重复频率双极方波电压下聚合物介质的表面损伤

Shihang Wang, Jian Gao, Jiao Xiang, Chuang Zhang, Hang Fu, Zhimin Yan, Jianying Li, Shengtao Li
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引用次数: 0

摘要

接口是绝缘损坏的起点,特别是在高频双极电压下。在介电/电极界面注入和提取电荷过程中,电场畸变和能量释放显著改变了分子结构,影响了介电性能,使表面层成为绝缘的薄弱环节。本文研究了重复频率双极方波电压均匀电场作用下聚合物介质的损伤。之所以选择聚乙烯作为样品,是因为它在电场作用下更容易降解。通过对比电老化前后聚乙烯样品的测试结果,发现浅电荷阱密度增加,直流击穿强度明显下降,而交流(50 Hz)击穿电压基本不变。结果表明,在重复频率双极方波电压作用下,聚合物介质的损伤始于介质表面。此外,这意味着直流击穿强度可以成为表征在重复频率双极方波电压下工作后介电损伤程度的关键特征。环氧树脂和聚酰亚胺的电老化实验也证实了这一结论。本研究为进一步系统研究重复频率双极方波电压下介质损伤机理奠定了初步基础。
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Surface damage of polymer dielectric under repetitive frequency bipolar square-wave voltage
The interface is the starting point for insulation damage, especially at high frequency bipolar voltages. The electric field distortion and energy release during charge injection and extraction at the dielectric/electrode interface significantly change the molecular structure, affecting the dielectric properties, and leading the surface layer a weak point of insulation. In this paper, the damage of polymer dielectric under uniform electric field of repetitive frequency bipolar square-wave voltage was studied. The polyethylene was chosen as the sample since it degrades more easily under the electric field. By comparing the test results of the polyethylene samples before and after the electrical aging process, it was found that the density of the shallow charge traps increased, and the dc breakdown strength decreased significantly while the ac (50 Hz) breakdown voltage was almost unchanged. It proved that the damage of polymer dielectric under the repetitive frequency bipolar square-wave voltage starts at the surface of the dielectric. In addition, it means that dc breakdown strength can be a key feature to characterize the degree of dielectric damage after serving under repetitive frequency bipolar square-wave voltage. The conclusion has also been proved by the electrical aging experiments of epoxy resin and polyimide. This study lay a preliminary foundation for further systematic research on the dielectric damage mechanism under repetitive frequency bipolar square-wave voltage.
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