C掺杂TiO2/CdS核壳纳米复合材料的合成、表征及可见光催化活性研究

A. Lavand, Y. S. Malghe, Suraj H. Singh
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引用次数: 15

摘要

采用微乳液法制备了碳(C)掺杂TiO2/CdS核壳纳米复合材料(C/TiO2/CdS)。采用x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、能量色散x射线光谱(EDX)、透射电子显微镜(TEM)和紫外可见分光光度法对合成粉体进行了表征。TEM图像显示,以CdS为核心,C掺杂TiO2为壳层,成功制备了C/TiO2/CdS核壳异质结构。紫外可见吸收光谱表明,CdS纳米粒子作为增感剂,在可见光区有效增强了C/TiO2/CdS纳米复合材料的光吸收能力。对合成的纳米复合材料可见光催化降解亚甲基蓝的活性进行了评价。C/TiO2/CdS核壳纳米复合材料比裸TiO2、CdS、CdS/TiO2和C掺杂TiO2表现出更好的光催化活性。
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Synthesis, Characterization, and Investigation of Visible Light Photocatalytic Activity of C Doped TiO2/CdS Core-Shell Nanocomposite
Carbon (C) doped TiO2/CdS core-shell nanocomposite (C/TiO2/CdS) was synthesized using microemulsion method. Synthesized powder was characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), and UV-visible spectrophotometery. TEM images reveal that C/TiO2/CdS core-shell heterostructure is successfully prepared with CdS as a core and C doped TiO2 as a shell. UV-visible absorption spectra show that CdS nanoparticles act as a sensitizer and effectively enhance the photoabsorption capacity of C/TiO2/CdS nanocomposite in visible region. Visible light photocatalytic activity of synthesized nanocomposite was evaluated for the degradation of methylene blue. C/TiO2/CdS core-shell nanocomposite exhibits better photocatalytic activity as compared to bare TiO2, CdS, CdS/TiO2, and C doped TiO2.
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