涉及 13 族元素的非催化羰基化反应：烯烃和炔烃的碳化和羰化作用。

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC Synthesis-Stuttgart Pub Date : 2023-08-01 Epub Date: 2022-10-12 DOI:10.1055/s-0042-1751362

Yudong Liu, K A Woerpel

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引用次数: 0

摘要

烯烃和炔烃的羰基化反应是一种强有力的碳-碳键形成反应。使用含有碳和第 13 族元素（尤其是硼和铝）之间的键的化合物尤其具有吸引力，因为其后续转化具有多功能性。非催化碳化和碳氨化是不太常见的反应类别。本短评讨论了烯和炔的非催化碳化和碳矾反应，包括反应设计和机理。

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Uncatalyzed Carbometallation Involving Group 13 Elements: Carboboration and Carboalumination of Alkenes and Alkynes.

Carbometallation of alkenes and alkynes are powerful carbon-carbon bond-forming reactions. The use of compounds containing bonds between carbon and group 13 elements, particularly boron and aluminum, are particularly attractive because of the versatility of subsequent transformations. Uncatalyzed carboboration and carboalumination represent less common classes of reactions. This Short Review discusses uncatalyzed carboboration and carboalumination reactions of alkenes and alkynes, including the reaction design and mechanism.

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.

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