{"title":"Ni36Fe32Ta7Si8B17非晶合金反硝化制备纳米晶fcc相","authors":"P Rizzi , M Baricco , G Riontino , L Battezzati","doi":"10.1016/S0965-9773(99)00363-3","DOIUrl":null,"url":null,"abstract":"<div><p><span>Various multicomponent alloys containing Ni-Fe-Si-B and refractory metals have been rapidly solidifed in order to check their tendency to produce glassy phases and their devitrification behaviour has been studied. Among these a Ni</span><sub>36</sub>Fe<sub>32</sub>Ta<sub>7</sub>Si<sub>8</sub>B<sub>17</sub><span><span> alloy presents primary crystallization with production of fcc nanocrystals embedded in the glassy matrix. The kinetics of the transformation is determined at 530 °C showing that it consists in two steps: fast nucleation and growth of nanocrystals plus homogenization of the remaining matrix with crystal coarsening. Evidence based on TEM observations, XRD patterns and </span>DSC experiments, are reported in favour of a homogeneous mechanism of nucleation. Faceting of nanocrystals is observed for the first time in such transformations and is attributed to a stress effect on the particles.</span></p></div>","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"11 6","pages":"Pages 747-755"},"PeriodicalIF":0.0000,"publicationDate":"1999-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00363-3","citationCount":"3","resultStr":"{\"title\":\"A nanocrystalline fcc phase via devitrification of a Ni36Fe32Ta7Si8B17 amorphous alloy\",\"authors\":\"P Rizzi , M Baricco , G Riontino , L Battezzati\",\"doi\":\"10.1016/S0965-9773(99)00363-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>Various multicomponent alloys containing Ni-Fe-Si-B and refractory metals have been rapidly solidifed in order to check their tendency to produce glassy phases and their devitrification behaviour has been studied. Among these a Ni</span><sub>36</sub>Fe<sub>32</sub>Ta<sub>7</sub>Si<sub>8</sub>B<sub>17</sub><span><span> alloy presents primary crystallization with production of fcc nanocrystals embedded in the glassy matrix. The kinetics of the transformation is determined at 530 °C showing that it consists in two steps: fast nucleation and growth of nanocrystals plus homogenization of the remaining matrix with crystal coarsening. Evidence based on TEM observations, XRD patterns and </span>DSC experiments, are reported in favour of a homogeneous mechanism of nucleation. Faceting of nanocrystals is observed for the first time in such transformations and is attributed to a stress effect on the particles.</span></p></div>\",\"PeriodicalId\":18878,\"journal\":{\"name\":\"Nanostructured Materials\",\"volume\":\"11 6\",\"pages\":\"Pages 747-755\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1999-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00363-3\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanostructured Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0965977399003633\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanostructured Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0965977399003633","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A nanocrystalline fcc phase via devitrification of a Ni36Fe32Ta7Si8B17 amorphous alloy
Various multicomponent alloys containing Ni-Fe-Si-B and refractory metals have been rapidly solidifed in order to check their tendency to produce glassy phases and their devitrification behaviour has been studied. Among these a Ni36Fe32Ta7Si8B17 alloy presents primary crystallization with production of fcc nanocrystals embedded in the glassy matrix. The kinetics of the transformation is determined at 530 °C showing that it consists in two steps: fast nucleation and growth of nanocrystals plus homogenization of the remaining matrix with crystal coarsening. Evidence based on TEM observations, XRD patterns and DSC experiments, are reported in favour of a homogeneous mechanism of nucleation. Faceting of nanocrystals is observed for the first time in such transformations and is attributed to a stress effect on the particles.
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