Ore minerals at Zhangmajing consist mostly of jordisite, pitchblende, pyrite, sphalerite, and galena. Jordisite has the highest Tl concentrations (3,307–9,921 ppm), whereas those in pyrite and sphalerite are below 2,000 ppm. Pyrite, jordisite, and sphalerite have δ34S values ranging from –16.5 to 0.3‰, suggesting that the sulfur was probably derived from a mixing of sources from the Paleoproterozoic basement and volcanic-subvolcanic rocks. This study suggests that the unusual element association of U, Mo, and Tl in Zhangmajing is the result of source rocks that are enriched in these elements, and that the metals were mainly sourced from the rocks during fluid-rock interaction and subsequently precipitated at moderate temperatures (~200°C).
张马井铀钼矿位于华北克拉通北缘,铀(约5000吨,含铀量为0.1 ~ 0.3%)和钼(11万吨,含钼量为0.339%)均具有经济价值,且钼主要赋存于jordisite中。本次研究首次确认了张马井的铊富集。该矿床赋存于张家口组流纹斑岩和火山岩中,被古元古代基底所包围。锆石U-Pb定年结果表明,火山-次火山岩形成于早白垩世(141 ~ 139 Ma)。锆石Hf同位素结果显示εHf(t)值为负-20.6 ~ -10.9,两期模式年龄为1.9 ~ 2.5 Ga,表明这些岩石主要来源于古元古代地壳物质的部分熔融。全岩地球化学分析表明,矿石具有高度异常的Tl浓度(平均为151 ppm),与Mo浓度呈正相关。张马井矿石矿物主要为jordisite、沥青铀矿、黄铁矿、闪锌矿和方铅矿。Jordisite的Tl浓度最高(3,307-9,921 ppm),而黄铁矿和闪锌矿的浓度低于2,000 ppm。黄铁矿、jordisite和闪锌矿的δ34S值在-16.5 ~ 0.3‰之间,表明硫的来源可能是古元古代基底和火山-次火山岩的混合。本文认为,张马庆地区U、Mo、Tl元素组合异常是烃源岩富集这些元素的结果,这些金属主要来自于流体-岩石相互作用过程中的岩石,并在中等温度下(~200℃)析出。
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引用次数: 0
A New Cu Province in Southern Australia? Geochronological Framework of Potential Iron Oxide Copper-Gold Systems in Northeastern Gawler Craton 南澳大利亚的一个新省?高勒克拉通东北部氧化铁-铜-金电位系统的年代格架
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-15 DOI: 10.5382/econgeo.5184
Jie Yu, Martin Hand, Dylan Gully, Dillon Brown, Laura J. Morrissey, Wei Hong, Chris Clark
Breccia-hosted and magnetite-dominated Cu mineralization has been recently discovered in the Peake and Denison Domain, northeastern Gawler craton, Australia. The iron oxide copper-gold (IOCG)-style alteration and mineralization and proximity to the world-class Olympic and Cloncurry IOCG provinces highlight the prospectivity potential for IOCG and affiliated deposits in the Peake and Denison Domain. New zircon-titanite-apatite U-Pb and apatite Lu-Hf age data from the Wills and Mawson prospects in the Peake and Denison region are presented to construct a geochronological framework for the new Cu district in southern Australia. Zircons from the host quartzofeldspathic gneiss define a major peak at ca. 1780 Ma, two shoulder peaks at ca. 1740 and ca. 1710 Ma, and minor peaks at ca. 1850 and ca. 1900 Ma. Titanite U-Pb and apatite Lu-Hf geochronology reveals an early-stage magnetite-actinolite-titanite-apatite alteration at ca. 1530 Ma for the Wills prospect, coincident with the coeval mineralization in the Cloncurry and Mary Kathleen IOCG districts of the Mount Isa inlier. The Wills prospect subsequently underwent ca. 1500 Ma ductile deformation. Apatite Lu-Hf and U-Pb geochronology from both prospects constrain vein-type and breccia-type Cu mineralization at ca. 1465 Ma, broadly coeval with regional barren Na-Ca alteration in the Peake and Denison Domain and barren potassic alteration in the Cloncurry IOCG District. The ca. 1465 Ma Cu mineralization is equivalent to the recently discovered later-stage Cu mineralization in the northern Olympic Cu-Au Province and potentially coincided with the rifting of Proto-Australia and the supercontinent Nuna in the early Mesoproterozoic.
最近在澳大利亚高勒克拉通东北部的Peake和Denison地区发现了以角砾岩为主、磁铁矿为主的铜成矿作用。氧化铁铜金(IOCG)类型的蚀变和矿化,以及靠近世界级的奥林匹克和Cloncurry IOCG省,突出了Peake和Denison域IOCG及其附属矿床的远景潜力。本文介绍了来自Peake和Denison地区Wills和Mawson勘探区的锆石-钛-磷灰石U-Pb和磷灰石Lu-Hf年龄数据,以构建澳大利亚南部新Cu区地质年代学框架。锆石在约1780 Ma有一个主峰,在约1740 Ma和约1710 Ma有两个肩峰,在约1850 Ma和约1900 Ma有两个小峰。钛矿U-Pb和磷灰石Lu-Hf年代学表明,威尔斯远景区约1530 Ma发生了早期磁铁矿-放线石-钛矿-磷灰石蚀变,与伊萨山Cloncurry和Mary Kathleen IOCG区同期成矿作用一致。威尔斯勘探区随后经历了约1500毫安的韧性变形。两个远景区的磷灰石Lu-Hf和U-Pb年代学限制了约1465 Ma的脉状和角砾岩型铜成矿作用,与Peake和Denison域的区域性贫瘠Na-Ca蚀变和Cloncurry IOCG区贫瘠钾蚀变大致相同。约1465年马铜成矿作用与最近在奥林匹克铜金省北部发现的晚期铜成矿作用相当,可能与中元古代早期原澳大利亚和努纳超大陆的裂谷作用相吻合。
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引用次数: 0
Aeromagnetic and Magnetotelluric Imaging of West-Central Idaho and the Stibnite-Yellow Pine Mining District: A Regional to District Perspective 爱达荷州中西部和辉锑矿-黄松矿区的航磁和大地电磁成像:区域到区域的视角
IF 5.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-14 DOI: 10.5382/econgeo.5182
Eric D. Anderson, Brian D. Rodriguez, Karen Lund, Christopher Dail, Bill Breen
Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).
利用航磁和大地电磁(MT)资料更好地了解爱达荷州中部辉锑矿-黄松矿区附近的地质和矿产资源。区域尺度航磁资料的还原极(RTP)变换表明,鲑鱼河缝合线以西的异域岛弧岩石的磁性明显强于缝合线以东的劳伦森陆相岩石,爱达荷岩基的花岗岩类在早成矿期和晚过铝期均具有中~低磁化。倾斜导数在航磁数据中的应用突出了主要的地壳尺度结构。向上5 km连续磁资料表明岛弧岩具有深部磁源。110公里长的MT剖面成像深度为30公里左右的电阻率结构。在较浅的深度,电阻率与绘制的地质单元相对应,在火山和顶垂变质沉积岩下具有中等电阻率,在爱达荷岩基下具有中至高电阻率。缝合图像下的地壳尺度中等电阻率,是构造岩浆作用的结果,该作用伴随着缝合和平移异域地体。基底下方和边缘的低电阻率值来源于变质沉积岩,这些变质沉积岩可能在熔体生成过程中起到熔体源和还原剂的作用,并在后来的成矿过程中提供金属。在辉锑矿-黄松矿区,高分辨率航磁编译显示与已绘制的岩性和矿床相关结构相关联。RTP变换区分了爱达荷岩基的磁性和非磁性花岗岩相。倾斜导数突出了变质沉积岩,其中一些是有利的找矿体。草甸溪断层拥有辉锑矿和Hangar平原矿床,并因热液蚀变而被成像为磁低。磁异常偏移和矿体重建显示95 Ma后的右旋分离约3 km,部分或全部偏移推断为61-66 Ma主成矿期后。
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引用次数: 0
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Economic Geology
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