基于两种不同结构的微型超级电容器电极的电学性能

H. E. Z. Abidin, A. A. Hamzah, M. A. Mohamed, B. Majlis, Noraini Marsi
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引用次数: 2

摘要

本文讨论了微型超级电容器的循环伏安特性和两种不同结构电极之间的充放电特性。以聚吡咯(Ppy)包覆镍电极为集流电极,聚乙烯醇(PVA)为固态电解质构建微超级电容器。研究了微超级电容器在不同电极结构下的循环伏安特性,即I-V曲线和典型的基于时间的充放电曲线。在Comsol Multiphysics版本。4.2a,选择稀释物种的二次电流分布和输运作为应用模块。模拟了双电极结构的微型超级电容器的I-V曲线。还原和氧化物质的输运用稀条件下随时间的扩散传质原理来描述。数字间电极的最大电流响应为5.5 A/m,平面电极的最大电流响应为0.025 A/m。对于数字间电极,不同时间平面电极在0.5 V时达到的最大伏坦相同。数字间电极和平面电极的放电过程分别发生在电压值在1s和10s降至零时。
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Electrical performances based on two different structured of micro supercapacitor electrodes
This paper discusses electrical performances of the micro supercapacitor such as cyclic voltammetry and charge discharge between two different structure of electrodes. The microsupercapacitor was constructed of Polypyrrole (Ppy) coated nickel electrode as current collector and polyvinyl alcohol (PVA) as solid state electrolyte. The electrochemical performances of the microsupercapacitor such as cyclic voltammetry also typically known as I-V curve and a typical time based charge discharge curve were investigated with different structured of electrode which is interdigital electrode and planar electrode for the same layout. In Comsol Multiphysics ver. 4.2a, the Secondary Current Distribution and Transport of Diluted Species has been selected as the Application module. I-V curve for the micro supercapacitor with the two structured of electrodes was simulated. The transport of a reduced and an oxidized species is described by time-dependent mass transfer principles for diffusion under dilute conditions. The maximum current response for the interdigital electrode is 5.5 A/m and for the planar electrode is 0.025 A/m. For the interdigital electrode, the maximum voltan achieved at 0.5 V same for the planar electrode with different time. Discharging process for interdigital and planar electrode occurred when the value of voltage decreasing and back to zero at 1s and 10 s respectively.
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