硫酸氧镁水泥/聚苯乙烯复合材料燃烧性能研究

Yu Shuijun, Xie Gaochao, Ren Mo, Yang Dailin
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引用次数: 1

摘要

为解决聚苯乙烯易燃易产生有毒气体的问题ꎬ采用硫酸镁水泥和聚苯乙烯颗粒制备了硫酸镁水泥/聚苯乙烯复合材料。然后ꎬ通过LOI试验ꎬUL-94垂直燃烧试验ꎬ烟密度试验ꎬ和热重分析研究了轻燃氧化镁与七水硫酸镁不同配比对聚苯乙烯颗粒燃烧性能的影响。结果表明:当硫酸镁含量保持不变时ꎬ失重范围和聚苯乙烯复合材料收率随轻烧氧化镁含量的增加而减小ꎬ,最大失重率随轻烧氧化镁含量的增加而增大,在700℃时最大失重率可达80􀆰73%。硫酸镁水泥包覆聚苯乙烯的LOI可达37􀆰2%ꎬ,且在轻烧氧化镁固定的情况下,LOI随硫酸镁的增大而增大。在另一种燃烧方式不变的情况下,LOI随轻烧氧化镁增加的趋势相同。复合材料的UL 94等级均可达到V-0ꎬ,其烟雾密度比纯聚苯乙烯颗粒低30倍左右。硫酸镁水泥能显著提高聚苯乙烯的阻燃性能和抑烟性能。
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Study on combustion properties of magnesium oxysulfate cement/polystyrene composites
In order to solve problem that polystyrene is inflammable and easy to produce poisonous gasꎬ magnesium oxysulfate cement and polystyrene particles were used to make magnesium oxysulfate cement / polystyrene composite material. Thenꎬ effects of different ratios of lightly ̄burned magnesium oxide and heptahydrate magnesium oxysulfate on combustion performance of polystyrene particles were studied by LOI testꎬ UL-94 vertical combustion testꎬ smoke density testꎬ and TGA. The results show that when content of magnesium sulfate maintains unchangedꎬ weightlessness range and rate of polystyrene composites decreases with the increase of lightly ̄burned magnesium oxideꎬ and so does the maximum mass loss rate while residual carbon rate increases with it at 700 °C with its maximum rate able to reach 80􀆰 73%. LOI of polystyrene coated with magnesium oxysulfate cement can reach up to 37􀆰 2%ꎬ and it increases along with 中 国 安 全 科 学 学 报 China Safety Science Journal 第30卷 2020年 that of magnesium oxysulfate when lightly ̄burned magnesium oxide stays fixed. It shows the same trend of LOI increasing along lightly ̄burned magnesium oxide when the other is unchanged. UL 94 level of composite materials can all reach V-0ꎬ and their smoke density is about 30 times lower than that of pure polystyrene particles. Flame retardation and smoke suppression of polystyrene are significantly improved by magnesium oxysulfate cement.
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来源期刊
CiteScore
1.30
自引率
0.00%
发文量
8733
期刊介绍: China Safety Science Journal is administered by China Association for Science and Technology and sponsored by China Occupational Safety and Health Association (formerly China Society of Science and Technology for Labor Protection). It was first published on January 20, 1991 and was approved for public distribution at home and abroad. China Safety Science Journal (CN 11-2865/X ISSN 1003-3033 CODEN ZAKXAM) is a monthly magazine, 12 issues a year, large 16 folo, the domestic price of each book is 40.00 yuan, the annual price is 480.00 yuan. Mailing code 82-454. Honors: Scopus database includes journals in the field of safety science of high-quality scientific journals classification catalog T1 level National Chinese core journals China Science and technology core journals CSCD journals The United States "Chemical Abstracts" search included the United States "Cambridge Scientific Abstracts: Materials Information" search included
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