染料敏化太阳能电池用低成本铂对电极

Anastasiia Iefanova, U. Gautam, P. Poudel, Daren Davoux, J. Nepal, Venkataiah Mallam, Q. Qiao, B. Logue, M. Baroughi
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引用次数: 3

摘要

采用喷雾沉积法制备了一种铂对电极(CE),以提供高效的染料敏化太阳能电池(DSSCs)。与传统的高效溅射法制备的铂反电极相比,该方法的铂用量减少了86%以上。这种新型反电极的成本估计仅为0.11美元/Wp。此外,该反电极在可见光和近红外波段具有80%以上的高透明度,并具有与传统Pt反电极相当的高催化活性。扫描电镜(SEM)图像显示,在透明导电氧化物(TCO)/玻璃衬底上分布着5 ~ 70 nm大小的铂纳米颗粒。基于该对电极的DSSC的功率转换效率为6.17%,而对应的参考DSSC的溅射Pt对电极的功率转换效率为6.46%。
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Low cost platinum counter electrode for dye-sensitized solar cells
A platinum counter-electrode (CE) was fabricated using spray-deposition method to provide efficient dye-sensitized solar cells (DSSCs). This method uses over 86% less Pt compared to conventional Pt counter-electrode prepared by highly efficient sputter deposition method. The cost of this new counter-electrode is estimated to be only 0.11$/Wp. Moreover, this counter-electrode exhibits a high transparency, over 80% in visible and near infrared, along with high catalytic activity, comparable with that of the conventional Pt counter-electrode. Scanning electron microscope (SEM) images show Pt nanoparticles varying in size from 5 nm to 70 nm distributed on transparent conducting oxide (TCO)/glass substrate. DSSCs based on this counter-electrode showed 6.17% power conversion efficiency, comparable to 6.46% efficiency of the corresponding reference DSSC with sputtered Pt counter-electrode.
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