罗望子活性炭对亚甲基蓝和活性黑5的吸附研究

Zaniah Ishak, Sa’diah Salim, Dilip Kumar
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引用次数: 19

摘要

处理废水,特别是合成染料的最环保的方法之一是从农业废弃物中生产活性炭。以罗望子为原料,将其转化为活性炭,研究了罗望子对合成染料的去除效果。将特定的农业废弃物浸泡在氯化锌中进行化学活化,以增加其表面积并提高其孔隙率。对罗望子进行物理活化的炭化工艺是:在300℃下燃烧1小时,冷却24小时,然后用盐酸洗涤,激活罗望子碳的孔表面。考察了接触时间、初始浓度、吸光度投加量、pH值等参数对罗望子活性炭吸附染料的影响。实验数据表明,罗罗籽活性炭对亚甲基蓝(MB)和活性黑5 (RB5)的吸附均符合Langmuir等温线,相关系数R2分别为0.9227和0.6117。罗罗籽活性炭对亚甲基蓝(MB)和活性黑5 (RB5)的吸附速率均符合拟二阶模型。为了达到工业部门印染废水的排放标准,需要进行更多的研究。
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Adsorption of Methylene Blue and Reactive Black 5 by Activated Carbon Derived from Tamarind Seeds
One of the most environmentally friendly methods to treat wastewater, especially synthetic dyes, is the production of activated carbon from agricultural waste. Tamarind seeds were transformed from negative-value waste into activated carbon in order to study the removal of synthetic dyes. The particular agro waste was soaked in ZnCl2 for chemical activation to increase its surface area and enhance its porosity. Physical activation of tamarind seeds was done by the carbonization process by burning at a temperature of 300 °C for 1 hour and cooling for 24 hours before washing with HCL to activate a pore surface for the tamarind seeds' carbon. The effects of parameters related to the adsorption of the dyes by tamarind seed activated carbon, such as contact time, initial concentration, absorbance dosage, and pH, were studied. The experimental data found that adsorption on both synthetic dyes exhibited a Langmuir isotherm in which the correlation value, R2, was 0.9227 (methylene blue) and 0.6117 (Reactive black 5). Meanwhile, the rate of adsorption for methylene blue (MB) and Reactive black 5 (RB5) by tamarind seed activated carbon was found to be well fitted in a pseudo-second-order model. More research is needed to meet the standard effluent of dyeing wastewater from the industrial sector.
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