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2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)最新文献

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Combining design of experiments and power loss computations to study the screen printing process 结合实验设计和功率损耗计算对丝网印刷过程进行研究
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744932
S. Thibert, J. Jourdan, B. Bechevet, J. Faissat, S. Mialon, D. Chaussy, N. Reverdy-Bruas, D. Beneventi
The screen printing process applied to the front side metallization of silicon solar cell was studied with a full factorial 324161 design of experiments on an industrial line. Four commercially silver pastes from different suppliers, six apertures, and nine stainless screens were used to analyze the printing results of two hundred and sixteen combinations. The fingers geometrical properties, the line resistivity, and the contact resistivity were inputted in a power loss simulation program to compute the optimal fingers spacing and the theoretical efficiency for each combination. The relative contribution and the effect of all factors and interactions on the solar cell efficiency were calculated to find out general guidelines for process optimization. Finally, a confirmation test was performed on mixed batches of 15.6 × 15.6 cm2, 200 μm thick Cz-Si solar cells to validate assumptions. With an optimized process a maximal 19.2 % efficiency was reached.
采用全因子324161工业试验设计,研究了硅太阳能电池正面金属化的丝网印刷工艺。来自不同供应商的四种商业银浆、六种孔径和九种不锈钢丝网被用来分析216种组合的印刷结果。将手指的几何特性、线电阻率和接触电阻率输入到功率损耗模拟程序中,计算出最佳手指间距和每种组合的理论效率。计算了各种因素和相互作用对太阳能电池效率的相对贡献和影响,从而得出工艺优化的一般准则。最后,对15.6 × 15.6 cm2, 200 μm厚的Cz-Si太阳能电池进行了验证试验。优化后的工艺效率最高可达19.2%。
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引用次数: 2
Performance of utility interconnected photovoltaic inverters operating beyond typical modes of operation 公用事业互联光伏逆变器超出典型运行模式的性能
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745071
S. Gonzalez, J. Stein, A. Fresquez, M. Ropp, D. Schutz
The high penetration of utility interconnected photovoltaic (PV) inverters can affect the utility at the point of common coupling. Today's utility interconnection standards are evolving to allow voltage and frequency support, and voltage and frequency ride-through capability. With multi-MW-sized PV plants and multitudes of small commercial and residential systems coming online each year, the interconnection standards are allowing distributed energy resource equipment to provide reactive power to supplement existing voltage-regulating devices and ride-through voltage and frequency anomalies. These new interconnection requirements, coupled with the high dc-to-ac ratios, are becoming more common with declining PV module costs and are changing the modes of operation for utility-interconnected PV systems. This report investigates the effects these modes of operation have on the inverter performance, array utilization, and power quality while focusing on conversion efficiency.
公用互联光伏逆变器的高渗透会影响公用耦合点的效用。今天的公用事业互连标准正在不断发展,以支持电压和频率,以及电压和频率穿越能力。随着每年多兆瓦级的光伏电站和众多小型商业和住宅系统的上线,互联标准允许分布式能源设备提供无功功率,以补充现有的电压调节设备,并通过电压和频率异常。随着光伏组件成本的下降,这些新的互连要求,加上高直流交流比,正变得越来越普遍,并正在改变公用事业互联光伏系统的运行模式。本报告探讨了这些操作模式对逆变器性能、阵列利用率和电能质量的影响,同时重点介绍了转换效率。
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引用次数: 6
The effect of rapid thermal annealing on the performance of CIGS cells with an ITO layer 快速热退火对ITO层CIGS电池性能的影响
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744340
Z. Li, R. Krishnan, G. Tong, R. Kaczynski, U. Schoop, T. Anderson
Rapid thermal annealing studies were conducted on SS/Mo/CIGS/CdS/ITO/Ag devices as a function of anneal time in dry N2 in the temperature range 50 to 200°C, as well as in humidified N2 (85% RH) at 85°C. Interestingly, dry N2 annealing produced an enhancement in cell performance for low thermal budget, predominantly due to increased JSC, and to a lesser extent higher VOC. As examples, CIGS cell efficiency increased by 1.8±0.8% after annealing at 50°C for 300s and 2.0±2.3% when annealed at 100°C for 600s. At higher anneal temperature or longer time the cell performance deteriorated with significant decrease in FF and VOC. The results for the 85% RH at 85°C anneals were similar to the dry anneal studies but with less dramatic changes. Cell performance results after dark annealing indicate light-soaking effects induced by the lamp are not important at these relatively short anneal times. Measurement of quantum efficiency for the annealed samples supports the assumption that the buffer layer/absorber interface degrades at a relatively low temperature and that ITO degradation takes place at higher thermal budgets.
研究了SS/Mo/CIGS/CdS/ITO/Ag器件在50 ~ 200℃的干燥N2和85℃的加湿N2 (85% RH)中退火时间的变化规律。有趣的是,干燥的N2退火在低热预算下产生了电池性能的增强,主要是由于JSC的增加,以及较小程度上更高的VOC。例如,在50℃退火300s后,CIGS电池效率提高了1.8±0.8%,在100℃退火600s时,效率提高了2.0±2.3%。在较高的退火温度或较长的退火时间下,电池性能恶化,FF和VOC显著降低。85°C下85% RH退火的结果与干燥退火研究相似,但变化较小。暗退火后的电池性能结果表明,在这些相对较短的退火时间内,灯引起的光浸泡效应并不重要。退火样品的量子效率测量支持缓冲层/吸收层界面在相对较低温度下降解的假设,而ITO降解发生在较高的热预算下。
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引用次数: 1
CZTSe devices fabricated from CZTSSe nanoparticles 由CZTSSe纳米颗粒制备的CZTSe器件
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744994
B. Walker, Bethlehem G. Negash, Stephen M. Szczepaniak, Kevin Brew, R. Agrawal
To understand and control the growth paths of kesterite based CZTSe films as prepared from kesterite nanoparticles we investigate films prepared from different chalcogenide ratios in the initial nanoparticles. To do so we introduce a new method for producing kesterite nanocrystals with controlled ratios of sulfur and selenium. Final CZTSe devices are prepared from these nanoparticles with total area solar power conversion efficiencies up to and exceeding eight percent (see Fig. 1). All devices made from selenizing nanoparticles that contained sulfur showed efficiency greater than six percent while pure selenide nanoparticles resulted in non-performing devices.
为了了解和控制由kesterite纳米颗粒制备的kesterite基ctse薄膜的生长路径,我们研究了初始纳米颗粒中不同硫族化物比例制备的薄膜。为此,我们介绍了一种新的方法,以控制硫和硒的比例来生产kesterite纳米晶体。最终的CZTSe器件由这些纳米颗粒制备,其总面积太阳能转换效率高达并超过8%(见图1)。所有由含硫硒化纳米颗粒制成的器件的效率均大于6%,而纯硒化纳米颗粒导致器件不良。
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引用次数: 2
MoSe2 formation during fabrication of Cu(In, Ga)Se2 solar cell absorbers by using stacked elemental layer precursor and selenization at high temperatures 利用叠置元素层前驱体和高温硒化法制备Cu(In, Ga)Se2太阳能电池吸收体过程中MoSe2的形成
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744990
S. Schmidt, C. Wolf, N. Papathanasiou, R. Schlatmann, C. Klimm, M. Klaus, C. Genzel, M. Billing, H. Schock
Cu(In, Ga)Se2 solar cell absorbers are prepared on a Mo-coated glass substrate by using a sequential process consisting of a sputter deposition of an In/CuGa/In metal precursor, subsequent PVD deposition of a Se layer and annealing in N2 atmosphere. The Se concentration in the final layer stack was found to be relatively up to 20 % higher than expected. The excess Se is bound in a MoSe2 layer with laterally varying thickness, between the absorber and the Mo back contact. Such a layer can lead to an increase in the series resistance of the completed solar cells. By pumping at a specific time, we were able to reduce the Se partial pressure selectively during the selenization. For a constant annealing time, we find that the MoSe2 thickness increases with the time in which a high Se partial pressure is maintained, i.e., the time before the selective pumping. A significant reduction of the Se partial pressure after half the annealing time led to solar cells with the smallest series resistance and overall best conversion efficiency. We further found that the addition of NaF before the annealing led to comparatively thin MoSe2 layers. This suggests that the Na incorporation from the glass substrate in our process is too small to hinder the MoSe2 growth. A more specific control of the Na supply is required in our process to manipulate the MoSe2 growth and the doping density in the absorber.
采用溅射沉积In/CuGa/In金属前驱体、PVD沉积Se层和N2气氛退火的顺序工艺,在mo涂层玻璃衬底上制备了Cu(In, Ga)Se2太阳能电池吸收体。最后一层堆积中的硒浓度比预期高出20%。多余的Se被束缚在吸收剂和Mo背接触之间具有横向变化厚度的MoSe2层中。这样一层可以导致完成的太阳能电池串联电阻的增加。通过在特定时间泵送,我们能够在硒化过程中选择性地降低硒分压。在一定的退火时间下,我们发现MoSe2的厚度随着高Se分压(即选择性泵送前的时间)保持的时间的增加而增加。经过一半的退火时间后,Se分压显著降低,使得太阳能电池具有最小的串联电阻和最佳的转换效率。我们进一步发现,在退火前加入NaF可以得到相对较薄的MoSe2层。这表明在我们的工艺中,来自玻璃衬底的Na掺入量太小,不会阻碍MoSe2的生长。在我们的工艺中,需要对Na供应进行更具体的控制,以操纵吸收剂中MoSe2的生长和掺杂密度。
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引用次数: 3
Conceptual product development with integrated concentrating PV systems — CPV in the built environment from a designer's perspective 集成聚光光伏系统的概念产品开发-从设计师的角度看建筑环境中的CPV
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744193
A. Reinders, M. Wiesenfarth, R. King
Our paper shows and discusses the results of a design study regarding product applications based on concentrating PV systems. It is generally acknowledged that CPV technology has great potential in medium to large power systems. So far the potential of CPV for products in the built environment has hardly been investigated. To capture probable future CPV products a project was executed in 2012 with 15 teams of design students who were commissioned to develop a conceptual product design with integrated CPV. Though all designs were innovative and surprising, four concepts appeared to be technically feasible: a flexible roof system, a shading bench with e-charger, a concept called Parasol; and an e-mobility charger. It is concluded that from the perspective of industrial design engineering a whole range of innovative CPV products can be developed for use in the built environment.
本文展示并讨论了基于聚光光伏系统的产品应用设计研究的结果。CPV技术在大中型电力系统中具有巨大的应用潜力。到目前为止,CPV在建筑环境产品中的潜力几乎没有被调查过。为了捕捉未来可能的CPV产品,我们在2012年执行了一个项目,由15个设计专业的学生组成的团队被委托开发一个集成CPV的概念产品设计。虽然所有的设计都是创新和令人惊讶的,但有四个概念在技术上似乎是可行的:一个灵活的屋顶系统,一个带电子充电器的遮阳长凳,一个名为阳伞的概念;还有一个电动汽车充电器。结论是,从工业设计工程的角度来看,可以开发一系列创新的CPV产品用于建筑环境。
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引用次数: 3
Comparison of different DC Arc spectra — Derivation of proposals for the development of an international arc fault detector standard 不同直流电弧光谱的比较。国际电弧故障检测器标准发展建议的推导
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744449
F. Reil, A. Sepanski, S. Raubach, M. Vosen, E. Dietrich
The number of German PV installations reach in early 2013 1.4 million systems. On the basis of recent research which was carried out within a 3 year R&D-project of TÜV Rheinland with Fraunhofer ISE and several industry partners, around 75 cases were found where a PV system caused a fire through arc faults or hot spots. Out of these known incidents, 65 cases caused major damage whereas 10 faults lead to total loss of the system and building [1]. These numbers display that fire incidents caused by e.g. arc faults are a minority, but every case reveals that latent risks exist when defective installation or products are applied. This work focuses on the qualification of different arc noise spectra which displays a variety of characteristics depending on the electrode contacts, contact materials, implied PV solar simulator, PV array or whether the arc was ignited in a short circuit or being in series with a load resistor or even the inverter.
2013年初,德国光伏安装数量达到140万套。在最近的研究中,TÜV莱茵与Fraunhofer ISE和几个行业合作伙伴进行了为期3年的研发项目,发现了大约75个光伏系统通过电弧故障或热点引起火灾的案例。在这些已知事故中,65起造成重大损失,10起故障导致系统和建筑物全部损失。这些数字表明,由电弧故障引起的火灾事件是少数,但每一个案例都表明,当安装或产品应用缺陷时,存在潜在的风险。本文重点研究了不同电弧噪声谱的定性,根据电极触点、触点材料、隐含式光伏太阳能模拟器、光伏阵列或电弧是否在短路中点燃或与负载电阻甚至逆变器串联而显示出不同的特征。
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引用次数: 6
Fabrication of dye-sensitized solar cells with N-doped TiO2 thin films: Effect of the nitrogen doping on the photoexcitation processes and generation of electron acceptor states n掺杂TiO2薄膜制备染料敏化太阳能电池:氮掺杂对光激发过程和电子受体态生成的影响
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745030
D. A. Duarte, M. Massi, Argemiro Soares da Silva Sobrinho
Nowadays much efforts have been done with the aim to increase the global efficiency of the dye-sensitized solar cells so that the doping of the TiO2 structure have been suggested as one of the most interesting solutions. In this paper the effect of the nitrogen incorporation in the TiO2 structure and studies about the effect of the doped films on the general properties of the solar cells are conducted.
目前,为了提高染料敏化太阳能电池的整体效率,已经做了很多努力,因此二氧化钛结构的掺杂被认为是最有趣的解决方案之一。本文研究了氮掺杂对TiO2结构的影响,以及掺杂膜对太阳能电池一般性能的影响。
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引用次数: 1
Conversion efficiencies of six grid-tied inverters at the Tucson electric power solar test yard 图森电力太阳能试验场六个并网逆变器的转换效率
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6745066
A. Brooks, J. Fijal, M. T. St. Germaine, Sean Orsburn, James B. Greenberg, V. Lonij, D. DellaGiustina, A. Cronin
We measure the conversion efficiencies of six inverters manufactured by Fronius, SMA, and Xantrex. We measure efficiencies ranging from 87.0% to 91.7%. We find differences between manufacturers' specified efficiency and field performance of -3.8% and -6.0% Inverter efficiencies are also studied as a function of global horizontal irradiance and ambient temperature.
我们测量了由Fronius, SMA和Xantrex制造的六种逆变器的转换效率。我们测量的效率范围从87.0%到91.7%。我们发现制造商的指定效率和现场性能之间的差异为-3.8%和-6.0%,逆变器效率也作为全球水平辐照度和环境温度的函数进行了研究。
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引用次数: 3
Achievement of 15.1% total area efficiency on 1.09m2 monolithic CIGSeS modules in TSMC Solar production line 在台积电太阳能生产线1.09m2单片CIGSeS模块上实现15.1%的总面积效率
Pub Date : 2013-06-16 DOI: 10.1109/PVSC.2013.6744480
Sean Yang, Kwang-Ming Lin, Wen-Chin Lee, C. Lin, L. Chu
15.1% total area efficiency on a monolithic 1.09m2 CIGSeS modules sets a new record for commercial-size, monolithic thin-film modules. This achievement results from improvements in both module design and thin-film composition, including: absorber improvement, cell redesign, and dead area reduction. Absorber improvement mainly consists of Selenization and Sulfurization (SAS) process optimization, resulting in open-circuit voltage (Voc) increase. Cell redesign mitigates the interconnect loss and maximize its benefit for Fill Factor (FF), while the reduction of the dead area increases module current. Production of modules with efficiency exceeding 15% is repeatable in the TSMC Solar production line located in Taichung, Taiwan.
1.09m2单片CIGSeS模块的总面积效率为15.1%,创下了商业尺寸单片薄膜模块的新纪录。这一成就源于组件设计和薄膜成分的改进,包括:吸收器改进、电池重新设计和死区减少。吸收器改进主要包括硒化和硫化(SAS)工艺优化,从而提高开路电压(Voc)。电池的重新设计减轻了互连损耗,并最大限度地提高了填充系数(FF),而死区的减少增加了模块电流。位于台湾台中的台积电太阳能生产线可重复生产效率超过15%的组件。
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引用次数: 1
期刊
2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)
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