用分形维数定量表征高岭石在丁苯橡胶复合材料中的分散性

Yude Zhang, Qinfu Liu, R. Frost
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引用次数: 5

摘要

采用分形方法对改性高岭石(MK)和沉淀二氧化硅(PS)在丁苯橡胶(SBR)基体中的分散性能进行了定量表征。分形维数(FD)越大,分散性越差。分形结果表明,MK在胶乳共混样品中的分散性优于磨浆共混样品。随着高岭石含量的增加,FD从1.713增加到1.800,高岭石的分散性逐渐降低。分散性与载料含量呈负相关。随着MK的降低和PS的增加,FD从1.735显著降低到1.496,高岭石的分散性显著增加。杂化可以提高填料在聚合物基体中的分散性。FD可以定量表征高岭石片在橡胶基体中的聚集和分散。
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Quantitative characterization of kaolinite dispersibility in styrene–butadiene rubber composites by fractal dimension
A fractal method was introduced to quantitatively characterize the dispersibility of modified kaolinite (MK) and precipitated silica (PS) in styrene–butadiene rubber (SBR) matrix based on the lower magnification transmission electron microscopic images. The fractal dimension (FD) is greater, and the dispersion is worse. The fractal results showed that the dispersibility of MK in the latex blending sample is better than that in the mill blending samples. With the increase of kaolinite content, the FD increases from 1.713 to 1.800, and the dispersibility of kaolinite gradually decreases. There is a negative correlation between the dispersibility and loading content. With the decrease of MK and increase of PS, the FD significantly decreases from 1.735 to 1.496 and the dipersibility of kaolinite remarkably increases. The hybridization can improve the dispersibility of fillers in polymer matrix. The FD can be used to quantitatively characterize the aggregation and dispersion of kaolinite sheets in rubber matrix.
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