Kartika Tahya, Candra Yulius Tahya, Healthy Kainama
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引用次数: 3

摘要

银鱼(Mene maculata)是摩鹿加海中发现的一种中上层鱼类,这种鱼的含油量很高,因此很容易提取其中的油脂进行酯交换。银鱼油油的酯交换反应需要催化剂,多相催化剂是较好的选择。本研究以鸡蛋壳为原料,采用多相CaO催化剂,通过油分离、CaO催化剂合成、油酯交换反应3个步骤,对黄颡鱼脂肪酸甲酯组成进行了测定。采用石油醚索氏法进行油分离,含油量为13.51%。在1000℃下煅烧2小时合成了CaO催化剂,并用XRD对其进行了表征。鱼油用CaO催化剂以混合物的11% (w/v)的比例进行酯交换。所得脂肪酸甲酯采用气相色谱-质谱分析。结果表明,酯交换产物由6种甲酯脂肪酸组成,分别为:肉豆油甲酯(11.85%)、棕榈油酸甲酯(8.71%)、棕榈酸甲酯(25.13%)、油酸甲酯(9.49%)、硬脂酸甲酯(10.04%)和5,8,11,14-四烯酸甲酯(1.96%)。
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Transesterifikasi Minyak Ikan Perak (Mene maculata) Dengan Katalis CaO Dari Cangkang Telur Ayam
Silver fish (Mene maculata) is a type of pelagic fish found in the Moluccas sea, this fish has a high oil content so that it is easy to extract the oil content for transesterification. The transesterification reaction of oil from silver fish oil needs a catalyst, and heterogenous catalyst is a better choice. This study was determined the fatty acid methyl ester composition of M. maculata by transesterification process using heterogeneous CaO catalyst from chicken egg shells through 3 steps i.e. oil isolation, CaO catalyst synthesis, and oil transesterification reactions. Oil isolation was carried out by soxhletation method using petroleum ether with the oil content was 13.51%. Synthesis of CaO catalyst was carried out by calcination at 1000 °C for 2 hours and then charactererized by XRD. Fish oil is transesterified using CaO catalyst in a ratio of 11% (w/v) of the mixture. Furthermore, fatty acid methyl esters obtained were analyzed using GC-MS. The results showed 6 methyl ester fatty acids as composition of transesterification products which were methyl myristic (11.85%), methyl palmitoleate (8.71%), methyl palmitic (25.13%), methyl oleic (9.49%), methyl stearic (10.04%), and methyl 5,8,11,14-eikosatetraenoate (1.96%).
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