蔗渣合成氮掺杂活性炭吸附CO2

R. Y. Kurniawan, Irsandi Dwi Oka Kurniawan, L. Atmaja, N. Widiastuti
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引用次数: 2

摘要

以甘蔗渣为碳源,尿素为氮源,经氢氧化钾(KOH)高温活化2 h,两步法合成氮掺杂活性炭(SBACN)。采用x射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外(FTIR)对合成的SBCN进行了表征。结果表明,由于KOH和尿素的协同活化作用,SBCN的结晶度低,石墨化程度低,微孔发育;这些特性为活性炭的二氧化碳吸附能力提供了重要的贡献,其二氧化碳吸附能力可达11.20% wt,高于原始活性炭。结果表明,氮官能团的存在对标准条件下的二氧化碳吸附特性有有益的影响,在固体吸附中表现出相当大的潜力。关键词氮掺杂氮掺杂活性炭,蔗渣,KOH和尿素活化,CO2吸附
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Synthesis N-Doped Activated Carbon from Sugarcane Bagasse for CO2 Adsorption
Nitrogen-doped activated carbon (SBACN) was synthesized from sugarcane bagasse waste as acarbon source and urea as nitrogen source through potassium hydroxide (KOH) activation for 2 h at high temperature via two step methods. The synthesized SBCN was characterized using X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Fourier Transform Infrared (FTIR). The results showed that the SBCN has low degree crystallinity and graphitization with highly developed micropores due to synergistik activation effect of KOH and urea. These characteristics provide an important contribution to carbon dioxide adsorption capacity, which can reach up to 11,20% wt and this value is higher than pristine activated carbon. The results indicating that the presence of this nitrogen functionalities is found to have a beneficial influence on the carbon dioxide adsorption characteristic in standart condition and exhibit considerable potential in solid adsorption. KeywordsNitrogen-doped Nitrogen-doped Activated Carbon, Sugarcane Bagasse, KOH and Urea Activation, CO2 Adsorption.
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审稿时长
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