吉打邦高岭土矿物作为铜金属吸附材料的活化研究

Sy. Indra Septiansyah, Idris Herkan Afandi, Retno Tasya Dirtami
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摘要

高岭土是指一组层状硅酸盐矿物,其层状结构与Al2Si2O5(OH)4组成为1:1。这种类型的高岭土叶状硅酸盐矿物通常被称为粘土矿物。高岭土粘土组主要由高岭石矿物或更广为人知的白粘土组成。高岭土广泛应用于造纸、陶瓷、橡胶、塑料、涂料、玻璃纤维、化妆品等行业。高岭土作为吸附剂的处理可以使用物理活化进行,其中高岭土被洗涤并与杂质分离并干燥成粉末。然后,高岭土的化学活化将通过HCl的浸出过程进行,HCl的最佳浓度旨在将高岭土与仍与高岭土化学结合的杂质分离。试验结果表明,回收率为71.42% ~ 81.2%,含水率<2%。高岭土的化学成分SiO2为53.32 ~ 67.32%,Al2O3为28.22 ~ 30.47%,Fe2O3为1.32%,CaO为0.03%,MgO为0.20%,MnO2为0.01%,K2O为0.86%,NaO为0.01%,Cr为0.01%,LOI为11.03%。对Cu金属在CuSO4溶液中的吸附试验结果表明,吸附率为62 ~ 93%,为吸附。
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Activation of Kaolin Minerals from Ketapang Regency as Cu Metal Adsorbent Material
Kaolin is a term given to a group of phyllosilicate minerals whose layers have a 1:1 structure with Al2Si2O5(OH)4 composition. This type of kaolin phyllosilicate mineral is commonly known as a clay mineral. The kaolin clay group consists mainly of the kaolinite mineral or better known as white clay. Kaolin is widely applied in industries such as paper, ceramics, rubber, plastic, paint, fiberglass, cosmetics, etc. The processing of kaolin as an adsorbent can be carried out using physical activation, where the kaolin is washed and separated from the impurities and dried into a powder. Then the chemical activation of kaolin will go through a leaching process using HCl with optimal concentrations aimed at separating kaolin from impurities that are still chemically bound to kaolin. The results of the characteristics show recovery of 71.42% to 81.2% and moisture content <2%. The chemical composition of kaolin containing SiO2 was 53.32–67.32%, Al2O3 was 28.22–30.47%, Fe2O3 was 1.32%, CaO was 0.03%, MgO was 0.20%, MnO2 was 0.01%, K2O of 0.86%, NaO of 0.01%, Cr of 0.01%, LOI of 11.03%. The adsorption test results on Cu metal in CuSO4 solution showed the absorption of 62–93% of Cu metal which was adsorption.
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